Dichloro[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene]palladium(II)

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Names

[ CAS No. ]:
205319-10-4

[ Name ]:
Dichloro[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene]palladium(II)

[Synonym ]:
Palladium(2+) chloride - (9,9-dimethyl-9H-xanthene-4,5-diyl)bis(diphenylphosphine) (1:2:1)
[4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene]dichloropalladium(II)
Phosphine, 1,1'-(9,9-dimethyl-9H-xanthene-4,5-diyl)bis[1,1-diphenyl-, palladium(2+) salt, hydrochloride (1:1:2)
[4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene]palladium(II) Dichloride
Dichloro[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene]palladium(II)

Chemical & Physical Properties

[ Melting Point ]:
287 °C(dec.)

[ Molecular Formula ]:
C₃₉H₃₂Cl₂OP₂Pd

[ Molecular Weight ]:
755.94

[ Exact Mass ]:
754.033997

[ PSA ]:
36.41000

[ LogP ]:
1.64260

MSDS

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Safety Information

[ RIDADR ]:
NONH for all modes of transport

Synthetic Route

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Precursor & DownStream

Precursor

DownStream

Articles

Palladium-catalyzed esterification of aryl halides using aryl formates without the use of external carbon monoxide.

Chem. Commun. (Camb.) 48 , 8012, (2012)

Aryl formates are efficient carbon monoxide sources in palladium-catalyzed esterification of aryl halides. The carbonylation readily proceeds at ambient pressure without the use of external carbon mon...

Palladium-catalyzed oxidative carbonylation of benzylic C-H bonds via nondirected C(sp3)-H activation.

J. Am. Chem. Soc. 134 , 9902, (2012)

A new strategy for generating benzylpalladium reactive species from toluenes via nondirected C(sp(3))-H activation has been developed. This led to construction of an efficient Pd-catalyzed reaction pr...

Improved carbonylation of heterocyclic chlorides and electronically challenging aryl bromides.

Org. Lett. 6 , 2097, (2004)

[reaction: see text] Optimized conditions are described that effect the carbonylation of diverse heterocyclic chlorides to yield the desired alkyl esters. In addition, bromoanilines and bromoanisoles,...

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