Di(pyridin-2-yl)methanone

Suppliers

Names

[ CAS No. ]:
19437-26-4

[ Name ]:
Di(pyridin-2-yl)methanone

[Synonym ]:
di(pyridin-2-yl)methanone
MFCD00006288
pyridyl monoketone
Di-2-pyridinylmethanone
DI-2-PYRIDYL KETONE
Methanone, di-2-pyridinyl-
2,2'-Carbonyldipyridine
Dipyridin-2-ylmethanone
di(2-pyridyl)ketone
2,2'-Dipyridyl ketone
bis(2-pyridyl)ketone
EINECS 243-067-3

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
343.5±17.0 °C at 760 mmHg

[ Melting Point ]:
52-55 °C(lit.)

[ Molecular Formula ]:
C11H8N2O

[ Molecular Weight ]:
184.19

[ Flash Point ]:
165.7±27.4 °C

[ Exact Mass ]:
184.063660

[ PSA ]:
42.85000

[ LogP ]:
0.58

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.594

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2933399090

Synthetic Route

Precursor & DownStream

Precursor

  • 2-picoline
  • 1,2-dipyridin-2-ylethanone
  • alpha-pyridoin
  • 2-pyridyllithium
  • ETHYL METHOXY(METHYL)CARBAMATE
  • 1,1,2,2-tetrakis(pyridin-2-yl)ethane
  • Di-2-pyridylglyoxal
  • 2-Acetopyridine
  • 2-cyanopyridine
  • Ethyl 2-picolinate

DownStream

  • 3-pyridin-2-yltriazolo[1,5-a]pyridine
  • N-(dipyridin-2-ylmethylideneamino)benzamide
  • Methyl picolinate
  • DIPYRIDIN-2-YLMETHANE
  • Di-2-pyridinylmethanol
  • Methanone,di-2-pyridinyl-, oxime
  • 1-(dipyridin-2-ylmethylideneamino)-3-ethylthiourea
  • 1-(dipyridin-2-ylmethylideneamino)-3-phenylthiourea

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Nickel/lanthanide single-molecule magnets: {Ni(3)Ln} "stars" with a ligand derived from the metal-promoted reduction of di-2-pyridyl ketone under solvothermal conditions.

Inorg. Chem. 49(21) , 9737-9, (2010)

Unusual {Ni(II)(3)Ln(III)(μ-OR)(6)}(3+) complexes with a "star" topology have been prepared with ligands derived from the metal-promoted reduction of di-2-pyridyl ketone under solvothermal conditions;...

Heterocyclic dithiocarbazate iron chelators: Fe coordination chemistry and biological activity.

Dalton Trans. 41(21) , 6536-48, (2012)

The iron coordination and biological chemistry of a series of heterocyclic dithiocarbazate Schiff base ligands is reported with regard to their activity as Fe chelators for the treatment of Fe overloa...

Initial employment of di-2-pyridyl ketone as a route to nickel(II)/lanthanide(III) clusters: triangular Ni(2)Ln complexes.

Dalton Trans. 39(37) , 8603-5, (2010)

Using monoanionic forms of di-2-pyridyl ketone as the only primary ligand, triangular Ni(2)M (M = lanthanide, Y) complexes with interesting magnetic properties have been synthesized.


More Articles


Related Compounds

  • (dipyridin-2-ylmethylideneamino)thiourea
  • di(pyridin-2-yl) sulfite
  • (di-pyridin-2-yl-methyl)-pyridin-2-yl-amine
  • phenyl(pyridin-2-yl)methanone O-cinnamoyl oxime
  • phenyl(pyridin-2-yl)methanone O-picolinoyl oxime
  • phenyl(pyridin-2-yl)methanone O-pivaloyl oxime
  • 2,2-Difluoro-1-[2-(methylsulfanyl)ethyl]cyclopropan-1-amine
  • 3,3-Difluoro-2-(3-methyloxetan-3-yl)propan-1-amine
  • 1-(3-Ethyloxetan-3-yl)-4,4-difluorocyclohexan-1-amine
  • 10-[(2,2-Difluorocyclopropyl)methyl]-2-methyl-6-oxa-2,9-diazaspiro[4.5]decane
  • 2-[1-(2-Fluoro-4-methylphenyl)cyclopropyl]-2-methoxyacetic acid
  • 3-{5-Azaspiro[2.4]heptan-5-yl}-2,2-difluoropropanoic acid
  • 3-[2-Fluoro-3-(trifluoromethyl)phenyl]-2-hydroxy-3-methylbutanoic acid
  • 2,2-Difluoro-3-(pyrimidin-2-ylsulfanyl)propanoic acid
  • 8-Cyclopropyl-2-methyl-6-oxa-2,10-diazaspiro[4.5]decane
  • 11-(Propan-2-yl)-5-oxa-2,12-diazadispiro[3.2.3^{7}.2^{4}]dodecane
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