2,2-dimethylpropyl carbonochloridate

Names

[ CAS No. ]:
20412-38-8

[ Name ]:
2,2-dimethylpropyl carbonochloridate

[Synonym ]:
2,2-dimethylpropyl chlorocarbonate
2,2-dimethyl-propyl chloroformate
neo-pentyl chloroformate
Chloroformic acid neopentyl ester
MFCD00274354

Chemical & Physical Properties

[ Density]:
1.003 g/mL at 25ºC(lit.)

[ Boiling Point ]:
55ºC36 mm Hg(lit.)

[ Molecular Formula ]:
C6H11ClO2

[ Molecular Weight ]:
150.60300

[ Flash Point ]:
32ºC

[ Exact Mass ]:
150.04500

[ PSA ]:
26.30000

[ LogP ]:
2.40790

[ Vapour Pressure ]:
3.64mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.410(lit.)

MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H226-H314-H331

[ Precautionary Statements ]:
P210-P280-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338-P403 + P233

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T: Toxic;

[ Risk Phrases ]:
R10

[ Safety Phrases ]:
16-26-36/37/39-45

[ RIDADR ]:
UN 2742 6.1/PG 2

[ HS Code ]:
2915900090

Synthetic Route

Precursor & DownStream

Precursor

  • phosgene
  • Neopentyl alcohol

DownStream

  • Dineopentylperoxydicarbonate
  • 2,2-dimethylpropyl carboniodidate

Customs

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

Articles

Correlation of the rates of solvolysis of neopentyl chloroformate-a recommended protecting agent.

Int. J. Mol. Sci. 12(2) , 1161-74, (2011)

The specific rates of solvolysis of neopentyl chloroformate (1) have been determined in 21 pure and binary solvents at 45.0 °C. In most solvents the values are essentially identical to those for ethyl...

Alkylation of alkenes: ethylaluminum sesquichloride-mediated hydro-alkyl additions with alkyl chloroformates and di-tert-butylpyrocarbonate.

J. Am. Chem. Soc. 126(33) , 10319-30, (2004)

A general method for the hydro-alkyl addition to the nonactivated C=C double bond of alkenes using alkyl chloroformates (primary, secondary), 12, and di-tert-butylpyrocarbonate, 52, mediated by ethyla...


More Articles


Related Compounds

  • (3-carbonochloridoyloxy-2,2-dimethylpropyl) carbonochloridate
  • 2,2-dimethylpropyl(trimethyl)stannane
  • 2,2-dimethylpropyl 2,3,4,5-tetrachlorobenzoate
  • 2,2-dimethylpropyl 4-fluorobenzoate
  • 2,2-DIMETHYLPROPYL 5-(1,3-DIOXOLAN-2-YL)-2-THIENYL KETONE
  • 2,2-dimethylpropyl 4,4,4-trinitrobutanoate