(2-Methylphenoxy)acetic acid

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Names

[ CAS No. ]:
1878-49-5

[ Name ]:
(2-Methylphenoxy)acetic acid

[Synonym ]:
(2-Methylphenoxy)acetic acid
Acetic acid, 2-(2-methylphenoxy)-
O-CRESOXYACETIC ACID
α-Methylphenoxyacetic acid
2-methylphenyloxyacetic acid
IFLAB-BB F1924-0028
o-methylphenoxyacetic acid
EINECS 217-517-4
2-Methylphenoxyacetic acid
MFCD00014354

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
288.4±15.0 °C at 760 mmHg

[ Melting Point ]:
155-157 °C(lit.)

[ Molecular Formula ]:
C9H10O3

[ Molecular Weight ]:
166.174

[ Flash Point ]:
115.7±13.9 °C

[ Exact Mass ]:
166.062988

[ PSA ]:
46.53000

[ LogP ]:
1.80

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.537

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
AJ7573000
CHEMICAL NAME :
Acetic acid, (o-tolyloxy)-
CAS REGISTRY NUMBER :
1878-49-5
BEILSTEIN REFERENCE NO. :
1943465
LAST UPDATED :
199612
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C9-H10-O3
MOLECULAR WEIGHT :
166.19

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
452 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TSPMA6 Travaux de la Societe de Pharmacie de Montpellier. (Soc. de Pharmacie de Montpellier, Faculte de Pharmacie de Montpellier, Ave. Ch.-Flahault, 34060 Montpellier, France) V.1- 1942- Volume(issue)/page/year: 34,121,1974

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
AJ7573000

[ HS Code ]:
2918990090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • MCPA
  • o-cresol
  • Chloroacetic acid
  • Glycolic acid
  • 4-Iodotoluene
  • 2-(2-methylphenoxy)methylethanoate
  • Sodium chloroacetate
  • Bromoacetic acid
  • ethyl 2-(o-tolyloxy)acetate
  • sodium,2-methylphenolate

DownStream

  • (2-Methylphenoxy)acetonitrile
  • MCPA
  • (2-Chloro-6-methylphenoxy)acetic acid
  • 8,9,10-trichloro-6-methyl-1,4-dioxa-spiro[4.5]dec-6-en-2-one
  • 4-methylphenoxyacetic acid
  • ethyl 2-(o-tolyloxy)acetate
  • 2-(2-methylphenoxy)acetyl chloride
  • 2-[(2-Methylphenoxy)methyl]-1H-benzimidazole
  • O-TOLYLOXY-ACETIC ACID HYDRAZIDE
  • Carbon dioxide

Customs

[ HS Code ]: 2918990090

[ Summary ]:
2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Methylphenoxy) acetic acid. Cox PJ and Hickey G.

Acta Crystallogr. Sect. E Struct. Rep. Online 60(5) , o771-73, (2004)


More Articles

Related Compounds

  • 2-(2-METHYLPHENOXY)ACETIC ACID
  • N,N-diethylethanamine,2-(2-methylphenoxy)acetic acid
  • 2-[bis(2-hydroxyethyl)amino]ethanol,2-(2-methylphenoxy)acetic acid
  • (4-Chloro-2-methylphenoxy)acetic Acid
  • (4-Fluoro-2-methylphenoxy)acetic acid
  • (4-Chloro-2-methylphenoxy)acetic acid allyl ester
  • 1-[2-(Dimethylamino)ethyl]-3-methylcyclobutane-1-carboxylic acid
  • 4-(2-Bromoethenyl)-2-tert-butyl-1,3-thiazole
  • 3-{[(Benzyloxy)carbonyl]amino}-4-(trifluoromethyl)benzoic acid
  • 3-(2-bromoethenyl)-1,4-dimethyl-1H-pyrazole
  • methyl 2-[(1E)-4-fluoro-2,3-dihydro-1H-inden-1-ylidene]acetate
  • 2-{2-[4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)oxan-3-yl]-N-methylacetamido}butanoic acid
  • 2-(5-Bromo-2-chlorophenyl)-1-methylpiperazine
  • 1-(6-Bromo-3-chloro-2-fluorophenyl)ethane-1,2-diol
  • methyl (3R)-3-(5-chloro-2-hydroxyphenyl)-3-hydroxypropanoate
  • 1-[3-(3-bromophenyl)propyl]-N-methylcyclopropan-1-amine
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