Tetrabutylammonium perchlorate

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Names

[ CAS No. ]:
1923-70-2

[ Name ]:
Tetrabutylammonium perchlorate

[Synonym ]:
Bu4N(1+)*ClO4(1-)
tetrabutylazanium perchlorate
N,N,N-Tributyl-1-butanaminium perchlorate
tetra-n-butylammonium perchlorate
Tetrabutylammonium Perchlorate
tetrabutylammoniumperchlorate
tetra(n-butyl)ammonium perchlorate
1-Butanaminium, N,N,N-tributyl-, perchlorate
MFCD00038722
EINECS 217-655-5
n,n,n-tributylbutan-1-aminium perchlorate
TBA perchlorate
Tetrabutylammonium Perchlorat
[(n-Bu)4N]ClO4
Tetrabutyl ammonium perchlorate

Chemical & Physical Properties

[ Melting Point ]:
211-215 °C

[ Molecular Formula ]:
C16H36ClNO4

[ Molecular Weight ]:
341.914

[ Exact Mass ]:
341.233276

[ PSA ]:
74.27000

[ LogP ]:
5.21790

[ Stability ]:
Stable. Strong oxidizer - contact with combustible material may cause fire. Incompatible with strong reducing agents, combustible materials. Do not heat.

[ Water Solubility ]:
acetonitrile: 0.1 g/mL, clear, colorless

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS03, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H272-H315-H319-H335

[ Precautionary Statements ]:
P220-P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
O:Oxidizingagent;Xi:Irritant;

[ Risk Phrases ]:
R36/37/38;R5;R8

[ Safety Phrases ]:
S17-S26-S36-S36/37/39

[ RIDADR ]:
UN 1479 5.1/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
5.1

[ HS Code ]:
2923900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Tetrabutylammonium bromide
  • Tetrabutylammonium iodide
  • Tetrabutylammonium hydroxide
  • N,N-diethylethanamine,perchloric acid
  • Tetrabutylammonium chloride
  • 1-Butanaminium, N,N,N-tributyl-, salt with 2,4,6-trinitrophenol (1:1) (9CI)

DownStream

  • Tetrabutylammonium iodide
  • N,N-diethylethanamine,perchloric acid
  • Tetrabutylammonium bromide
  • Tetrabutylammonium chloride
  • 1-Butanaminium, N,N,N-tributyl-, salt with 2,4,6-trinitrophenol (1:1) (9CI)
  • Chlorine dioxide
  • Tetrabutylammonium cyanide
  • Chlorotriphenylgermane
  • hexaphenyldigermoxane
  • 1-Butene

Customs

[ HS Code ]: 2923900090

[ Summary ]:
2923900090 other quaternary ammonium salts and hydroxides。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

High-turnover hypoiodite catalysis for asymmetric synthesis of tocopherols.

Science 345(6194) , 291-4, (2014)

The diverse biological activities of tocopherols and their analogs have inspired considerable interest in the development of routes for their efficient asymmetric synthesis. Here, we report that chira...

Tandem cyclization of α-cyano α-alkynyl aryl ketones induced by tert-butyl hydroperoxide and tetrabutylammonium iodide.

Org. Lett. 14(23) , 6024-7, (2012)

The radical cascade protocol of the α-cyano α-TMS/aryl-capped alkynyl aryl ketones promoted by tert-butyl hydroperoxide under catalysis with tetrabutylammonium iodide in refluxing benzene has been dev...

Synthesis, crystal structure and anaerobic DNA photocleavage of ruthenium complexes [Ru(tpy)(dpoq)Cl](+) and [Ru(tpy)(dpoq)CH3CN](2.).

J. Inorg. Biochem. 149 , 80-7, (2015)

Two new Ru(II) complexes [Ru(tpy)(dpoq)Cl](+)1 and [Ru(tpy)(dpoq)CH3CN](2+)2 (tpy = 2,2':6',2''-terpyridine; dpoq = dipyrido[1,2,5]oxadiazolo[3,4-b]quinoxaline) have been synthesized and characterized...


More Articles

Related Compounds

  • Tetrabutylammonium fluorosulfate
  • Tetrabutylammonium phthalate
  • tetrabutylammonium, ethyl phosphonate
  • tetrabutylammonium hydrogen bifluoride
  • tetrabutylammonium bis-trifluoromethane&
  • Tetrabutylammonium Tetraphenylborate
  • dimethyl N-[(1,3-benzodioxol-5-ylmethyl)carbamoyl]-L-glutamate
  • 2-(Azetidin-3-yl)-5-ethyl-1,2,5-thiadiazolidine 1,1-dioxide
  • 3-(2-Phenylethyl)-6-(3,4,5-trimethoxyphenyl)[1,2,4]triazolo[3,4-b][1,3,4]thiadiazole
  • N-(2-(2-(2,5-dioxopyrrolidin-1-yl)ethoxy)ethyl)-4-phenyltetrahydro-2H-pyran-4-carboxamide
  • 6-[(3,4-Dichlorophenyl)methoxy]-2-(2-thienylmethylene)benzo[b]furan-3-one
  • N-(2-(2-(2,5-dioxopyrrolidin-1-yl)ethoxy)ethyl)-2-(4-(isopropylthio)phenyl)acetamide
  • (Z)-3-oxo-2-(thiophen-2-ylmethylene)-2,3-dihydrobenzofuran-6-yl 4-bromobenzenesulfonate
  • N-{2-[2-(2,5-dioxopyrrolidin-1-yl)ethoxy]ethyl}-4'-methyl-[1,1'-biphenyl]-4-carboxamide
  • 2-[(5Z)-5-(2-fluorobenzylidene)-2,4-dioxo-1,3-thiazolidin-3-yl]-N-(quinoxalin-6-yl)acetamide
  • 3-(2-bromophenyl)-N-(2-(2-(2,5-dioxopyrrolidin-1-yl)ethoxy)ethyl)propanamide
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