Dichloro(3-methyl-2-butenylidene)bis(tricyclohexylphosphine)ruthenium(II)

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Names

[ CAS No. ]:
194659-03-5

[ Name ]:
Dichloro(3-methyl-2-butenylidene)bis(tricyclohexylphosphine)ruthenium(II)

[Synonym ]:
RuCl2(=CHCH=CMe2)(PCy3)2
dichloro(3-methyl-1,2-butenylidene)bis(tricyclohexylphosphine)ruthenium(II)
Grubbs Catalyst 801
(CH3)2C=CHCH=Ru(PCy3)2Cl2
Bis(tricyclohexylphosphine)isopentenylidene ruthenium dichloride
MFCD04039970
Dichloro(3-methyl-2-buten-1-ylidene)ruthenium - tricyclohexylphosphine (1:2)
3-ME-2-BUTENYLIDENEBIS(TRICYCLOHEXYLPHOSPHINE)DICHLORORUTHE.
Dichloro(3-methyl-2-butenylidene)bis(tricyclohexylphosphine)ruthenium(II)
ruthenium(II) dichloro(3-methyl-1,2-butenylidene)bis(tricyclohexylphosphine)
Phosphine, tricyclohexyl-, compd. with dichloro(3-methyl-2-buten-1-ylidene)ruthenium (2:1)

Chemical & Physical Properties

[ Boiling Point ]:
383.4±0.0 °C at 760 mmHg

[ Melting Point ]:
160-165ºC(lit.)

[ Molecular Formula ]:
C₄₁H₇₄Cl₂P₂Ru

[ Molecular Weight ]:
800.950

[ Flash Point ]:
195.6±0.0 °C

[ Exact Mass ]:
800.369019

[ PSA ]:
27.18000

[ LogP ]:
7.00

[ Vapour Pressure ]:
0.0±0.0 mmHg at 25°C

[ Storage condition ]:
2-8°C

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H228

[ Precautionary Statements ]:
P210

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
F+

[ Safety Phrases ]:
22-24/25

[ RIDADR ]:
UN1325 - class 4.1 - PG 2 - Flammable solids, organic, n.o.s., HI: all

[ WGK Germany ]:
3

Articles

Schrodi, Y.; Pederson, R. L.

Aldrichimica Acta 40th ed.,, 45, (2007)

Vougioukalakis, G. C.; Grubbs, R. H.

Chem. Rev. 110th ed.,, 1746, (2010)

Grubbs, R. H.

Tetrahedron 60th ed.,, 7117, (2004)