Methyl pent-3-enoate

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Names

[ CAS No. ]:
20515-19-9

[ Name ]:
Methyl pent-3-enoate

[Synonym ]:
methyl-3-pentenoate
3-Pentatenoic Acid Methyl Ester
Methyl trans-3-Pentenoate
Methyl (3E)-3-pentenoate
Methyl (3E)-pent-3-enoate
(E)-Pent-3-enoic acid methyl ester
3-Pentensaeuremethylester
methyl cis/trans-pent-3-enoate
EINECS 212-453-3
3-Pentenoic acid, methyl ester, (3E)-
METHYL TRANS-PENTENOIC ACID
pent-3-enoic acid methyl ester
3-Pentenoic acid, methyl ester
3-pentenoic methyl ester
Methyl pent-3-enoate
methyl 3-trans-pentenoate
MFCD00191576
3-Pentenoioc acid methyl ester

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
120.8±9.0 °C at 760 mmHg

[ Molecular Formula ]:
C6H10O2

[ Molecular Weight ]:
114.142

[ Flash Point ]:
45.9±17.1 °C

[ Exact Mass ]:
114.068077

[ PSA ]:
26.30000

[ LogP ]:
1.53

[ Vapour Pressure ]:
15.0±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.422

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Risk Phrases ]:
R10

[ Safety Phrases ]:
S16

[ RIDADR ]:
UN 3272 3/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Methanol
  • γ-Valerolactone
  • diazomethane
  • Carbon dioxide
  • butadiene
  • (E)-but-2-en-1-amine
  • carbon monoxide
  • ethene
  • 6-OXABICYCLO[3.1.0]HEX-3-ENE
  • Methyl 5-bromopentanoate

DownStream

  • Methyl 4-oxopentanoate
  • Methyl 6-oxohexanoate
  • methyl valerate
  • Aristolindiquinone

Articles

Total Syntheses of (-)-Grandinolide and (-)-Sapranthin by the Sharpless Asymmetric Dihydroxylation of Methyl trans-3-Pentenoate: Elucidation of the Stereostructure of (-)-Sapranthin. Harcken C, et al.

Chemistry 4(11) , 2342-52, (1998)

Monolith-and Silica-Supported Carboxylate-Based Grubbs-Herrmann-Type Metathesis Catalysts. Krause JO, et al.

Adv. Synth. Catal. 345(8) , 996-1004, (2003)

C-Alkoxycarbonyl nitrones: building blocks for the synthesis of butenolides, lactams and modified nucleosides. Romeo G, et al.

Mini Rev. Org. Chem. 2(1) , 59-77, (2005)


More Articles

Related Compounds

  • methyl pent-3-enoate
  • methyl pent-3-enoate
  • methyl 3-[(phenylthio)methyl]pent-3-enoate
  • ethyl (E)-2-cyano-3-ethyl-2-methyl-pent-3-enoate
  • diethyl 2-(2-methylprop-1-enyl)propanedioate
  • methyl pent-3-ynoate
  • 3-(4-Fluorophenyl)-6-[({3-[4-(methylsulfanyl)phenyl]-1,2,4-oxadiazol-5-yl}methyl)sulfanyl]pyridazine
  • 3-(4-Ethylphenyl)-5-(((6-(4-fluorophenyl)pyridazin-3-yl)thio)methyl)-1,2,4-oxadiazole
  • 3-(3,4-Dimethylphenyl)-5-(((6-(4-fluorophenyl)pyridazin-3-yl)thio)methyl)-1,2,4-oxadiazole
  • 3-(3,4-Dimethoxyphenyl)-6-[({3-[4-(trifluoromethyl)phenyl]-1,2,4-oxadiazol-5-yl}methyl)sulfanyl]pyridazine
  • 3-(3,4-Dimethoxyphenyl)-6-({[3-(3,4,5-trimethoxyphenyl)-1,2,4-oxadiazol-5-yl]methyl}sulfanyl)pyridazine
  • 3-(3,4-Dimethoxyphenyl)-6-({[3-(2-thienyl)-1,2,4-oxadiazol-5-yl]methyl}thio)pyridazine
  • 3-(3,4-Dimethylphenyl)-6-({[3-(2-methylphenyl)-1,2,4-oxadiazol-5-yl]methyl}sulfanyl)pyridazine
  • 3-(3,4-Dimethylphenyl)-6-({[3-(3-methylphenyl)-1,2,4-oxadiazol-5-yl]methyl}sulfanyl)pyridazine
  • 3-(3,4-Dimethylphenyl)-6-({[3-(4-methylphenyl)-1,2,4-oxadiazol-5-yl]methyl}sulfanyl)pyridazine
  • 3-(2-Chlorophenyl)-5-(((6-(3,4-dimethylphenyl)pyridazin-3-yl)thio)methyl)-1,2,4-oxadiazole
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