1,1,2,2-Tetrahydroperfluorododecyl iodide

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Names

[ CAS No. ]:
2043-54-1

[ Name ]:
1,1,2,2-Tetrahydroperfluorododecyl iodide

[Synonym ]:
C10F21CH2CH2I
11H,11H,12H,12H,12H-heneicosafluoro-12-iodo-dodecane
1H,1H,2H,2H-perfluorododecyl iodide
1H,1H,2H,2H-Perfluoro-1-iodododecane
1-iodo-1H,1H,2H,2H-perfluorodecane
MFCD00039412
1-Iodo-1H,1H,2H,2H-perfluorododecane
EINECS 218-054-0

Chemical & Physical Properties

[ Density]:
1.82

[ Boiling Point ]:
108 °C

[ Melting Point ]:
83-88 °C

[ Molecular Formula ]:
C₁₂H₄F₂₁I

[ Molecular Weight ]:
674.03100

[ Flash Point ]:
108°C/10mm

[ Exact Mass ]:
673.90200

[ LogP ]:
8.09150

[ Vapour Pressure ]:
0.0207mmHg at 25°C

[ Index of Refraction ]:
1.324

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2903799090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Perfluorooctyl iodide
Perfluorododecyl iodide
ethene
1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-6-iodohexane
Perfluorodecyl iodide

DownStream

1,1,2,2-Tetrahydroperfluoro dodecanol
(perfluoro-n-octyl)ethylene
2-(Perfluorooctyl)ethanol
(Perfluorodecyl)ethylene
1H,1H,2H,2H-Heptadecafluorodecyl acrylate
2-(Perfluorodecyl)ethyl acrylate
diisopropyl-(1h,1h,2h,2h-perfluorododecyl)silane

Customs

[ HS Code ]: 2903799090

[ Summary ]:
2903799090 halogenated derivatives of acyclic hydrocarbons containing two or more different halogens。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Articles

Fluorous Synthesis: Fluorous Protocols for the Ugi and Biginelli Multicomponent Condensations.

J. Org. Chem. 62 , 2917, (1997)

A new protocol for multicomponent condensation reactions that uses fluorous (highly fluorinated) substrates is introduced. This method takes advantage of the ease of purification of fluorous compounds...

Synthesis of fluorous fullerene adducts: reversible solubilization of fullerenes in perfluorinated solvents

J. Org. Chem. 65 , 2619, (2000)

Fullerene (C60) Diels-Alder adducts with perfluoroalkylated 1,3-cyclopentadiene (1a,b) were synthesized and studied. The perfluoroalkylated cyclopentadiene was found to be less reactive toward C60 tha...

R.P. Hughes, H.A. Trujillo

Organometallics 15 , 286, (1996)

1,1,2,2-Tetrahydroperfluorododecyl iodide
2-(Perfluorodecyl)ethyl acrylate
1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,17,17,18,18-heptatriacontafluoro-20-iodoicosane
1,1,2,2,3,3-hexamethylaziridinium iodide
1,1,2,2,3,3,4,4-octafluoro-5-iodo-5-(trifluoromethyl)cyclopentane
1,1,2,2,3,3,4,4,5,5,6,6-Dodecafluoro-1-iodohexane
3-[4-(2-bromobenzoyl)piperazin-1-yl]-6-(3-methyl-1H-pyrazol-1-yl)pyridazine
(2-chloro-6-fluorophenyl)(4-(6-(3-methyl-1H-pyrazol-1-yl)pyridazin-3-yl)piperazin-1-yl)methanone
3-(3-methyl-1H-pyrazol-1-yl)-6-{4-[2-(trifluoromethyl)benzoyl]piperazin-1-yl}pyridazine
3-(3-methyl-1H-pyrazol-1-yl)-6-{4-[3-(trifluoromethyl)benzoyl]piperazin-1-yl}pyridazine
3-(3-methyl-1H-pyrazol-1-yl)-6-{4-[4-(trifluoromethyl)benzoyl]piperazin-1-yl}pyridazine
(4-(6-(3-methyl-1H-pyrazol-1-yl)pyridazin-3-yl)piperazin-1-yl)(naphthalen-1-yl)methanone
(4-(6-(3-methyl-1H-pyrazol-1-yl)pyridazin-3-yl)piperazin-1-yl)(naphthalen-2-yl)methanone
3-[4-(furan-2-carbonyl)piperazin-1-yl]-6-(3-methyl-1H-pyrazol-1-yl)pyridazine
cyclopentyl(4-(6-(3,4,5-trimethyl-1H-pyrazol-1-yl)pyridazin-3-yl)piperazin-1-yl)methanone
cyclohexyl(4-(6-(3,4,5-trimethyl-1H-pyrazol-1-yl)pyridazin-3-yl)piperazin-1-yl)methanone

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