2-(Benzyloxy)aniline

Names

[ CAS No. ]:
20012-63-9

[ Name ]:
2-(Benzyloxy)aniline

[Synonym ]:
2-Aminophenyl benzyl ether
MFCD03093873
2-Benzyloxyaniline
benzyl 2-Aminophenyl Ether
Benzenamine, 2-(phenylmethoxy)-
O-benzyloxy-2-aminophenol
2-(Benzyloxy)aniline

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
345.8±17.0 °C at 760 mmHg

[ Melting Point ]:
35-39 °C(lit.)

[ Molecular Formula ]:
C₁₃H₁₃NO

[ Molecular Weight ]:
199.248

[ Flash Point ]:
170.7±14.2 °C

[ Exact Mass ]:
199.099716

[ PSA ]:
35.25000

[ LogP ]:
2.75

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.616

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2922299090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2922299090

[ Summary ]:
2922299090. other amino-naphthols and other amino-phenols, other than those containing more than one kind of oxygen function, their ethers and esters; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

A novel aryl-hydrazide from the marine lichen Lichina pygmaea: isolation, synthesis of derivatives, and cytotoxicity assays.

Bioorg. Med. Chem. Lett. 20(15) , 4582-6, (2010)

A new aryl-hydrazide l-glutamic acid derivative, pygmeine (3), was isolated from a methanolic extract of Lichina pygmaea, a marine lichen. Synthetic derivatives obtained via a two-step coupling of l-g...

Selective alkylation of aminophenols. Wang R and Xu J.

ARKIVOC , 293-299, (2010)

Structural study of four benzyloxybenzoic acids and benzyloxyanilines using X-ray powder diffraction: interplay of strong and weak intermolecular interactions. Chattopadhyay B, et al.

CrystEngComm 15(6) , 1077-85, (2013)

2-(BENZYLOXY)-5-(TRIFLUOROMETHYL)ANILINE
2-benzyloxy-4-methoxy-aniline, hydrochloride
2-benzyloxy-3-methoxy-4-nitro-N-(p-toluenesulfonyl)aniline
2-(Benzyloxy)-N-{2-[4-(tert-butyl)phenoxy]-propyl}aniline
2-(Benzyloxy)-N-{2-[2,4-di(tert-butyl)phenoxy]-ethyl}aniline
2-benzyloxy-5-dibromo-3-[(N-phenyl)aminomethyl]pyridine
tert-butyl N-[1-methyl-2-(5-nitrobenzofuran-7-yl)ethyl]carbamate
2-Amino-6-chloro-4-methylbenzenesulfonic acid
6-[3-(4-methylphenyl)-1,2,4-oxadiazol-5-yl]-11H-pyrido[2,1-b]quinazolin-11-one
6-(3-phenyl-1,2,4-oxadiazol-5-yl)-11H-pyrido[2,1-b]quinazolin-11-one
2-[(2R)-2-aminopropyl]-6-ethoxyphenol
3-(furan-2-yl)-2H-pyrazolo[3,4-d]pyrimidin-4-amine
2-(4-methoxyphenyl)-5-[(3-phenyl-1,2,4-oxadiazol-5-yl)methyl]-4H,5H-pyrazolo[1,5-d][1,2,4]triazin-4-one
5-{[3-(4-ethoxy-3-methoxyphenyl)-1,2,4-oxadiazol-5-yl]methyl}-2-(4-methoxyphenyl)-4H,5H-pyrazolo[1,5-d][1,2,4]triazin-4-one
5-{[3-(2-bromophenyl)-1,2,4-oxadiazol-5-yl]methyl}-2-(4-methoxyphenyl)-4H,5H-pyrazolo[1,5-d][1,2,4]triazin-4-one
2-(3-((4-chlorophenyl)sulfonyl)-4-oxoquinolin-1(4H)-yl)-N-(p-tolyl)acetamide

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