10-camphorsulfonyl chloride

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Names

[ Name ]:
10-camphorsulfonyl chloride

[Synonym ]:
Bicyclo[2.2.1]heptane-1-methanesulfonyl chloride, 7,7-dimethyl-2-oxo-, (1S,4R)-
camphor-10-sulfonyl chloride
D-(+)-10-Camphorsulfonyl chloride
MFCD00064156
(1S)-(+)-10-Camphorsulfonyl Chloride
camphor-10-sulfonic acid chloride
camphorsulfonyl chloride
((1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonyl chloride
Dextro-10-camphorsulfonyl chloride
D(+)-10-Camphorsulfonyl Chloride
(1S)-Camphor-10-sulfonic acid chloride
(+)-Camphor-10-sulfonyl chloride
[(1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]hept-1-yl]methanesulfonyl chloride
EINECS 244-314-8
10-camphorsulfonyl chloride
Bicyclo[2.2.1]heptane-1-methanesulfonyl chloride, 7,7-dimethyl-2-oxo-
D-CAMPHOR-10-SULFONYL CHLORIDE
(7,7-Dimethyl-2-oxobicyclo[2.2.1]hept-1-yl)methansulfonylchlorid
(7,7-Dimethyl-2-oxobicyclo[2.2.1]hept-1-yl)-methanesulfonyl chloride
(+)-10-Camphorsulfonyl Chloride
(7,7-Dimethyl-2-oxobicyclo[2.2.1]hept-1-yl)methanesulfonyl chloride

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
349.4±15.0 °C at 760 mmHg

[ Melting Point ]:
67-68 °C

[ Molecular Formula ]:
C₁₀H₁₅ClO₃S

[ Molecular Weight ]:
250.742

[ Flash Point ]:
165.1±20.4 °C

[ Exact Mass ]:
250.043045

[ PSA ]:
59.59000

[ LogP ]:
1.55

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.528

[ Storage condition ]:
2~8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 3261 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
2914700090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

D-Camphorsulfonic acid
acide S(+)-10-camphresulfinique
(+)-Camphor

DownStream

(S)-(+)-(2-BUTENOYL)-2 10-CAMPHORSULTAM
(4S)-7,7-dimethyl-4-nitrobicyclo[2.2.1]heptan-3-one
(2R)-Bornane-10,2-sultam
(+)-Camphor
(1S)-(-)-(10-Camphorsulfonyl)imine
(1R,3S)-CYCLOPENT-4-ENE-1,3-DIOL
(1S)-(-)-10-MERCAPTOBORNEOL
(1s)-10-camphorsulfonamide
7,7-DIMETHYL-2-OXOBICYCLO[2.2.1]HEPTANE-1-CARBOXYLIC ACID
4,5-DIFLUORO-2-METHYLBROMOBENZENE

Customs

[ HS Code ]: 2914700090

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

Articles

Orally active, nonpeptide oxytocin antagonists.

J. Med. Chem. 35 , 3919, (1992)

The first nonpeptide antagonists of the neurohypophyseal hormone, oxytocin (OT) are described. Derivatives of the spiroindenepiperidine ring system, these compounds include L-366,509, an orally bioava...

[The HPLC analysis of chiral beta-receptor blockers].

Pharmazie 48(11) , 829-33, (1993)

Investigations on direct separation by RP-HPLC of selected enantiomeric beta-adrenergic active agents are described. R- and S-1-phenylethylisocyanate (PEIC) as well as (1S)-(+)-campher-10-sulfonylchlo...

Synthesis , 947, (1992)

DL-10-Camphorsulfonyl Chloride
(-)-10-Camphorsulfonyl Chloride
L-(-)-10-Camphorsulfonyl chloride
(1R)-(-)-(10-Camphorsulfonyl)oxaziridine
(+)-10-(camphorsulfonyl)methyl isocyanide
(1S)-(+)-(10-camphorsulfonyl)oxaziridine
4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
4-{[3-(Propan-2-yl)-1,2,4-oxadiazol-5-yl]methyl}piperidine hydrochloride
1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
(4-Methyl-tetrahydro-furan-2-yl)-methanol
N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
tert-Butyl-DL-alanine
4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide