Bisdiphenylphosphinoparacyclophane

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Names

[ CAS No. ]:
192463-40-4

[ Name ]:
Bisdiphenylphosphinoparacyclophane

[Synonym ]:
(S)-Phanephos
<2.2>PHANEPHOS
(S)-Phanephos,ee
4-FLUOROBENZOYLACETONITRILE N-BOC-4-OXO-L-PROLINE
(S)-(+)-4,12-Bis(D
Bisdiphenylphosphinoparacyclophane
4,12-bis(diphenylphosphino)[2.2]paracyclophane
(S)-(+)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE
(S)-(+)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane,min.(S)-PHANEPHOS
(S)-(+)-4,12-BIS-(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE (S)-PHANEPHOS
(R)-PHANEPHOS

Chemical & Physical Properties

[ Melting Point ]:
222-225ºC

[ Molecular Formula ]:
C₄₀H₃₄P₂

[ Molecular Weight ]:
576.64500

[ Exact Mass ]:
576.21400

[ PSA ]:
27.18000

[ LogP ]:
7.08680

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
26-36/37/39

[ RIDADR ]:
NONH for all modes of transport

Articles

A catalyst for efficient and highly enantioselective hydrogenation of aromatic, heteroaromatic, and alpha,beta-unsaturated ketones

Org. Lett. 2 , 4173, (2000)

PhanePhos-ruthenium-diamine complexes catalyze the asymmetric hydrogenation of a wide range of aromatic, heteroaromatic, and alpha, beta-unsaturated ketones with high activity and excellent enantiosel...

J. Am. Chem. Soc. 119 , 6207, (1997)