2',4'-Acetoxylidine

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Names

[ CAS No. ]:
2050-43-3

[ Name ]:
2',4'-Acetoxylidine

[Synonym ]:
N-(2,4-Dimethylphenyl)acetamide
2',4'-Acetoxylidine
N-Acetoxy-2,4-dimethylaniline
EINECS 218-088-6
Acetamide, N-(2,4-dimethylphenyl)-
Acetanilide,2',4'-dimethyl
MFCD00026125
4-Acetamino-m-xylol
Essigsaeure-asymm.-m-xylidid
2',4'-ACETOXYLIDIDE
2',4'-Dimethylacetanilide

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
297.3±9.0 °C at 760 mmHg

[ Melting Point ]:
129-132ºC(lit.)

[ Molecular Formula ]:
C10H13NO

[ Molecular Weight ]:
163.216

[ Flash Point ]:
172.6±3.7 °C

[ Exact Mass ]:
163.099716

[ PSA ]:
29.10000

[ LogP ]:
2.00

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.560

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
AN7420000
CHEMICAL NAME :
2',4'-Acetoxylidide
CAS REGISTRY NUMBER :
2050-43-3
BEILSTEIN REFERENCE NO. :
2690429
LAST UPDATED :
199701
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C10-H13-N-O
MOLECULAR WEIGHT :
163.24
WISWESSER LINE NOTATION :
1VMR B1 D1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1300 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 19,20,1971

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn

[ Risk Phrases ]:
R22;R36/37/38

[ Safety Phrases ]:
S26-S36/37

[ RIDADR ]:
NONH for all modes of transport

[ RTECS ]:
AN7420000

[ HS Code ]:
2924299090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2,4-Xylidine
  • Ethanoic anhydride
  • Dicumyl peroxide
  • 4'-Methylacetanilide
  • 2,4-Pentandione
  • 2,4-dimethylacetophenone oxime
  • N-(3t-[2]furyl-allylidene)-2,4-dimethyl-aniline
  • carbon monoxide
  • methyl iodide
  • 3,5-Dimethylaniline

DownStream

  • Acetamide,N-(2,4-dimethyl-6-nitrophenyl)-
  • N-(2,4-dimethyl-5-nitrophenyl)acetamide
  • 3,5-DIMETHYL-1,2-BENZENEDIAMINE
  • 4(3H)-Quinazolinone,2,6-dimethyl-
  • 4,6,8-Trimethylquinoline
  • 2-CHLORO-4,6-DIMETHYL ACETANILIDE
  • aminoterephthalic acid
  • 5-Bromo-2,4-dimethylaniline
  • 2-Chloro-4,6-dimethylaniline
  • N,2,4-Trimethylaniline

Customs

[ HS Code ]: 2924299090

[ Summary ]:
2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Carcinogenic effect of N-hydroxy-N-2-fluorenylacetamide, 2',4'-dimethylacetanilide, and 2',4'6'-trimethylacetanilide on liver in suckling mice.

Proc. Soc. Exp. Biol. Med. 122(1) , 111-4, (1966)

Spyra W and Winkelmann K.

The Conversion of Liquid Rocket Fuels , (2006) 165 , 125-133

Haynes WM.

CRC Handbook of Chemistry and Physics 96th ed.,, (2015), 3-218


More Articles

Related Compounds

  • 2',4'-Dihydroxyphenyl-3',5',α,β-tetrabrom-β-naphthylethyl-keton
  • 2',4'-Dihydroxy-4,6'-diMethoxydihydrochalcone
  • 2',4'-DIFLUORO-N-METHYLACETANILIDE
  • 2',4'-Dihydroxy-3,7':4,8'-diepoxylign-7-ene
  • 2',4',5,7-tetrahydroxy-5',6-dimethoxyflavone
  • 2',4',5',7'-tetrachlorofluorescein
  • 6-Mercapto-1-(m-tolyl)-1H-pyrazolo[3,4-d]pyrimidin-4(5H)-one
  • 1-(2,3-Dimethylphenyl)-6-mercapto-1H-pyrazolo[3,4-d]pyrimidin-4(5H)-one
  • 4-(4,4-Difluoropiperidin-1-ylmethyl)-2-ethoxyphenylamine
  • 1-(2,5-Dimethoxyphenyl)-6-mercapto-1H-pyrazolo[3,4-d]pyrimidin-4(5H)-one
  • 1-(2-Fluorophenyl)-6-mercapto-1H-pyrazolo[3,4-d]pyrimidin-4(5H)-one
  • 1-(2-Chlorophenyl)-6-mercapto-1H-pyrazolo[3,4-d]pyrimidin-4(5H)-one
  • 1-(3-Fluorophenyl)-6-mercapto-1H-pyrazolo[3,4-d]pyrimidin-4(5H)-one
  • 1-(3-Chloro-2-methylphenyl)-6-mercapto-1H-pyrazolo[3,4-d]pyrimidin-4(5H)-one
  • 6-Mercapto-1-(2-methoxy-5-methylphenyl)-1H-pyrazolo[3,4-d]pyrimidin-4(5H)-one
  • 1-(3-Chloro-4-methoxyphenyl)-6-mercapto-1H-pyrazolo[3,4-d]pyrimidin-4(5H)-one
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