2-(Benzyloxy)acetyl chloride

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Names

[ CAS No. ]:
19810-31-2

[ Name ]:
2-(Benzyloxy)acetyl chloride

[Synonym ]:
2-(benzyloxy)ethanoyl chloride
2-(phenylmethoxy)acetyl chloride
Benzyloxyacetylchloride
benzyloxyacetic acid chloride
MFCD00010768
(Benzyloxy)acetyl chloride
2-(benzyloxy)acetyl chloride
ACETYL CHLORIDE,(PHENYLMETHOXY)
Benzyloxyacetyl Chloride
benzyloxyacetic chloride
Acetyl chloride, 2-(phenylmethoxy)-

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
282.3±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C₉H₉ClO₂

[ Molecular Weight ]:
184.620

[ Flash Point ]:
96.4±20.8 °C

[ Exact Mass ]:
184.029114

[ PSA ]:
26.30000

[ LogP ]:
2.51

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.525

[ Storage condition ]:
−20°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R14;R34

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 3265 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
2918990090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

(Benzyloxy)acetic acid
Benzyl alcohol
Oxalyl chloride
Benzyloxyacetic acid ethyl ester

DownStream

S-phenyl 2-phenylmethoxyethanethioate
(S)-(+)-4-Benzyl-3-benzyloxyacetyl-2-oxazolidinone
2-(Benzyloxy)acetaldehyde
(2E,4R,5R,6R,7E)-6,10-dimethyl-5-phenylmethoxyundeca-2,7-dien-4-ol
[(Z)-dec-2-en-4-yl] 2-phenylmethoxyacetate
methyl (E,2R,3R)-3-methyl-2-phenylmethoxyundec-4-enoate
[(Z)-6-methylhept-2-en-4-yl] 2-phenylmethoxyacetate
methyl (2R,3S,4E,6R,7S,8E)-3,7,11-trimethyl-2,6-bis(phenylmethoxy)dodeca-4,8-dienoate
(2E,4R,5R,6R,7E)-6-methyl-5-phenylmethoxytetradeca-2,7-dien-4-ol
Methyl 2-(benzyloxy)acetate

Customs

[ HS Code ]: 2918990090

[ Summary ]:
2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Asymmetric synthesis of 1-(2- and 3-haloalkyl)azetidin-2-ones as precursors for novel piperazine, morpholine, and 1,4-diazepane annulated beta-lactams.

J. Org. Chem. 71 , 7083, (2006)

A high-yielding, asymmetric synthesis of novel 4-formyl-1-(2- and 3-haloalkyl)azetidin-2-ones was developed as valuable starting materials for the synthesis of different enantiomerically enriched bicy...

Stereoselective synthesis of (S)-3-(methylamino)-3-((R)-pyrrolidin-3-yl)propanenitrile.

J. Org. Chem. 77(10) , 4732-9, (2012)

(S)-3-(methylamino)-3-((R)-pyrrolidin-3-yl)propanenitrile (1) is a key intermediate in the preparation of PF-00951966, (1) a fluoroquinolone antibiotic for use against key pathogens causing community-...

J. Org. Chem. 59 , 932, (1994)

2-acetyl chloride
1H-Pyrrole-2-acetyl chloride, alpha-oxo- (9CI)
2H-Isoindole-2-acetyl chloride, 1,3-dihydro-1,3-dioxo-α-propyl-, (αS)
1H-Pyrrole-2-acetyl chloride, 5-methyl-alpha-oxo- (9CI)
METHYL 2-(2-(2-(BENZYLOXY)ACETYL)PHENYL)ACETATE
(4R,5S)-3-(2-(benzyloxy) acetyl)-4-methyl-5-phenyloxazolidin-2-one
3-(carboxymethyl)-1-methyl-2-phenyl-pyrrolidine-3-carboxylic acid
4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
Bietamiverine, (R)-
2-Cyclopropoxy-N1,N3-dimethylisophthalamide
(4-Methyl-tetrahydro-furan-2-yl)-methanol
N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde