N-HEXYLLITHIUM

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Names

[ CAS No. ]:
21369-64-2

[ Name ]:
N-HEXYLLITHIUM

[Synonym ]:
N-HEXYLLITHIUM
Hexyllithium
Lithium,hexyl
Hexyllithium solution
EINECS 404-950-0
lithium hexane
HxLi
MFCD00191446

Chemical & Physical Properties

[ Density]:
0.708 g/mL at 25ºC

[ Boiling Point ]:
68.5ºC at 760 mmHg

[ Molecular Formula ]:
C6H13Li

[ Molecular Weight ]:
92.10840

[ Flash Point ]:
16 °F

[ Exact Mass ]:
92.11770

[ LogP ]:
2.53430

[ Storage condition ]:
2-8°C

[ Stability ]:
Stable, but highly flammable. Reacts violently with water, releasing flammable gas. May spontaneously inflame in air. Moisture and air sensitive. Incompatible with water, alcohols, halocarbons.

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS07, GHS08, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H250-H260-H304-H314-H336-H361f-H373-H411

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P210-P222-P223-P231 + P232-P370 + P378-P422

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F,Xn,N,C

[ Risk Phrases ]:
R11

[ Safety Phrases ]:
S26-S30-S43-S45-S61-S62-S36-S37-S39

[ RIDADR ]:
UN 3394 4

[ WGK Germany ]:
2

[ Hazard Class ]:
4.3

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • chlorohexane
  • 1-Bromohexane

DownStream

  • Lithium dimethylamide
  • N-n-Hexylaniline
  • 2-Nonene
  • 8-hydroxytetradecan-7-one
  • 2,2-dimethylnonan-3-ol
  • 1-Hexylnaphthalene
  • Heptanal
  • Dodecane
  • 1-(cyclohex-1-enyl)heptan-1-one
  • 1-(5-methylcyclopent-1-en-1-yl)heptan-1-one

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Colloidal nanocrystals of lithiated group 14 elements.

Angew. Chem. Int. Ed. Engl. 53(52) , 14527-32, (2014)

The synthesis of colloidal nanocrystals (NCs) of lithiated group 14 elements (Z=Si, Ge, and Sn) is reported, which are Li4.4 Si, Li3.75 Si, Li4.4 Ge, and Li4.4 Sn. Lix Z compounds are highly reactive ...


More Articles

Related Compounds

  • N,N'-bis[2-(3,4-dimethoxyphenyl)ethyl]-N,N'-dimethylpropane-1,3-diamine
  • N-octanoyl benzotriazole
  • N-[4-[(6-chloro-[1,3]dioxolo[4,5-b]acridin-10-yl)amino]-3-methoxyphenyl]methanesulfonamide
  • N-(diaminomethylidene)pyrrolidine-1-carboximidamide,hydrochloride
  • N-phenyl-[1,3]dioxolo[4,5-b]acridin-10-amine
  • N-[bis(diethylamino)silyl]-N-ethylethanamine
  • 1-[3-(1H-Indol-2-yl)pyrrolidin-1-yl]prop-2-en-1-one
  • 2,3-Dichloro-N-[2-(5-methyl-1,2,4-oxadiazol-3-yl)propan-2-yl]pyridine-4-carboxamide
  • 2,3-Dichloro-N-[2-(1,3-thiazol-2-yl)butan-2-yl]pyridine-4-carboxamide
  • 3-Chloro-N-[2-(5-methyl-1,3-thiazol-2-yl)propan-2-yl]pyrazine-2-carboxamide
  • 7-(9H-Fluoren-9-ylmethoxycarbonyl)-6,8-dihydro-5H-imidazo[1,2-a]pyrazine-3-carboxylic acid
  • 4-Cyclopropyl-1-(propan-2-yl)pyrrolidine-3-carboxylic acid
  • 2-(4-Fluoro-3-methoxyphenyl)cyclopropane-1-carboxylic acid
  • 2-(3-Fluoropyridin-4-yl)cyclopropane-1-carboxylic acid
  • (1'S)-10'-oxa-2',17'-diazaspiro[azetidine-3,15'-tricyclo[15.3.1.0,4,9]henicosane]-4'(9'),5',7',12'-tetraene-3',16'-dione
  • (1'S)-10'-oxa-2',17'-diazaspiro[azetidine-3,15'-tricyclo[15.4.1.0,4,9]docosane]-4'(9'),5',7',12'-tetraene-3',16'-dione
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