2,6-Dichlorobenzyl bromide

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Names

[ CAS No. ]:
20443-98-5

[ Name ]:
2,6-Dichlorobenzyl bromide

[Synonym ]:
2-(Bromomethyl)-1,3-dichlorobenzene
Benzene,2-(bromomethyl)-1,3-dichloro
o,o'-dichlorobenzyl bromide
2,6-Dichlorobenzyl BroMide
Benzene, 2-(bromomethyl)-1,3-dichloro-
1-Bromomethyl-2,6-dichlorobenzene
EINECS 243-827-4
MFCD00000577
2-(bromomethyl)-1,3-dichloro-benzene
α-Bromo-2,6-dichlorotoluene

Chemical & Physical Properties

[ Density]:
1.7±0.1 g/cm3

[ Boiling Point ]:
260.9±25.0 °C at 760 mmHg

[ Melting Point ]:
54-56 °C(lit.)

[ Molecular Formula ]:
C7H5BrCl2

[ Molecular Weight ]:
239.925

[ Flash Point ]:
126.2±13.3 °C

[ Exact Mass ]:
237.895157

[ LogP ]:
4.12

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.597

[ Storage condition ]:
Store at RT.

[ Water Solubility ]:
methanol: 0.1 g/mL, clear

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
XS7966000
CHEMICAL NAME :
Toluene, alpha-bromo-2,6-dichloro-
CAS REGISTRY NUMBER :
20443-98-5
BEILSTEIN REFERENCE NO. :
0637351
LAST UPDATED :
199707
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C7-H5-Br-Cl2
MOLECULAR WEIGHT :
239.93
WISWESSER LINE NOTATION :
GR CG B1E

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
75 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#09451

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S22-S26-S27-S28-S36/37/39-S45-S25

[ RIDADR ]:
UN 3261 8/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
XS7966000

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
2903999090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2,6-Dichlorotoluene
  • 2,6-Dichlorobenzyl alcohol
  • 2,6-Dichlorophenylacetic acid chloride
  • [1-(2,6-dichloro-benzyl)-1H-[4]pyridyliden]-acetone
  • Water
  • Hydrogen bromide

DownStream

  • 3-[(2,6-DICHLOROBENZYL)OXY]BENZALDEHYDE
  • 2,6-dichlorobenzyl methyl ether
  • 2,6-DICHLORO-3-NITROBENZOIC ACID
  • 2,6-Dichlorobenzoic acid
  • Dibenzyl ether
  • 1-(2,6-DICHLOROBENZYL)INDOLINE-2,3-DIONE
  • 2,6-Dichlorobenzaldehyde
  • (2,6-dichlorophenyl)methanamine
  • 2-AMINO-3-(2,6-DICHLOROPHENYL)PROPANOIC ACID
  • 4-[(2,6-DICHLOROBENZYL)OXY]BENZALDEHYDE

Preparation


Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Related Compounds

  • 5-((2,6-Dichlorobenzyl)thio)-1-methyl-1H-tetrazole
  • 2,6-DICHLOROBENZYL 4-STYRYL-2-PYRIMIDINYL SULFIDE
  • 2,6-DICHLOROBENZYL 5-[3-(TRIFLUOROMETHYL)PHENYL]-2-PYRIMIDINYL SULFIDE
  • 2,6-DICHLOROBENZYL N-[2-(2-FURYL)VINYL]CARBAMATE
  • 2,6-dichlorobenzyl radical
  • (2,6-dichlorobenzyl)phosphonic acid
  • N-(2-ethoxyphenyl)-2-(2-morpholino-4-oxo-7-(thiophen-2-yl)thiazolo[4,5-d]pyridazin-5(4H)-yl)acetamide
  • N-cyclopentyl-2-(2-morpholino-4-oxo-7-(thiophen-2-yl)thiazolo[4,5-d]pyridazin-5(4H)-yl)acetamide
  • N-cyclohexyl-2-(2-morpholino-4-oxo-7-(thiophen-2-yl)thiazolo[4,5-d]pyridazin-5(4H)-yl)acetamide
  • N-benzyl-2-(2-morpholino-4-oxo-7-(thiophen-2-yl)thiazolo[4,5-d]pyridazin-5(4H)-yl)acetamide
  • N-(furan-2-ylmethyl)-2-(2-morpholino-4-oxo-7-(thiophen-2-yl)thiazolo[4,5-d]pyridazin-5(4H)-yl)acetamide
  • 2-(2-morpholino-4-oxo-7-(thiophen-2-yl)thiazolo[4,5-d]pyridazin-5(4H)-yl)-N-phenethylacetamide
  • N-(4-methylbenzyl)-2-(2-morpholino-4-oxo-7-(thiophen-2-yl)thiazolo[4,5-d]pyridazin-5(4H)-yl)acetamide
  • 5-(3-fluorobenzyl)-2-morpholino-7-(thiophen-2-yl)thiazolo[4,5-d]pyridazin-4(5H)-one
  • 5-(3-methylbenzyl)-2-morpholino-7-(thiophen-2-yl)thiazolo[4,5-d]pyridazin-4(5H)-one
  • 5-(2,5-dimethylbenzyl)-2-morpholino-7-(thiophen-2-yl)thiazolo[4,5-d]pyridazin-4(5H)-one
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