diethyl (3-chloropropyl)malonate

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Names

[ CAS No. ]:
18719-43-2

[ Name ]:
diethyl (3-chloropropyl)malonate

[Synonym ]:
(3-chloro-propyl)-malonic acid diethyl ester
diethyl chloropropylmalonate
Malonic acid,3-chloropropyl-,diethyl ester
2-(3-chloropropyl)malonic acid diethyl ester
diethyl 2-(3-chloropropyl)malonate
(3-Chlor-propyl)-malonsaeure-diaethylester
Diethyl (3-chloropropyl)malonate
MFCD00009169

Chemical & Physical Properties

[ Density]:
1.101 g/mL at 25 °C(lit.)

[ Boiling Point ]:
136 °C5 mm Hg(lit.)

[ Molecular Formula ]:
C10H17ClO4

[ Molecular Weight ]:
236.69300

[ Flash Point ]:
>230 °F

[ Exact Mass ]:
236.08200

[ PSA ]:
52.60000

[ LogP ]:
1.74780

[ Vapour Pressure ]:
0.0021mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.443(lit.)

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2917190090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 1-Bromo-3-chloropropane
  • Diethyl malonate
  • 3-chloropropyl iodide

DownStream

  • 5-Chloropentanoic acid
  • DIETHYL 2-(3-CHLOROPROPYL)-2-ETHYLMALONATE
  • 2H-1,2-Oxazine-3-carboxamide, 2-(chloroacetyl)-5,6-dihydro-N-methyl- (9CI)
  • 2H-1,2-Oxazine-3-carboxamide, 2-(chloroacetyl)tetrahydro-N-methyl- (9CI)

Customs

[ HS Code ]: 2917190090

[ Summary ]:
2917190090 acyclic polycarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Synthetic studies in unnatural cyclic amino acids. Lee VJ and Woodward RB.

J. Org. Chem. 44(14) , 2487-2491, (1979)


More Articles

Related Compounds

  • Diethyl (3-chloropropyl)phosphonate
  • diethyl 2-(2-(benzyloxy)-3-chloropropyl)malonate
  • diethyl 2,2-bis(3-chloropropyl)propanedioate
  • Diethyl (3-methylbutyl)malonate
  • diethyl (3-benzoylphenyl)malonate
  • diethyl (3-oxopropyl)malonate
  • 3-[6-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-4,4-dimethylhexanoyl]-1,3-thiazolidine-4-carboxylic acid
  • rac-(1R,5R)-1-amino-3lambda6-thiabicyclo[3.1.0]hexane-3,3-dione
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine