Isopropyllithium

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Names

[ CAS No. ]:
1888-75-1

[ Name ]:
Isopropyllithium

[Synonym ]:
Lithium Propane
Isopropyllithium solution
ISOPROPYLLITHIUM
EINECS 217-561-4
i-propyllithium
lithium propan-2-ide
MFCD02093613
propen-2-yl lithium
lithium,(1-methylethyl)

Chemical & Physical Properties

[ Density]:
0.632 g/mL at 25ºC

[ Boiling Point ]:
35-36ºC

[ Molecular Formula ]:
C3H7Li

[ Molecular Weight ]:
50.02870

[ Flash Point ]:
31 °F

[ Exact Mass ]:
50.07080

[ LogP ]:
1.36400

[ Storage condition ]:
2~8℃

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS07, GHS08, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H224-H304-H315-H318-H336-H411

[ Precautionary Statements ]:
P210-P261-P273-P280-P301 + P310-P305 + P351 + P338

[ Hazard Codes ]:
F+: Highly flammable;C: Corrosive;

[ Risk Phrases ]:
R12

[ Safety Phrases ]:
16-33-36/37/39-45

[ RIDADR ]:
UN 2924 3/PG 1

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2-Chloropropane
  • Bromo(isopropyl)magnesium

DownStream

  • 2,3,4-Trimethyl-2-pentene
  • 1,3-dimethyl-2-propan-2-ylbenzene
  • 4-Bromo-2-isopropylthiazole
  • anisole, p-isopropyl-
  • diethoxy-di(propan-2-yl)silane
  • Boranamine, N,N-dimethyl-1,1-bis(1-methylethyl)
  • tris(1-methylethyl)-Borane
  • tris(dimethylamino)borane
  • 3-Methyl-2-butanone

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Organolithium-induced alkylative ring opening of aziridines: synthesis of unsaturated amino alcohols and ethers.

J. Org. Chem. 71 , 8510, (2006)

Organolithium-induced alkylative ring opening of N-sulfonyl-protected aziridinyl ethers is described. The reactions were efficiently carried out with a variety of organolithiums, providing a promising...


More Articles

Related Compounds

  • Isopropyllithium
  • tert-butyl N-[1-(1,2-dihydroxyethyl)cyclopentyl]carbamate
  • tert-butyl N-[2-(aminomethyl)-3-hydroxypropyl]-N-(propan-2-yl)carbamate
  • 5-(3-methanesulfonylphenyl)-1H-imidazol-2-amine
  • 2-(2-Isocyanatopropan-2-yl)-1,3-dimethoxy-5-methylbenzene
  • 4-Amino-4-(2-bromo-6-fluorophenyl)cyclohexan-1-ol
  • Methyl 5-(2-amino-1,1-difluoroethyl)-2-methylfuran-3-carboxylate
  • [3,3-Difluoro-1-(4,5,6,7-tetrahydro-1-benzothiophen-2-yl)cyclobutyl]methanamine
  • tert-butyl N-[2-(2-cyclopropylphenyl)-1-oxopropan-2-yl]-N-methylcarbamate
  • 2-[4-(Difluoromethoxy)-2-fluorophenyl]-2-methylpropanoic acid
  • 2-fluoro-1-[4-(1H-pyrazol-1-yl)phenyl]ethan-1-ol
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