2-Bromomalonaldehyde

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Names

[ CAS No. ]:
2065-75-0

[ Name ]:
2-Bromomalonaldehyde

[Synonym ]:
Malonaldehyde,bromo
2-bromo-1,3-propanedial
BrCH(CHO)2
Propanedial, 2-bromo-
2-brommalondialdehyd
propanedial, bromo-
Bromomalonaldehyde
Bromomalondialdehyde
Malonaldehyde, bromo-
MFCD00459999
2-Bromomalonaldehyde
2-bromomalondialdehyde
PROPANEDIAL,BROMO
2-bromo-malonaldehyde

Chemical & Physical Properties

[ Density]:
1.8±0.1 g/cm3

[ Boiling Point ]:
134.8±25.0 °C at 760 mmHg

[ Melting Point ]:
132-136 °C(lit.)

[ Molecular Formula ]:
C3H3BrO2

[ Molecular Weight ]:
150.959

[ Flash Point ]:
69.5±9.7 °C

[ Exact Mass ]:
149.931641

[ PSA ]:
34.14000

[ LogP ]:
0.96

[ Vapour Pressure ]:
8.0±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.469

[ Storage condition ]:
Keep Cold

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2913000090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 1,1,3,3-Tetramethoxypropane
  • 2,2-Dibromo-3-(bromomethyl)oxirane
  • 2-bromo-1,1,3,3-tetraethoxy-propane
  • 3-chloro-1,3-diethoxy-propene

DownStream

  • 6-Bromo-7-methylimidazo[1,2-a]pyridine-3-carbaldehyde
  • 6-Bromo-pyrazolo[1,5-a]py...
  • 6-bromo-[1,2,4]triazolo[1,5-a]pyrimidine
  • 5-Bromo-1-methyl-1H-pyrazolo[3,4-b]pyridine
  • 3-Bromo-7-methoxyquinoline
  • 6-Bromopyrazolo[1,5-a]pyrimidine
  • 5-Bromo-1H-pyrazolo[3,4-b]pyridine
  • 6-Chloroimidazo[1,2-a]pyridine-3-carbaldehyde
  • 4-Bromo-1-(4-fluorophenyl)-1H-pyrazole
  • Imidazo[1,2-a]pyridine-3-carbaldehyde

Customs

[ HS Code ]: 2913000090

[ Summary ]:
HS: 2913000090 halogenated, sulphonated, nitrated or nitrosated derivatives of products of heading 2912 Educational tariff:17.0% Tax rebate rate:9.0% Regulatory conditions:none Most favored nation tariff:5.5% General tariff:30.0%

Articles

Reactions of 9-substituted guanines with bromomalondialdehyde in aqueous solution predominantly yield glyoxal-derived adducts.

Org. Biomol. Chem. 2 , 1943-1950, (2004)

Reactions of 9-ethylguanine, 2'-deoxyguanosine and guanosine with bromomalondialdehyde in aqueous buffers over a wide pH-range were studied. The main products were isolated and characterized by (1)H a...

A simplified and efficient synthesis of 5,10-dideaza-5,6,7,8-tetrahydrofolic acid (DDATHF).

Invest. New Drugs 14(3) , 281-5, (1996)

A new and extremely efficient synthesis of DDATHF from 4-vinylbenzoic acid and bromomalondialdehyde as precursors has been developed which proceeds in 48% overall yield.

Formation of ethenocarbaldehyde derivatives of adenosine and cytidine in reactions with mucochloric acid.

Chem. Res. Toxicol. 6(4) , 495-9, (1993)

Mucochloric acid, a genotoxic compound formed during chlorine disinfection of drinking water, was reacted with adenosine and cytidine at pH 4.0, 90 degrees C. HPLC analyses with UV detection at 325 nm...


More Articles

Related Compounds

  • 2-bromo-1,1,3,3-tetraethoxy-propane
  • 2-[(4-aminobenzoyl)-benzylamino]ethyl-diethylazanium,chloride
  • 2-methyl-2-methylsulfanylpropanenitrile
  • 2-(4-methoxyphenyl)-4-nitrobenzoic acid
  • 2-(4-methoxyphenyl)-5-methylbenzoic acid
  • 2-(4-methoxyphenyl)-6-methylbenzoic acid