1,4,9,12-Tetraoxadispiro(4.2.4.2)tetradecane

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Names

[ CAS No. ]:
183-97-1

[ Name ]:
1,4,9,12-Tetraoxadispiro(4.2.4.2)tetradecane

[Synonym ]:
cyclohexane-1,4-dione bisethylene acetal
1,4,9,12-Tetraoxadispiro[4.2.4.2]tetradecane
1,4-Cyclohexanedione bis(ethylene acetal)
1,4-Cyclohexanedione Bis(ethyleneketal)
1,4,9,12-Tetraoxadispiro(4.2.4.2)tetradecane
1,4-cyclohexanedione diethyl acetal
cyclohexane-1,4-dione bis-ethylene ketal
MFCD00010851
1,4-Cyclohexanedione bis-<1,2-ethanediyl acetal>

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
276.5±0.0 °C at 760 mmHg

[ Melting Point ]:
79-80 °C(lit.)

[ Molecular Formula ]:
C₁₀H₁₆O₄

[ Molecular Weight ]:
200.232

[ Flash Point ]:
136.0±33.3 °C

[ Exact Mass ]:
200.104858

[ PSA ]:
36.92000

[ LogP ]:
0.67

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.513

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Ethylene glycol
1,4-Cyclohexanedione
2-Dimethylamino-1,3-dioxolane
1,4-Dioxaspiro[4.5]decan-8-one
ethyl 8-oxo-1,4-dioxaspiro[4.5]decane-7-carboxylate

DownStream

1,4-Dioxaspiro[4.5]decan-8-one
1,4-Cyclohexanedione
1,4,9,12-Tetrathiadispiro[4.2.4.2]tetradecane
[1,1':4',1''-Terphenyl]-4,4''-diol
8-Methylene-1,4-dioxaspiro[4.5]decane

Articles

A review of the reactivity of organic compounds with oxygen-containing functionality in superheated water. Siskin M and Katritzky AR.

J. Anal. Appl. Pyrolysis 54(1) , 193-214, (2000)

13,14-dimethyl-1,4,9,12-tetraoxadispiro[4.2.48.25]tetradecane
4,7,12,14-tetraoxadispiro[4.2.48.25]tetradecane
1,4,9,12-Tetrathiadispiro[4.2.4.2]tetradecane
1,4,9,12-tetraoxadispiro[4.2.48.25]tetradeca-6,13-diene
7,14-dibromo-1,4,9,12-tetraoxadispiro[4.2.48.25]tetradecane
1,4,9,12-tetraoxacyclohexadecane-5,8,13,16-tetrone
5-{1-[3-(2-Methoxyphenyl)propanoyl]pyrrolidin-2-yl}-3-(4-methylphenyl)-1,2,4-oxadiazole
5-[1-(2-Chloro-4-fluorobenzoyl)pyrrolidin-2-yl]-3-(4-methylphenyl)-1,2,4-oxadiazole
3-(4-Methylphenyl)-5-[1-(4-phenylbutanoyl)pyrrolidin-2-yl]-1,2,4-oxadiazole
2-Methoxy-5-({2-[3-(4-methylphenyl)-1,2,4-oxadiazol-5-yl]pyrrolidin-1-yl}carbonyl)pyridine
5-{1-[(4-Methylphenoxy)acetyl]pyrrolidin-2-yl}-3-(4-methylphenyl)-1,2,4-oxadiazole
3-(4-Fluorophenyl)-5-{1-[(3-methylphenoxy)acetyl]pyrrolidin-2-yl}-1,2,4-oxadiazole
3-(4-Fluorophenyl)-5-{1-[(2-methoxyphenyl)acetyl]pyrrolidin-2-yl}-1,2,4-oxadiazole
[2-[3-(4-Fluorophenyl)-1,2,4-oxadiazol-5-yl]pyrrolidin-1-yl]-(3,4,5-triethoxyphenyl)methanone
5-[1-(3,4-Dimethoxybenzoyl)pyrrolidin-2-yl]-3-(4-fluorophenyl)-1,2,4-oxadiazole
(2-Ethoxyphenyl)-[2-[3-(4-fluorophenyl)-1,2,4-oxadiazol-5-yl]pyrrolidin-1-yl]methanone

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