o-Bromo(methylthio)benzene

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Names

[ CAS No. ]:
19614-16-5

[ Name ]:
o-Bromo(methylthio)benzene

[Synonym ]:
1-Bromo-2-(methylsulfanyl)benzene
2-(methylthio)bromo benzene
1-Bromo-2-(methylthio)benzene
EINECS 243-183-4
Benzene, 1-bromo-2-(methylthio)-
2-Br-phenyl methyl sulfide
2-BroMothioanisole
1-methylthio-2-bromobenzene
2-Bromophenyl methyl sulphide
o-Bromothioanisole
2-Bromo Thioanisole
2-Bromophenyl methyl sulfide
o-Bromo(methylthio)benzene
MFCD00000066

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
258.8±0.0 °C at 760 mmHg

[ Melting Point ]:
-24 °C

[ Molecular Formula ]:
C₇H₇BrS

[ Molecular Weight ]:
203.100

[ Flash Point ]:
95.0±22.6 °C

[ Exact Mass ]:
201.945175

[ PSA ]:
25.30000

[ LogP ]:
3.64

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.624

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R22;R36/37/38

[ Safety Phrases ]:
S37/39-S26

[ RIDADR ]:
UN 3334

[ HS Code ]:
2930909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

2-Bromothiophenol
methyl iodide
CYCLOHEXYL METHYL SULFIDE
1,2-Dibromobenzene
2-bromobenzenediazonium hydrogensulfate
N-Acetyl-S-(4-bromophenyl)cysteine
Dimethyl sulfate
1-Bromo-2-fluorobenzene

DownStream

2-BROMOPHENYL METHYL SULFONE
2-Bromophenyl Methyl Sulfoxide
3-(Methylsulfonyl)aniline
Naphthalene
Thioanisole
Anisole
dimethoxyanisole
2-(methylthio)benzonitrile
2-Fluoro thioanisole
2-(Methylsulfanyl)benzoic acid

Customs

[ HS Code ]: 2930909090

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Sulfonium boranes for the selective capture of cyanide ions in water.

Angew. Chem. Int. Ed. Engl. 48(27) , 4957-60, (2009)

Going fishing! The sulfonium borane [1](+) complexes cyanide in pure water at the maximum allowable concentration of 50 ppb recommended by the European Union. The high cyanide ion affinity displayed b...

Isolation of S-(bromophenyl)cysteine isomers from liver proteins of bromobenzene-treated rats.

Chem. Res. Toxicol. 4(1) , 17-20, (1991)

The thioether-methyleneborane (PhSCH2B (C6F5) 2) 2: synthesis and reactivity with donors and alkynes. Tanur CA and Stephan DW.

Organometallics 30(13) , 3652-57, (2011)