Phenacyl Bromide

Suppliers

Names

[ CAS No. ]:
2142-69-0

[ Name ]:
Phenacyl Bromide

[Synonym ]:
ortho-bromoacetophenone
Phenacyl Bromide
2‘-Bromoacetophenone
2-Bromoacetophenone
EINECS 218-398-1
2′-Bromoacetophenone
Ethanone, 1- (2-bromophenyl)-
o-Bromoacetophenone
Ethanone, 1-(2-bromophenyl)-
o-MeOC-Ph-Br
1-(2-Bromophenyl)ethanone
2-Bromo-1-phenylethanone
2'-Bromoacetophenone
Acetophenone, o-bromo-
o-bromoacetophnones
MFCD00000067
α-Bromoacetophenone
o-MeOC-C6H4-Br
Acetophenone, 2'-bromo-
acetophenone, 2-bromo-
2'-BromoActophenone
Ethanone, 2-bromo-1-phenyl-
1-ACETYL-2-BROMOBENZENE
2-Bromo-1-Phenylethan-1-One
1-Bromo-2-acetylbenzene
Acetophenone,o-bromo
2-Acetyl-1-bromobenzene

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
249.0±23.0 °C at 760 mmHg

[ Melting Point ]:
°C

[ Molecular Formula ]:
C8H7BrO

[ Molecular Weight ]:
199.05

[ Flash Point ]:
86.6±9.9 °C

[ Exact Mass ]:
197.968018

[ PSA ]:
17.07000

[ LogP ]:
2.28

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.554

[ Storage condition ]:
-20°C

[ Water Solubility ]:
PRACTICALLY INSOLUBLE

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ Packaging Group ]:
I; II; III

[ Hazard Class ]:
6.1

[ HS Code ]:
29147090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 1-Bromo-2-ethynylbenzene
  • 1-(2'-BROMOPHENYL)-1-HYDROXYETHANE
  • Acetophenone
  • METHYLMAGNESIUM BROMIDE
  • 2-Bromobenzoyl chloride
  • Methyl 3-(2-bromophenyl)-3-oxopropanoate
  • 2-Bromoethylbenzene
  • 2-Bromobenzaldehyde
  • Trimethyl(vinyloxy)silane

DownStream

  • 1-(2-bromophenyl)-3-phenylprop-2-en-1-one
  • 2-(2-(DICYCLOHEXYLPHOSPHINO)PHENYL)-1-METHYL-1H-INDOLE
  • 1-(2-(METHYLTHIO)PHENYL)ETHANONE
  • Acetophenone
  • 1-[2-(2-acetylphenyl)sulfanylphenyl]ethanone
  • 2'-Aminoacetophenone
  • 4-methyl-2-phenylquinazoline
  • 2-(2-Bromophenyl)-2-methyl-1,3-dioxolane
  • ether
  • Methylbenzylalcohol

Customs

[ HS Code ]: 2914700090

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

Articles

Enantioselective alkynylation of aromatic ketones catalyzed by chiral camphorsulfonamide ligands.

Angew. Chem. Int. Ed. Engl. 42(41) , 5057-8, (2003)

Non-Condensed Trifluoromethylated 5, 5-Bicycles: Synthesis of 2-[3-Alkyl (phenyl)-1H-pyrazol-1-yl]-4-phenyl-5-alkylthiazole and-4, 5, 6, 7-tetrahydrobenzothiazole Systems. Bonacorso HG, et al.

Synthesis 2002(08) , 1079-83, (3003)

Palladium-catalysed convenient synthesis of 3-methyleneisoindolin-1-ones. Cho CS, et al.

Synth. Commun. 32(!2) , 1821-27, (2002)


More Articles

Related Compounds

  • Phenacyl Bromide
  • Phenacyl Bromide
  • phenacyl bromide
  • phenacyl bromide oxime
  • phenacyl bromide oxime
  • 3-iodophenacyl bromide
  • 3-(1-Aminobutan-2-yl)-1-methylpiperidin-3-ol
  • Methyl(propan-2-yl)[3-(pyrrolidin-3-yl)propyl]amine
  • 4-Pyrimidinamine, 2-cyclopropyl-6-[2-(dimethylamino)-2-methylpropoxy]-N-ethyl-
  • Phenylmethyl N-[5-(methylamino)-5-oxopentyl]carbamate
  • 4-Pyrimidinamine, 6-(2-benzothiazolylthio)-2-(1-methylethyl)-
  • tert-butyl 3-(4-methylthiazol-2-yl)-5,6-dihydro-[1,2,4]triazolo[4,3-a]pyrazine-7(8H)carboxylate
  • 3-[1-(Trifluoroacetyl)pyrrolidin-3-yl]propanoic acid
  • Methyl 3-isopropyl-1,2,4-thiadiazole-5-carboxylate
  • tert-butyl 4-(1H-1,2,3,4-tetrazol-5-yl)benzoate
  • tert-butyl 3-(2-methyl-1,3-thiazol-4-yl)-6,8-dihydro-5H-[1,2,4]triazolo[4,3-a]pyrazine-7-carboxylate
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