(2-Methoxyphenoxy)acetic acid

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Names

[ CAS No. ]:
1878-85-9

[ Name ]:
(2-Methoxyphenoxy)acetic acid

[Synonym ]:
Acetic acid, 2-(2-methoxyphenoxy)-
O-(2-Methoxy-phenyl)-glykolsaeure
(2-Methoxyphenoxy)acetic acid
MFCD00014352
Acetic acid,(o-methoxyphenoxy)
(2-Methoxy-phenoxy)-essigsaeure
EINECS 217-526-3
(o-Methoxyphenoxy)acetic acid
Acetic acid,(2-methoxyphenoxy)
2-methoxyphenoxyacetic acid
Guaiacoxyacetic acid

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
303.0±17.0 °C at 760 mmHg

[ Melting Point ]:
123-126 °C(lit.)

[ Molecular Formula ]:
C9H10O4

[ Molecular Weight ]:
182.173

[ Flash Point ]:
120.9±14.4 °C

[ Exact Mass ]:
182.057907

[ PSA ]:
55.76000

[ LogP ]:
1.16

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.529

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
AI8930700
CHEMICAL NAME :
Acetic acid, (o-methoxyphenoxy)-
CAS REGISTRY NUMBER :
1878-85-9
BEILSTEIN REFERENCE NO. :
1874501
LAST UPDATED :
199612
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C9-H10-O4
MOLECULAR WEIGHT :
182.19

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
386 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TSPMA6 Travaux de la Societe de Pharmacie de Montpellier. (Soc. de Pharmacie de Montpellier, Faculte de Pharmacie de Montpellier, Ave. Ch.-Flahault, 34060 Montpellier, France) V.1- 1942- Volume(issue)/page/year: 34,121,1974

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H315-H319

[ Precautionary Statements ]:
P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
AI8930700

[ HS Code ]:
2918990090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Ethyl (2-methoxyphenoxy)acetate
  • Guaiacol
  • Chloroacetic acid
  • Sodium chloroacetate
  • methyl chloroacetate
  • 4-(Benzyloxy)-3-methoxybenzaldehyde
  • sodium 2-methoxyphenolate

DownStream

  • 4,6-dichloro-5-(2-Methoxyphenoxy)-2-(pyridin-4-yl)pyrimidine
  • 2-(2-methoxyphenoxy)ethanol
  • Guaiacol
  • Carbon dioxide
  • carbon monoxide
  • 2-(2-methoxyphenoxy)-1-[4-[2-(2-methoxyphenoxy)acetyl]piperazin-1-yl]ethanone
  • 7-Methoxy-1-benzofuran-3(2H)-one
  • (2-METHOXYBIPHENYL-3-YL)-METHANOL
  • Ethyl (2-methoxyphenoxy)acetate
  • N-[2-(2,6-dimethoxyphenoxy)ethyl]-2-(2-methoxyphenoxy)ethanamine

Customs

[ HS Code ]: 2918990090

[ Summary ]:
2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

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Related Compounds

  • 2,2-bis(2-methoxyphenoxy)acetic acid
  • calcium,2-(2-methoxyphenoxy)acetic acid
  • (4-chloro-2-methoxyphenoxy)acetic acid tert-butyl ester
  • [4-(Hydroxymethyl)-2-methoxyphenoxy]acetic acid
  • 2-(4-FORMYL-2-METHOXYPHENOXY) ACETIC ACID, N-(2-CHLOROPHENYL)AMIDE
  • 2-(4-FORMYL-2-METHOXYPHENOXY) ACETIC ACID, N-(4-ETHOXYPHENYL) AMIDE
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide
  • N-[3-(Aminooxy)propyl]-N-butyl-1-butanamine