Diisopropylcarbamic chloride

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Names

[ CAS No. ]:
19009-39-3

[ Name ]:
Diisopropylcarbamic chloride

[Synonym ]:
Diisopropylcarbamicchloride
Carbamic chloride, bis(1-methylethyl)-
(i-Pr)2NCOCl
diisopropylcarbamoylchloride
Diisopropylcarbamoyl Chloride
Diisopropylcarbamic chloride
EINECS 242-743-5
diisopropylcarbamyl chloride
diisopropylcarbamic acid chloride
diisopropyl carbamoyl chloride
MFCD00015013
N,N-Diisopropylcarbamoyl chloride

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
204.3±0.0 °C at 760 mmHg

[ Melting Point ]:
57-59ºC(lit.)

[ Molecular Formula ]:
C7H14ClNO

[ Molecular Weight ]:
163.645

[ Flash Point ]:
82.4±18.7 °C

[ Exact Mass ]:
163.076385

[ PSA ]:
20.31000

[ LogP ]:
2.00

[ Appearance of Characters ]:
Crystalline Powder or To Low Melting Solid | Colorless to pale yellow or white to pale yellow

[ Vapour Pressure ]:
0.3±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.448

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C

[ Risk Phrases ]:
34

[ Safety Phrases ]:
26-36/37/39-45

[ RIDADR ]:
UN 3261 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ HS Code ]:
2903199000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • phosgene
  • Diisopropylamine
  • Disulfide, bis(diisopropylthiocarbamoyl) (8CI)
  • Triphosgene
  • N,N-DIISOPROPYL ETHYL CARBAMATE
  • 1Y1&NVHY1&1
  • Diphosgene

DownStream

  • 3-phenylpropyl N,N-di(propan-2-yl)carbamate
  • N,N-DIISOPROPYL ETHYL CARBAMATE
  • benzyl N,N-di(propan-2-yl)carbamate
  • 1-hydroxy-N,N-di(propan-2-yl)cyclohexane-1-carboxamide
  • but-2-enyl N,N-di(propan-2-yl)carbamate
  • cyclopenten-1-ylmethyl N,N-di(propan-2-yl)carbamate
  • S-methyl N,N-di(propan-2-yl)carbamothioate
  • S-cyclohex-2-en-1-yl N,N-di(propan-2-yl)carbamothioate
  • S-propyl N,N-di(propan-2-yl)carbamothioate

Customs

[ HS Code ]: 2903199000

[ Summary ]:
2903199000 other saturated chlorinated derivatives of acyclic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Articles

Stereoselective Intermolecular Carbolithiation of Open-Chain and Cyclic 1-Aryl-1-alkenyl N,N-Diisopropylcarbamates Coupled with Electrophilic Substitution. Observation of p-Carboxylation in a Benzyllithium Derivative. Peters JG, et al.

Synthesis 03 , 0381-292, (2002)

Asymmetric ?-Deprotonation and Substitution Reactions of (Z)-1, 3-Diphenyl-1-propenyl N, N-Diisopropylcarbamate. Reuber J, et al.

European J. Org. Chem. 14 , 3017-25, (2005)

The total synthesis of (-)-aplysin via a lithiation-borylation-propenylation sequence. Fletcher CJ, et al.

Tetrahedron 68(23) , 7598-7604, (2012)


More Articles

Related Compounds

  • diisopropylcarbamic acid (E)-hex-1-enyl ester
  • Strontium chloride-Sr82
  • calcium,chloride,hydroxide
  • sulfuryl chloride fluoride
  • Benzoyl chloride, 2-hydroxy-3-methoxy- (9CI)
  • dodecanoyl chloride,hydrofluoride
  • Sodium 4-(methoxycarbonyl)pyridine-3-sulfinate
  • 2-(4-Pentylphenyl)thiophene
  • 3-[Tert-butyl(dimethyl)silyl]oxypropanehydrazide
  • 2-Methylthiazolo[4,5-d]pyrimidin-7(6H)-one
  • 5-Acetyl-2-(4-bromopyrazol-1-yl)benzonitrile
  • 4,4'-Dichlorobiphenyl-d8
  • 2-{Bicyclo[1.1.1]pentan-1-yl}-2-methylpropanal
  • 5-(2-Chlorophenyl)-2-cyclopropyl-4-pyrimidinecarboxaldehyde
  • Bicyclo[3.2.0]heptane-6-carbaldehyde
  • Cyclopentyl-(4-piperazin-1-ylpiperidin-1-yl)methanone
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