Aluminum phosphide

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Names

[ CAS No. ]:
20859-73-8

[ Name ]:
Aluminum phosphide

[Synonym ]:
EINECS 244-088-0
Detia
Celphos
al-phos
MFCD00046171
celphine
fumitoxin
Talunex
delicia
aluminum phosphide
celphide
phosphinidynealuminum
Chelphos
gastion

Chemical & Physical Properties

[ Density]:
2.42

[ Melting Point ]:
2000℃

[ Molecular Formula ]:
AlP

[ Molecular Weight ]:
57.95

[ LogP ]:
0.55080

[ Stability ]:
Flammable solid. Contact with acids liberates highly toxic gas (phosphine). Incompatible with acids, moisture, oxidizing agents.

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
BD1400000
CHEMICAL NAME :
Aluminum phosphide
CAS REGISTRY NUMBER :
20859-73-8
LAST UPDATED :
199803
DATA ITEMS CITED :
22
MOLECULAR FORMULA :
Al-P
MOLECULAR WEIGHT :
57.95
WISWESSER LINE NOTATION :
AL P

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Human - woman
DOSE/DURATION :
60 mg/kg
TOXIC EFFECTS :
Vascular - other changes Lungs, Thorax, or Respiration - dyspnea Gastrointestinal - gastritis
REFERENCE :
HUTODJ Human Toxicology. (Macmillan Press Ltd., Houndmills, Basingstoke, Hants., RG 21 2XS, UK) V.1- 1981- Volume(issue)/page/year: 7,343,1988
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Human - man
DOSE/DURATION :
21 mg/kg
TOXIC EFFECTS :
Vascular - other changes Gastrointestinal - gastritis
REFERENCE :
HUTODJ Human Toxicology. (Macmillan Press Ltd., Houndmills, Basingstoke, Hants., RG 21 2XS, UK) V.1- 1981- Volume(issue)/page/year: 7,343,1988
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Human - woman
DOSE/DURATION :
180 mg/kg
TOXIC EFFECTS :
Cardiac - pulse rate increase, without fall in BP Liver - jaundice, other or unclassified Kidney, Ureter, Bladder - changes in tubules (including acute renal failure, acute tubular necrosis)
REFERENCE :
HUTODJ Human Toxicology. (Macmillan Press Ltd., Houndmills, Basingstoke, Hants., RG 21 2XS, UK) V.1- 1981- Volume(issue)/page/year: 7,343,1988
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Human - man
DOSE/DURATION :
86 mg/kg
TOXIC EFFECTS :
Behavioral - coma Vascular - other changes Gastrointestinal - nausea or vomiting
REFERENCE :
HUTODJ Human Toxicology. (Macmillan Press Ltd., Houndmills, Basingstoke, Hants., RG 21 2XS, UK) V.1- 1981- Volume(issue)/page/year: 7,343,1988
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Human - man
DOSE/DURATION :
2800 mg/m3
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85ARAE "Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revision Volume(issue)/page/year: 3,38,1976/1977 *** REVIEWS *** ACGIH TLV-TWA 2 mg(Al)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 2 mg(Al)/m3 JAN 1993 OEL-BELGIUM:TWA 2 mg(Al)/m3 JAN 1993 OEL-DENMARK:TWA 2 mg(Al)/m3 JAN 1993 OEL-FRANCE:TWA 2 mg(Al)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 2 mg(Al)/m3 JAN 1993 OEL-RUSSIA:TWA 2 mg(Al)/m3 JAN 1993 OEL-SWEDEN:TWA 2 mg(Al)/m3 JAN 1993 OEL-SWITZERLAND:TWA 2 mg(Al)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 2 mg(Al)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 84460 No. of Facilities: 280 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 12600 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 84460 No. of Facilities: 190 (estimated) No. of Industries: 3 No. of Occupations: 4 No. of Employees: 623 (estimated)

Safety Information

[ Hazard Codes ]:
T+,F,N

[ Risk Phrases ]:
R15/29

[ Safety Phrases ]:
S3/9/14-S30-S36/37-S45-S61

[ RIDADR ]:
1397

[ Packaging Group ]:
I

[ Hazard Class ]:
4.3

[ HS Code ]:
2848000010

Customs

[ HS Code ]: 2848000010


Related Compounds

  • Aluminum phosphide
  • Aluminum,tris[(9Z)-9-octadecenoato-kO]-m-oxo(2-propanolato)di- (9CI)
  • aluminum phthalocyanine hydroxide
  • Aluminum zirconium chloride hydroxide
  • aluminum,2-ethylhexanoate,benzoate
  • aluminum,(2R,3R,4R,5R)-3,4,5,6-tetrahydroxy-2-oxidohexanoate,dihydroxide,dihydrate
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide
  • Benzoic acid, 2-[2-bromo-2-(2-phenylhydrazinylidene)ethylidene]hydrazide