Lithium azide

Suppliers

Names

[ CAS No. ]:
19597-69-4

[ Name ]:
Lithium azide

[Synonym ]:
Lithiumazid
Lithium triazide
EINECS 243-177-1
Lithium azide
lithim azide
lithium nitride
MFCD00041956
Lthium triazide

Chemical & Physical Properties

[ Density]:
1.088 g/mL at 25 °C

[ Boiling Point ]:
103 °C

[ Melting Point ]:
decomposes at 115–298℃ [CRC10]

[ Molecular Formula ]:
LiN3

[ Molecular Weight ]:
48.96110

[ Exact Mass ]:
49.02520

[ PSA ]:
49.75000

[ LogP ]:
0.21376

[ Appearance of Characters ]:
Liquid | Clear colorless

Safety Information

[ Symbol ]:

GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H300 + H330-H311

[ Supplemental HS ]:
Contact with acids liberates very toxic gas.

[ Precautionary Statements ]:
P260-P264-P280-P284-P301 + P310-P310

[ Hazard Codes ]:
T+: Very toxic;

[ Risk Phrases ]:
26/27/28-32

[ Safety Phrases ]:
S23;S45;S36/S37/S39

[ RIDADR ]:
UN 3287 6.1/PG 2

[ Hazard Class ]:
4.1

Synthetic Route

Precursor & DownStream

Precursor

  • Ammonia
  • Lithium
  • nitrous oxide
  • Nitrogen

DownStream

  • Phosphonitrilic chloride trimer
  • 2l5,4l5,6l5,8l5-1,3,5,7,2,4,6,8-Tetrazatetraphosphocine,2,2,4,4,6,6,8,8-octachloro-
  • Lithium
  • Ammonia

Related Compounds

  • Lithium azide
  • lithium nitrite monohydrate
  • lithium,1,3,5-trimethylcyclopenta-1,3-diene
  • lithium,trimethyl(prop-2-enyl)silane
  • lithium pyruvate
  • lithium,1-trityl-2H-imidazol-2-ide