Tosyl cyanide

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Names

[ CAS No. ]:
19158-51-1

[ Name ]:
Tosyl cyanide

[Synonym ]:
p-tosyl cyanide
MFCD00009977
p-Tolylsulfonyl cyanide
4-tolylsulfonylcyanide
tosyl cyanide
p-toluenesulphonyl cyanide
4-Methylbenzenesulfonyl cyanide
p-Toluenesulfonyl cyanide
Benzenesulfonyl cyanide, 4-methyl-
4-methylbenzolsulfonylcyanid
EINECS 242-849-1
Tosylcyanide

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
289.8±0.0 °C at 760 mmHg

[ Melting Point ]:
47-50 °C(lit.)

[ Molecular Formula ]:
C8H7NO2S

[ Molecular Weight ]:
181.212

[ Flash Point ]:
125.5±21.5 °C

[ Exact Mass ]:
181.019745

[ PSA ]:
66.31000

[ LogP ]:
1.28

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.548

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H312 + H332-H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R20/21;R34

[ Safety Phrases ]:
S26-S27-S28-S36/37/39-S45

[ RIDADR ]:
UN 3261 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
2926909090

Precursor & DownStream

Precursor

  • Sodium toluene-4-sulphinate
  • Cyanogen chloride

DownStream

  • 2-(p-tolylsulphonylmethyl)hexanenitrile
  • 2-butyl-4-[(4-methylphenyl)sulfonylmethyl]octanenitrile
  • 2-Bromo-5-cyano-3-picoline
  • 2-Azabicyclo[2.2.1]hept-5-en-3-one
  • 2-furoylacetonitrile
  • 2-(4-(tert-Butyl)phenyl)acetonitrile
  • 2-Bromothiophene-3-carbonitrile
  • 3-Bromo-2-thiophenecarbonitrile
  • Bis(benzo[d]thiazol-2-yl)methanone
  • BENZO[D]THIAZOLE-2-CARBONITRILE

Customs

[ HS Code ]: 2926909090

[ Summary ]:
HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

2-azabicyclo[2.2.2]octa-3,5-dione via a nitrile Diels-Alder reaction.

J. Org. Chem. 68(21) , 8256-7, (2003)

The hetero-Diels-Alder reaction of an electron-deficient nitrile, p-toluenesulfonyl cyanide, with the silyl enol ether of cyclohexenone produced a hydrolytically sensitive [4 + 2] adduct in good yield...

Radical-mediated alkenylation, alkynylation, methanimination, and cyanation of B-alkylcatecholboranes.

Angew. Chem. Int. Ed. Engl. 45 , 5847, (2006)

Synthesis , 2551, (2006)


More Articles

Related Compounds

  • 4-(5-amino-1-methyl-1H-1,2,4-triazol-3-yl)pyridin-2-amine dihydrochloride
  • (2S,5S)-5-(4-methoxyphenyl)pyrrolidine-2-carboxylic acid hydrochloride
  • 3-(2-fluorophenyl)-1H-pyrazol-4-amine dihydrochloride
  • methyl 2-amino-2-(1-phenyl-1H-pyrazol-4-yl)acetate hydrochloride
  • oxalic acid; {1-[(4-fluorophenyl)methyl]-1H-1,2,3-triazol-4-yl}methanamine
  • N-(Azepan-4-yl)-N-(pyrimidin-5-ylmethyl)acetamidedihydrochloride
  • 6lambda6-Thia-3-azabicyclo[3.2.1]octane-6,6-dione hydrochloride
  • 2-Fluorobenzohydrazide hydrochloride
  • 4-(3-methyl-1H-pyrazol-1-yl)piperidine hydrochloride
  • 4-Fluoro-4-phenylazepane, oxalic acid
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