9-bromofluorene

Suppliers

Names

[ CAS No. ]:
1940-57-4

[ Name ]:
9-bromofluorene

[Synonym ]:
9-bromofluorene
9-Fluorenyl Bromide
9-Bromo-9H-fluorene
EINECS 217-722-9
9H-Fluorene, 9-bromo-
9H-Fluorene,9-bromo
9-Brom-fluoren
FLUORENE,9-BROMO
9H-fluoren-9-yl bromide
MFCD00001133

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
327.9±31.0 °C at 760 mmHg

[ Melting Point ]:
101-104 °C(lit.)

[ Molecular Formula ]:
C13H9Br

[ Molecular Weight ]:
245.115

[ Flash Point ]:
129.6±14.5 °C

[ Exact Mass ]:
243.988754

[ LogP ]:
4.28

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.681

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
LL5890000
CHEMICAL NAME :
Fluorene, 9-bromo-
CAS REGISTRY NUMBER :
1940-57-4
BEILSTEIN REFERENCE NO. :
2047220
LAST UPDATED :
199612
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C13-H9-Br
MOLECULAR WEIGHT :
245.13
WISWESSER LINE NOTATION :
L B656 HHJ HE

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Human - man
REFERENCE :
BJDEAZ British Journal of Dermatology. (Blackwell Scientific Pub. Ltd., POB 88, Oxford, UK) V.63- 1951- Volume(issue)/page/year: 80,491,1968
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Human
REFERENCE :
CHINAG Chemistry and Industry (London). (Royal Soc. of Chemistry, Distribution Centre, Blackhorse Rd., Letchworth, Herts SG6 1HN, UK) V.1- 1923- Volume(issue)/page/year: (49),2080,1967 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
180 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#01610

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R34;R43

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 1759 8/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
LL5890000

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
2903999090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 9-fluorenol
  • 9H FLUORENE
  • 9H-Fluorene-9-carboxylic acid
  • Acetyl bromide
  • 9-Fluorenone
  • di-fluoren-9-yl ether
  • 9H-Fluorene, 9-chloro-
  • 9-fluorenyl acetate
  • 9H-Fluorene, 9-diazo-

DownStream

  • N,N-di(propan-2-yl)-9H-fluoren-9-amine
  • 9-Fluorenone
  • p-Anisic acid
  • 9-fluorenyl(4-methoxyphenyl)(nitro)acetonitrile
  • 9-prop-2-enoxy-9H-fluorene
  • 9-Mercaptofluorene
  • 9H FLUORENE
  • 9,9'-Bifluorene
  • [benzyl(methoxy)phosphoryl]methylbenzene

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Related Compounds

  • 9-phenyl-9-bromofluorene
  • 2-acetyl-9-bromofluorene
  • 2-benzoyl-9-bromofluorene
  • 2,7-Dichloro-9-bromofluorene
  • methyl 9-bromofluorene-9-carboxylate
  • 9-methyl-4-(1-methylindol-2-yl)carbazole
  • tert-butyl N-[1-(prop-2-en-1-yl)piperidin-4-yl]carbamate
  • (2s)-2-Amino-2-(5-bromo-2-methoxypyridin-3-yl)ethan-1-ol
  • (1R,2S)-1-Amino-1-(5-chloro-2-fluorophenyl)propan-2-OL
  • (S)-1-(2-Chloro-5-fluorophenyl)-2-methylpropan-1-amine
  • 1-Chloro-1-(3-(chloromethyl)-4-mercaptophenyl)propan-2-one
  • 1-(2-Chloro-6-(fluoromethyl)phenyl)propan-2-one
  • 8-Bromo-4-oxo-4H-pyrido[1,2-a]pyrimidine-3-carboxaldehyde
  • Tellurocyanic acid
  • Carbonic acid, triseleno-
  • (3R)-3-Amino-3-(2-bromo-4-chlorophenyl)propan-1-OL
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