2-Morpholinoethanamine

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Names

[ CAS No. ]:
2038-03-1

[ Name ]:
2-Morpholinoethanamine

[Synonym ]:
2-morpholinoethan-1-amine
N-2-Aminoethylmorfolin [Czech]
EINECS 218-011-6
N-Aminoethylmorpholine
N-(2-aminoethyl)-morpholine
2-(N-morpholino)ethylamine
2-(morpholin-4-yl)-ethyl amine
MFCD00006182
4-(2-aminoethyl)-morpholine
4-MORPHOLINEETHANAMINE
2-Morpholinoethylamine
2-(Morpholin-4-yl)ethanamin
2-(4-Morpholinyl)ethanamine
4-(2-Aminoethyl)morpholine
2-morpholinoethanamine
Morpholine,4-(2-aminoethyl)
2-(morpholin-4-yl)ethanamine

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
202.6±20.0 °C at 760 mmHg

[ Melting Point ]:
24 °C

[ Molecular Formula ]:
C6H14N2O

[ Molecular Weight ]:
130.188

[ Flash Point ]:
76.3±21.8 °C

[ Exact Mass ]:
130.110611

[ PSA ]:
38.49000

[ LogP ]:
-1.01

[ Vapour Pressure ]:
0.3±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.474

[ Water Solubility ]:
soluble

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
QD7350000
CHEMICAL NAME :
Morpholine, 4-(2-aminoethyl)-
CAS REGISTRY NUMBER :
2038-03-1
BEILSTEIN REFERENCE NO. :
0104378
LAST UPDATED :
199701
DATA ITEMS CITED :
8
MOLECULAR FORMULA :
C6-H14-N2-O
MOLECULAR WEIGHT :
130.22
WISWESSER LINE NOTATION :
T6N DOTJ A2Z

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Open irritation test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU. Volume(issue)/page/year: 26,269,1944
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,888,1986
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,888,1986 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
3 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU. Volume(issue)/page/year: 26,269,1944
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
2145 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. (Heymans Institute of Pharmacology, De Pintelaan 185, B-9000 Ghent, Belgium) V.4- 1898- Volume(issue)/page/year: 109,108,1957
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
300 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU. Volume(issue)/page/year: 26,269,1944 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X1251 No. of Facilities: 119 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 2625 (estimated) No. of Female Employees: 597 (estimated)

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302-H314-H317

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
T:Toxic;C:Corrosive;

[ Risk Phrases ]:
R22;R24;R34;R43

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 2735 8/PG 2

[ WGK Germany ]:
2

[ RTECS ]:
QD7350000

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
2934999090

Synthetic Route

Precursor & DownStream

Precursor

  • 4-Morpholinylacetonitrile
  • 3-MORPHOLIN-4-YL-PROPIONIC ACID HYDRAZIDE
  • 1,2-Ethanediamine
  • Bis(chloroethyl) ether
  • 4-(2-Chloroethyl)morpholine
  • 2-PHENYL-5-OXAZOLONE
  • 2-(2-Morpholin-4-yl-ethyl)-isoindole-1,3-dione
  • 6-chloro-5-ethylamino-3-methoxy-pyrazine-2-carboxylic acid 2-morpholin-4-yl-ethylamide
  • Aziridine

DownStream

  • N-(5-Chloro-2-nitrobenzo(b)thien-3-yl)-4-morpholineethanamine
  • N-Benzyl-2-morpholinoethanamine
  • Dibenzylamine
  • phenytoin
  • 1,3-Dicyclohexylurea
  • Hydrazinecarbothioamide,N-[2-(4-morpholinyl)ethyl]-
  • Moclobemide
  • 2-Morpholinoethyl isothiocyanate

Customs

[ HS Code ]: 2934999090

[ Summary ]:
2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Carbonic anhydrase activators: activation of the human tumor-associated isozymes IX and XII with amino acids and amines.

Bioorg. Med. Chem. 16 , 3530-6, (2008)

The first activation study of the human carbonic anhydrase (hCA, EC 4.2.1.1) isoforms associated to tumors, hCA IX and XII, with a small library of natural and non-natural amino acids as well as aroma...

Carbonic anhydrase activators: activation of isozyme XIII with amino acids and amines.

Bioorg. Med. Chem. Lett. 16 , 3955-9, (2006)

The first activation study of isoform XIII of carbonic anhydrase (CA, EC 4.2.1.1) is reported. A series of amino acids and amines incorporating protonatable moieties of the primary/heterocyclic amine ...

Carbonic anhydrase activators: the first activation study of the human secretory isoform VI with amino acids and amines.

Bioorg. Med. Chem. 15 , 5351-7, (2007)

The secretory isozyme of human carbonic anhydrase (hCA, EC 4.2.1.1), hCA VI, has been cloned, expressed, and purified in a bacterial expression system. The kinetic parameters for the CO(2) hydration r...


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Related Compounds

  • 2-morpholinoethanamine
  • N-ETHYL-2-MORPHOLINOETHANAMINE
  • N-Benzyl-2-morpholinoethanamine
  • N-Methyl-2-morpholinoethanamine
  • N,N-Dimethyl-2-morpholinoethanamine
  • 2-Morpholinoethanamine Dihydrochloride
  • tert-butyl N-[1-(1-amino-3-hydroxypropan-2-yl)cyclobutyl]carbamate
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • rac-[(1R,2R)-2-(1-methyl-1H-indol-5-yl)cyclopropyl]methanamine
  • 1-{[(2S)-oxolan-2-yl]methyl}cyclopropane-1-carbaldehyde
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 1-(But-3-yn-1-yl)-4,5-difluoro-2-nitrobenzene