n-methyl-4-hydrazino-7-nitrobenzofurazan

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Names

[ CAS No. ]:
214147-22-5

[ Name ]:
n-methyl-4-hydrazino-7-nitrobenzofurazan

[Synonym ]:
1-methyl-1-(4-nitro-2,1,3-benzoxadiazol-7-yl)hydrazine

Chemical & Physical Properties

[ Density]:
1.611g/cm3

[ Boiling Point ]:
425.7ºC at 760mmHg

[ Melting Point ]:
-160ºC

[ Molecular Formula ]:
C7H7N5O3

[ Molecular Weight ]:
209.16200

[ Flash Point ]:
211.3ºC

[ Exact Mass ]:
209.05500

[ PSA ]:
114.00000

[ LogP ]:
1.66440

[ Appearance of Characters ]:
powder | Dark brown

[ Vapour Pressure ]:
1.88E-07mmHg at 25°C

[ Index of Refraction ]:
1.739

[ Storage condition ]:
2-8°C

[ Water Solubility ]:
Soluble in acetonitrile, methanol

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2934999090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 4-Chloro-7-nitrobenzofurazan
  • monomethylhydrazine

DownStream

Customs

[ HS Code ]: 2934999090

[ Summary ]:
2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

4-(N-Methylhydrazino)-7-nitro-2,1,3-benzooxadiazole (MNBDH): A Novel Fluorogenic Peroxidase Substrate The authors would like to thank the Fonds der Chemischen Industrie (Frankfurt/Main) for financial support.

Angew. Chem. Int. Ed. Engl. 39 , 1453, (2000)

N-Methyl-4-hydrazino-7-nitrobenzofurazan as a New Reagent for Air Monitoring of Aldehydes and Ketones.

Anal. Chem. 71 , 1893, (1999)

The synthesis of N-methyl-4-hydrazino-7-nitrobenzofurazan (MNBDH) and its application as a new reagent for the determination of aldehydes and ketones are described. MNBDH reacts with carbonyl compound...

Determination of nitrite in waters by microplate fluorescence spectroscopy and HPLC with fluorescence detection.

Anal. Chem. 71 , 3003, (1999)

A selective and versatile fluorescence spectroscopic method for the determination of nitrite in waters has been developed. Nitrite reacts in the presence of mineral acids with the nonfluorescent N-met...


More Articles

Related Compounds

  • (S)-2-(N-methyl-4,7-dihydrothieno[2,3-b]pyridine-5-carbonyl)aminobutan-1-ol
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  • N-Methyl-4-chloro-7-azaindole
  • N-methyl-4,5,6,7-tetrahydro-1,3-benzothiazol-5-amine,hydrochloride
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 3-Amino-1-(3,5-dimethoxy-4-methylphenyl)propan-1-one
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • 1-Bromo-3-difluoromethoxy-4-fluoro-2-nitrobenzene
  • tert-Butyl-DL-alanine