Phenylthioethene

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Names

[ CAS No. ]:
1822-73-7

[ Name ]:
Phenylthioethene

[Synonym ]:
vinylsulfanyl-benzene
vinyl phenyl thioether
(Phenylthio)ethylene
(Vinylsulfanyl)benzene
Phenyl vinyl sulphide
PHENYL VINYL SULFIDE
(vinylthio)benzene
MFCD00009646
EINECS 217-351-2
Benzene, (ethenylthio)-
thiophenyl vinyl ether
phenyl ethyl thioether
Phenylthioethene
Phenyl etheryl sulfide
phenyl vinyl thioether

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
199.1±13.0 °C at 760 mmHg

[ Molecular Formula ]:
C8H8S

[ Molecular Weight ]:
136.214

[ Flash Point ]:
45.6±0.0 °C

[ Exact Mass ]:
136.034668

[ PSA ]:
25.30000

[ LogP ]:
2.04

[ Vapour Pressure ]:
0.5±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.577

[ Storage condition ]:
2-8°C

MSDS

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R10

[ Safety Phrases ]:
S16

[ RIDADR ]:
UN 1993 3/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

[ HS Code ]:
2930909090

Synthetic Route

Precursor & DownStream

Precursor

  • (Vinylsulfinyl)benzene
  • 2-chloroethenylmercury
  • Thiophenol
  • vinyl acetate
  • Acetylene
  • 2-chloro-1-(trimethylsilyl)ethyl phenyl sulfide
  • (6-Butyl-5-decen-5-yl)-λ2-stannane
  • Diphenyl disulfide
  • 2-bromoethyl phenyl sulfide
  • phenylethylthiol

DownStream

  • 3,4-Dihydroisoquinoline
  • (Vinylsulfinyl)benzene
  • ethyl 5-methyl-2-phenylsulfanyl-2,3-dihydrofuran-4-carboxylate
  • 2,2-dichlorocyclopropyl phenyl sulfone
  • diphenyl(2-phenylsulfanylethyl)phosphane
  • Benzene,(1-propen-1-ylthio)-
  • Carbon tetrafluoride
  • hexafluoroethane
  • 4-Methoxystyrene
  • 4-Methoxybiphenyl

Customs

[ HS Code ]: 2930909090

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Tri- and tetrasubstituted functionalized vinyl sulfides by radical allylation.

Org. Lett. 15(24) , 6250-3, (2013)

2-Fluoropyridinyl-6-oxy- precursors derived from phenyl vinyl sulfide react with radicals generated from xanthates via an addition-elimination process to furnish the corresponding vinyl sulfides in go...


More Articles


Related Compounds

  • 1-bromo-1-phenylthioethene
  • 1-bromo-2-phenylthioethene
  • 1-Chloro-1-phenylthioethene
  • 1-phenyl-2-phenylthioethene
  • Z-1-bromo-2-phenylthioethene
  • (E)-1-nitro-2-phenylthioethene
  • Benzyl 4-({[(tert-butoxy)carbonyl](methyl)amino}methyl)-4-hydroxypiperidine-1-carboxylate
  • tert-butyl N-(2-{[(benzyloxy)carbonyl](2-hydroxypropyl)amino}ethyl)carbamate
  • 3-(4-Methylphenyl)prop-2-yne-1-sulfonyl chloride
  • benzyl N-[(2R,3S)-3-{[(tert-butoxy)carbonyl]amino}-4-hydroxybutan-2-yl]carbamate
  • Tert-butyl 3-({[(benzyloxy)carbonyl]amino}methyl)-3-(2-hydroxyethyl)azetidine-1-carboxylate
  • Tert-butyl 4-(hydroxymethyl)-5-(2,2,2-trifluoroacetamido)azepane-1-carboxylate
  • Tert-butyl 4-(hydroxymethyl)-2-(2,2,2-trifluoroacetyl)-2,8-diazaspiro[4.5]decane-8-carboxylate
  • 4-Methyl-3-[(1-methylcyclopentyl)methyl]cyclohexan-1-one
  • tert-butyl N-(2-hydroxyethyl)-N-[1-(2,2,2-trifluoroacetyl)piperidin-3-yl]carbamate
  • Tert-butyl 4-hydroxy-1'-(2,2,2-trifluoroacetyl)-[4,4'-bipiperidine]-1-carboxylate
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