TETRACARBONYL(TRIFLUOROMETHYLTHIO)MANGANESE dimer

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Names

[ CAS No. ]:
21239-57-6

[ Name ]:
TETRACARBONYL(TRIFLUOROMETHYLTHIO)MANGANESE dimer

Chemical & Physical Properties

[ Molecular Formula ]:
C10H2F6Mn2O8S2

[ Molecular Weight ]:
538.11500

[ Exact Mass ]:
537.78600

[ PSA ]:
77.60000

[ LogP ]:
1.93520

[ Vapour Pressure ]:
6010mmHg at 25°C

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
OP1325000
CHEMICAL NAME :
Manganese, tetracarbonyl(trifluoromethylthio)-, dimer
CAS REGISTRY NUMBER :
21239-57-6
LAST UPDATED :
199701
DATA ITEMS CITED :
19
MOLECULAR FORMULA :
C10-F6-Mn2-O8-S2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
180 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#07141 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:CL 5 mg(Mn)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,149,1971 OSHA PEL (Gen Indu):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 5 mg(Mn)/m3 JAN 1993 OEL-BELGIUM:TWA 5 mg(Mn)/m3 JAN 1993 OEL-DENMARK:TWA 2.5 mg(Mn)/m3 JAN 1993 OEL-FINLAND:TWA 2.5 mg(Mn)/m3 JAN 1993 OEL-HUNGARY:TWA 0.3 mg(Mn)/m3;STEL 0.6 mg(Mn)/m3 JAN 1993 OEL-JAPAN:TWA 0.3 mg(Mn)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 1 mg(Mn)/m3 JAN 1993 OEL-POLAND:TWA 0.3 mg(Mn)/m3 JAN 1993 OEL-SWEDEN:TWA 1 mg(Mn)/m3;STEL 2.5 mg(Mn)/m3 (resp. dust) JAN 1993 OEL-SWEDEN:TWA 2.5 mg(Mn)/m3;STEL 5 mg(Mn)/m3 (total dust) JAN 1993 OEL-UNITED KINGDOM:TWA 5 mg(Mn)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV

Synthetic Route

Precursor & DownStream

Precursor

  • Manganese carbonyl
  • BIS(TRIFLUOROMETHYL)DISULFIDE
  • tris(trifluoromethylmercapto)amine
  • trifluoromethanesulphenyl chloride

DownStream


Related Compounds

  • tetracarbonyl-η4-cyclooctatetraene-tungsten(0)
  • tetracarbonyl{η2-(dimethylamino)methylvinylborane}iron
  • tetracarbonyl(cycloheptene)iron
  • Tetracarbonyl(trimethylgermyl)cobalt
  • tetracarbonyl(η2-dimethyl fumarate)iron
  • Tetracarbonyl-η4-(2,4-dibutyl-1,3-di-tert-butyl-1,3,2,4-diazadiboretidin)chrom
  • 3-(4-Methyl-1,3-thiazol-2-yl)-2-(2,2,2-trifluoroacetamido)propanoic acid
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 1,2,4-Trifluoro-3-(nitromethyl)benzene
  • 4-(6-amino-1H-1,2,3-benzotriazol-1-yl)-1lambda6-thiane-1,1-dione
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde