N-Hydroxy-4-methylbenzenecarboximidamide

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Names

[ CAS No. ]:
19227-13-5

[ Name ]:
N-Hydroxy-4-methylbenzenecarboximidamide

[Synonym ]:
N-Hydroxy-4-methylbenzenecarboximidamide
N'-Hydroxy-4-methylbenzimidamide
N-hydroxy-4-methylbenzamidine
4-Methylbenzamidoxime
PARA-TOLUAMIDOXIME
4-methylphenyl amidoxime
4-Methylbenzenecarboxamideoxime
oxime of 4-methyl benzaldehyde
Benzenecarboximidamide, N-hydroxy-4-methyl-
MFCD00019952
p-toluamidoxime
p-tolamidoxime
P-TOLUAMIDEOXIME

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
314.4±35.0 °C at 760 mmHg

[ Melting Point ]:
140-145 °C(lit.)

[ Molecular Formula ]:
C₈H₁₀N₂O

[ Molecular Weight ]:
150.178

[ Flash Point ]:
144.0±25.9 °C

[ Exact Mass ]:
150.079315

[ PSA ]:
58.61000

[ LogP ]:
1.61

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.564

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: XS4870000

CHEMICAL NAME :: p-Toluamidoxime

CAS REGISTRY NUMBER :: 19227-13-5

LAST UPDATED :: 199707

DATA ITEMS CITED :: 1

MOLECULAR FORMULA :: C8-H10-N2-O

MOLECULAR WEIGHT :: 150.20

WISWESSER LINE NOTATION :: QNU1MR D1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 180 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#04182

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
XS4870000

[ HS Code ]:
2925290090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

p-Tolunitrile
Triethylamine
Acetonitrile

DownStream

(4-methylphenyl)cyanamide
5-Chloromethyl-3-p-tolyl-[1,2,4]oxadiazole
3-[3-(4-methylphenyl)-1,2,4-oxadiazol-5-yl]propanoic acid
3-(4-methylphenyl)-5-[2-[3-(4-methylphenyl)-1,2,4-oxadiazol-5-yl]ethyl]-1,2,4-oxadiazole
4-Methylbenzenecarboximidamide
N-cyclohexyl-3-(4-methylphenyl)-1,2,4-oxadiazol-5-amine
1,3-Dicyclohexylurea
5-Methyl-3-p-tolyl-1,2,4-oxadiazole

Customs

[ HS Code ]: 2925290090

[ Summary ]:
2925290090 other imines and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

4-Methylbenzamide oxime. Wang HB, et al.

Acta Crystallogr. Sect. E Struct. Rep. Online 62(7) , o3105-o3106, (2006)

Acid hydrolysis of 3-aryl-5-trinitromethyl-1,2,4-oxadiazoles. Tyrkov AG.

Russ. J. Org. Chem. 37(9) , 1353-1354, (2001)

N-hydroxy-4-methylbenzenecarboximidamide
N-Hydroxy-4-methylbenzenecarboximidamide
N-Hydroxy-4-methylbenzenecarboximidamide
3-Fluoro-N-hydroxy-4-methylbenzenecarboximidamide
N-hydroxy-4-methyl-3-oxo-N-phenylpentanamide
N-hydroxy-4-methyl-2-oxochromene-3-carboxamide
2-chloro-N-[(3,5-dimethyl-1-phenyl-1H-pyrazol-4-yl)methyl]acetamide
2-Thiophenemethanol, 2-formate
Ethyl 2-amino-4-thiazolebutanoate
2-Ethyl-3-hydroxy-1-propan-2-ylpyridin-4-one
4-[4-(2-Phenylethenesulfonyl)piperazine-1-carbonyl]-1,2-dihydroquinolin-2-one
2-((1-(3-Methoxyphenyl)-5-phenyl-1H-imidazol-2-yl)thio)acetonitrile
[(1-cyanocyclohexyl)carbamoyl]methyl 4-(1H-pyrrol-1-yl)benzoate
N-(triphenylphosphoranylidene)methanamine hydrobromide
(S)-1-((1-Benzylpyrrolidin-2-yl)methyl)-2-methyl-1H-imidazole
Notoamide A

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