2-(Benzyloxy)aniline

Names

[ CAS No. ]:
20012-63-9

[ Name ]:
2-(Benzyloxy)aniline

[Synonym ]:
2-Aminophenyl benzyl ether
MFCD03093873
2-Benzyloxyaniline
benzyl 2-Aminophenyl Ether
Benzenamine, 2-(phenylmethoxy)-
O-benzyloxy-2-aminophenol
2-(Benzyloxy)aniline

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
345.8±17.0 °C at 760 mmHg

[ Melting Point ]:
35-39 °C(lit.)

[ Molecular Formula ]:
C₁₃H₁₃NO

[ Molecular Weight ]:
199.248

[ Flash Point ]:
170.7±14.2 °C

[ Exact Mass ]:
199.099716

[ PSA ]:
35.25000

[ LogP ]:
2.75

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.616

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2922299090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2922299090

[ Summary ]:
2922299090. other amino-naphthols and other amino-phenols, other than those containing more than one kind of oxygen function, their ethers and esters; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

A novel aryl-hydrazide from the marine lichen Lichina pygmaea: isolation, synthesis of derivatives, and cytotoxicity assays.

Bioorg. Med. Chem. Lett. 20(15) , 4582-6, (2010)

A new aryl-hydrazide l-glutamic acid derivative, pygmeine (3), was isolated from a methanolic extract of Lichina pygmaea, a marine lichen. Synthetic derivatives obtained via a two-step coupling of l-g...

Selective alkylation of aminophenols. Wang R and Xu J.

ARKIVOC , 293-299, (2010)

Structural study of four benzyloxybenzoic acids and benzyloxyanilines using X-ray powder diffraction: interplay of strong and weak intermolecular interactions. Chattopadhyay B, et al.

CrystEngComm 15(6) , 1077-85, (2013)

2-(BENZYLOXY)-5-(TRIFLUOROMETHYL)ANILINE
2-benzyloxy-4-methoxy-aniline, hydrochloride
2-benzyloxy-3-methoxy-4-nitro-N-(p-toluenesulfonyl)aniline
2-(Benzyloxy)-N-{2-[4-(tert-butyl)phenoxy]-propyl}aniline
2-(Benzyloxy)-N-{2-[2,4-di(tert-butyl)phenoxy]-ethyl}aniline
2-benzyloxy-5-dibromo-3-[(N-phenyl)aminomethyl]pyridine
N-{2-hydroxy-2-[(thiophen-3-yl)methyl]propyl}-4-methoxy-2-methylbenzene-1-sulfonamide
N-(2-methoxyethyl)-1-[5-(3-methyl-1,2,4-oxadiazol-5-yl)pyridin-2-yl]-N-[(thiophen-2-yl)methyl]piperidine-3-carboxamide
1-[2-hydroxy-2-(thiophen-3-yl)ethyl]-N-[2-(thiophen-2-yl)ethyl]-1H-1,2,3-triazole-4-carboxamide
1-(7-Bromobenzo[D]thiazol-2-YL)ethanone
2-Amino-N-(3-chloro-4-fluorophenyl)-3-nitroisonicotinamide
1-Amino-1-(4-chloro-2,6-difluorophenyl)acetone
(6-Methylspiro[2.5]octan-6-yl)methanamine
2-(4-methoxybenzyl)-5-bromo-7-iodo-2H-indazole
7-bromo-5-butyl-1H-benzimidazole
1-(4-methoxybenzyl)-5-bromo-7-iodo-1H-indazole

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