m-Bromoacetophenone

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Names

[ CAS No. ]:
2142-63-4

[ Name ]:
m-Bromoacetophenone

[Synonym ]:
3'-Bromoacetophenone
m-MeOC-C6H4-Br
Acetophenone, 3'-bromo-
1-Acetyl-3-bromobenzene
3-BROMOACETOPHENONE
3‘-Bromoacetophenone
EINECS 218-396-0
Acetophenone,3'-bromo
m-Bromoacetophenone
bromoacetophenone-3
MFCD00000083
3’-Bromoacetophenone
1-(3-bromophenyl)ethan-1-one
m-Br-phenylacetophenone
Ethanone, 1- (3-bromophenyl)-
Ethanone, 1-(3-bromophenyl)-
1-(3-Bromophenyl)ethanone

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
255.2±23.0 °C at 760 mmHg

[ Melting Point ]:
8-11 °C(lit.)

[ Molecular Formula ]:
C8H7BrO

[ Molecular Weight ]:
199.045

[ Flash Point ]:
90.9±9.9 °C

[ Exact Mass ]:
197.968018

[ PSA ]:
17.07000

[ LogP ]:
2.58

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.554

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/38

[ Safety Phrases ]:
S26-S36-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ Packaging Group ]:
II; III

[ HS Code ]:
29147090

Synthetic Route

Precursor & DownStream

Precursor

  • 3-Bromo-alpha-methylbenzenemethanol
  • Acetophenone
  • 1-phenethyl bromide
  • QVR CE
  • METHYLLITHIUM
  • N,N-Dimethylacetamide
  • 1,3-Dibromobenzene
  • 3-Aminoacetophenone
  • 1-(3-bromophenyl)ethanone oxime
  • N-Methoxy-N-methylacetamide

DownStream

  • (3,5-DIMETHYLPHENYL)PHOSPHINE
  • Bromoethane
  • 3-BROMOMANDELICACID
  • 3-BROMOPHENYL ACETATE
  • 3-Bromo-alpha-methylbenzenemethanol
  • Acetone
  • 3′-(Trifluoromethyl)acetophenone
  • 3-tert-butylbromobenzene
  • 4-Morpholinoacetophenone
  • 1-(4'-METHOXY[1,1'-BIPHENYL]-3-YL)ETHANONE

Customs

[ HS Code ]: 2914700090

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%


Related Compounds

  • m-bromoacetophenone oxime
  • m-Nitrobenzylidene-p-methoxyaniline
  • 3-Jod-phenylhydrazin
  • m-Dioxane, 2-propenyl-4-isopropyl-5,5-dimethyl-
  • m-PEG2-O-Ph-3-NH2
  • m-trifluoromethylbenzyl nitrate
  • N-(3,4-dimethylphenyl)-2-{3-[(2-fluorophenyl)methanesulfonyl]-1H-indol-1-yl}acetamide
  • 2-{3-[(2-fluorophenyl)methanesulfonyl]-1H-indol-1-yl}-N-(2-methoxyethyl)acetamide
  • 2-(3-((2-fluorobenzyl)sulfonyl)-1H-indol-1-yl)-N-isopentylacetamide
  • 2-(3-((2-fluorobenzyl)sulfonyl)-1H-indol-1-yl)-N-(4-isopropylphenyl)acetamide
  • 2-(3-((2-fluorobenzyl)sulfonyl)-1H-indol-1-yl)-N-(2-methoxy-5-methylphenyl)acetamide
  • 2-(3-((2-fluorobenzyl)sulfonyl)-1H-indol-1-yl)-N-(4-fluorophenyl)acetamide
  • N-cyclohexyl-2-(3-((2-fluorobenzyl)sulfonyl)-1H-indol-1-yl)-N-methylacetamide
  • N-(2,4-difluorophenyl)-2-(3-((2-fluorobenzyl)sulfonyl)-1H-indol-1-yl)acetamide
  • N-(2,4-dimethylphenyl)-2-(3-((2-fluorobenzyl)sulfonyl)-1H-indol-1-yl)acetamide
  • N-(5-chloro-2-methoxyphenyl)-2-(3-((2-fluorobenzyl)sulfonyl)-1H-indol-1-yl)acetamide
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