methibenzuron

Suppliers

Names

[ Name ]:
methibenzuron

[Synonym ]:
Methabenzthiazuron [BSI:ISO]
1-(benzothiazol-2-yl)-1,3-dimethylurea
Methbenzthiazuron
Metabenzthiazuron
N-2-benzothiazolyl-N,N’-dimethylurea
Methabenzthiazuron
N-benzthiazolyl-N-methyl-N'-methyl-urea
3-(benzthiazol-2-yl)-1,3-dimethyl-urea
TRIBUNIL
MFCD00055498
Preparation 5633
N-(benzothiazol-2-yl)-N,N'-dimethylurea
1-benzothiazol-2-yl-1,3-dimethylurea
Caswell No. 081B
1-(1,3-Benzothiazol-2-yl)-1,3-dimethylurea
Urea, N-2-benzothiazolyl-N,N'-dimethyl-
1-(2-benzthiazolyl)-1,3-dimethylurea
methibenzuron
N-1,3-benzothiazol-2-yl-N,N’-dimethylurea
EINECS 242-505-0
Bayer 5633

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Melting Point ]:
119-120.5°

[ Molecular Formula ]:
C₁₀H₁₁N₃OS

[ Molecular Weight ]:
221.279

[ Flash Point ]:
11ºC

[ Exact Mass ]:
221.062286

[ PSA ]:
73.47000

[ LogP ]:
1.63

[ Index of Refraction ]:
1.682

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: YR8980000

CHEMICAL NAME :: Urea, 1-(2-benzothiazolyl)-1,3-dimethyl-

CAS REGISTRY NUMBER :: 18691-97-9

BEILSTEIN REFERENCE NO. :: 0196633

LAST UPDATED :: 199612

DATA ITEMS CITED :: 11

MOLECULAR FORMULA :: C10-H11-N3-O-S

MOLECULAR WEIGHT :: 221.30

WISWESSER LINE NOTATION :: T56 BN DSJ CN1&VM1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >2500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,561,1991

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >500 mg/m3/4H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A263,1983

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A263,1983

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 315 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Behavioral - antipsychotic

REFERENCE :: PFZNAQ Pflanzenschutz-Nachricten. (Farbenfabriken Bayer GmbH, Pflanzenschutz - Abteilung, Leverkusen, Fed. Rep. Ger.) V.15- 1962- Volume(issue)/page/year: 22,351,1969

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: >1 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,561,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Mammal - dog

DOSE/DURATION :: >1 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,561,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Mammal - cat

DOSE/DURATION :: >1 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A263,1983

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: >2500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A263,1983

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Unreported

SPECIES OBSERVED :: Bird - quail

DOSE/DURATION :: 1 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: FMCHA2 Farm Chemicals Handbook. (Meister Pub., 37841 Euclid Ave., Willoughy, OH 44094) Volume(issue)/page/year: -,C309,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Unreported

SPECIES OBSERVED :: Mammal - species unspecified

DOSE/DURATION :: 2500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 30ZDA9 "Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag New York, Inc., 1971 Volume(issue)/page/year: -,227,1971

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Unreported

SPECIES OBSERVED :: Bird - domestic

DOSE/DURATION :: >2 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: FMCHA2 Farm Chemicals Handbook. (Meister Pub., 37841 Euclid Ave., Willoughy, OH 44094) Volume(issue)/page/year: -,C309,1991

Safety Information

[ Symbol ]:

GHS09

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H410

[ Precautionary Statements ]:
P273-P501

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;Gloves

[ Hazard Codes ]:
N,T,F

[ Risk Phrases ]:
R50/53

[ Safety Phrases ]:
S60

[ RIDADR ]:
UN 3077 9/PG 3

[ RTECS ]:
YR8980000

[ Packaging Group ]:
III

[ HS Code ]:
2934200017

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

N-methylbenzothiazol-2-amine
1,3-Dimethylurea
Methylisocyanate 1 x 500mg neat

DownStream

Customs

[ HS Code ]: 2934200017

[ Summary ]:
2934200017 1-(benzo[d]thiazol-2-yl)-1,3-dimethylurea。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:20.0%

Articles

[Effect of post-emergence application of two herbicides to winter wheat on the soil microflora (author's transl)].

Zentralbl. Bakteriol. Naturwiss. 134(7) , 573-86, (1979)

In a field experiment the herbicides U 46 PD-Fluid (dichlorprop salt) and Tribunil (methabenzthiazuron) were applied in April 1976 post-emergence to winter wheat cultivated in 3 different soils. After...

[Possibilities and limits of studies with C14-labeled herbicides for predicting the tendency of pesticides to wash out into the soil].

Schriftenr. Ver. Wasser. Boden. Lufthyg. 79 , 107-27; discussion 151-8, (1989)

Plant experiments on the bioavailability of unextracted [carbonyl-14C]methabenzthiazuron residues from soil.

J. Agric. Food Chem. 28(1) , 122-5, (1980)

4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
1-{4-[(2H-1,3-benzodioxol-5-yl)methyl]piperazin-1-yl}-3-[(2,5-dimethoxyphenyl)methoxy]propan-2-ol dihydrochloride
1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
Ethyl 2-(2-phenylethoxy)benzeneacetate
1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
(4-Methyl-tetrahydro-furan-2-yl)-methanol
N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
tert-Butyl-DL-alanine