syn-7-bromobicyclo[2.2.1]hept-2-ene

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Names

[ CAS No. ]:
20047-65-8

[ Name ]:
syn-7-bromobicyclo[2.2.1]hept-2-ene

[Synonym ]:
syn-7-bromonorbornene
(1R,4S)-7-Bromobicyclo[2.2.1]hept-2-ene
7anti-bromo-norborn-2-ene
(4S,1R)-7-bromobicyclo[2.2.1]hept-2-ene
7anti-Brom-norborn-2-en
MFCD01862962
syn-7-Brom-norbornen

Chemical & Physical Properties

[ Density]:
1.46 g/mL at 20ºC(lit.)

[ Boiling Point ]:
68-70ºC (13 mmHg)

[ Molecular Formula ]:
C7H9Br

[ Molecular Weight ]:
173.05000

[ Flash Point ]:
63.2ºC

[ Exact Mass ]:
171.98900

[ LogP ]:
2.34590

[ Vapour Pressure ]:
0.696mmHg at 25°C

[ Index of Refraction ]:
1.526-1.53

[ Storage condition ]:
Refrigerator (+4°C)

MSDS

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Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26;S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
29035980

Synthetic Route

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Precursor & DownStream

Precursor

  • NORBORNENE

DownStream

  • tri-n-butyltin bromide

Articles

Synthesis and thermal rearrangement of 7-(1, 2-butadien-1-yl) bicyclo [2.2. 1] hept-2-ene [7-(3-methylallenyl) norbornene]. Duncan JA, et al.

J. Am. Chem. Soc. 104(10) , 2837-39, (1982)


More Articles

Related Compounds

  • Bicyclo[2.2.1]hept-2-ene,7-bromo-, anti- (9CI)
  • syn-7-(1,2-butadienyl)bicyclo[2.2.1]hept-2-ene
  • Bicyclo[2.2.1]hept-2-ene, 7-(dichloromethoxy)-, (7-syn)- (9CI)
  • anti-7-methyl-2,3-diazabicyclo[2.2.1]hept-2-ene
  • 2,3-Diazabicyclo[2.2.1]hept-2-ene,7-(1-methylethyl)-,syn-(9CI)
  • Bicyclo[2.2.1]hept-2-ene-7-carboxylic acid, 7-(2-propenyl)-, methyl ester, (7-anti)- (9CI)