Phenacyl Bromide

Suppliers

Names

[ Name ]:
Phenacyl Bromide

[Synonym ]:
ortho-bromoacetophenone
Phenacyl Bromide
2‘-Bromoacetophenone
2-Bromoacetophenone
EINECS 218-398-1
2′-Bromoacetophenone
Ethanone, 1- (2-bromophenyl)-
o-Bromoacetophenone
Ethanone, 1-(2-bromophenyl)-
o-MeOC-Ph-Br
1-(2-Bromophenyl)ethanone
2-Bromo-1-phenylethanone
2'-Bromoacetophenone
Acetophenone, o-bromo-
o-bromoacetophnones
MFCD00000067
α-Bromoacetophenone
o-MeOC-C6H4-Br
Acetophenone, 2'-bromo-
acetophenone, 2-bromo-
2'-BromoActophenone
Ethanone, 2-bromo-1-phenyl-
1-ACETYL-2-BROMOBENZENE
2-Bromo-1-Phenylethan-1-One
1-Bromo-2-acetylbenzene
Acetophenone,o-bromo
2-Acetyl-1-bromobenzene

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
249.0±23.0 °C at 760 mmHg

[ Melting Point ]:
°C

[ Molecular Formula ]:
C₈H₇BrO

[ Molecular Weight ]:
199.05

[ Flash Point ]:
86.6±9.9 °C

[ Exact Mass ]:
197.968018

[ PSA ]:
17.07000

[ LogP ]:
2.28

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.554

[ Storage condition ]:
-20°C

[ Water Solubility ]:
PRACTICALLY INSOLUBLE

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ Packaging Group ]:
I; II; III

[ Hazard Class ]:
6.1

[ HS Code ]:
29147090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

1-Bromo-2-ethynylbenzene
1-(2'-BROMOPHENYL)-1-HYDROXYETHANE
Acetophenone
METHYLMAGNESIUM BROMIDE
2-Bromobenzoyl chloride
Methyl 3-(2-bromophenyl)-3-oxopropanoate
2-Bromoethylbenzene
2-Bromobenzaldehyde
Trimethyl(vinyloxy)silane

DownStream

1-(2-bromophenyl)-3-phenylprop-2-en-1-one
2-(2-(DICYCLOHEXYLPHOSPHINO)PHENYL)-1-METHYL-1H-INDOLE
1-(2-(METHYLTHIO)PHENYL)ETHANONE
Acetophenone
1-[2-(2-acetylphenyl)sulfanylphenyl]ethanone
2'-Aminoacetophenone
4-methyl-2-phenylquinazoline
2-(2-Bromophenyl)-2-methyl-1,3-dioxolane
ether
Methylbenzylalcohol

Customs

[ HS Code ]: 2914700090

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

Articles

Enantioselective alkynylation of aromatic ketones catalyzed by chiral camphorsulfonamide ligands.

Angew. Chem. Int. Ed. Engl. 42(41) , 5057-8, (2003)

Non-Condensed Trifluoromethylated 5, 5-Bicycles: Synthesis of 2-[3-Alkyl (phenyl)-1H-pyrazol-1-yl]-4-phenyl-5-alkylthiazole and-4, 5, 6, 7-tetrahydrobenzothiazole Systems. Bonacorso HG, et al.

Synthesis 2002(08) , 1079-83, (3003)

Palladium-catalysed convenient synthesis of 3-methyleneisoindolin-1-ones. Cho CS, et al.

Synth. Commun. 32(!2) , 1821-27, (2002)

Phenacyl Bromide
Phenacyl Bromide
phenacyl bromide
phenacyl bromide oxime
phenacyl bromide oxime
3-iodophenacyl bromide
Ethaneboronic acid, 2-ureido-, dimethyl ester
Methyl 4-amino-1,2,3,4-tetrahydronaphthalene-1-carboxylate
Ethyl 3-iodo-1-(3,3,3-trifluoropropyl)pyrazole-4-carboxylate
tert-Butyl 2-(5-amino-3-methyl-1H-pyrazol-1-yl)acetate
methyl 3-bromo-1-isobutyl-1H-pyrazole-4-carboxylate
Propanamide, N-[4-[[1-(4-ethylphenyl)-4-[(2-furanylmethyl)thio]-2,5-dihydro-2,5-dioxo-1H-pyrrol-3-yl]amino]phenyl]-
(6R)-5-Benzyl-2-(4-methylphenyl)sulfonyl-6-propan-2-yl-8-oxa-2,5-diazaspiro[3.5]nonane
Methyl 2-methyl-5-(trifluoromethyl)pyridine-4-carboxylate
1,1-Bis(chloromethyl)-2-fluorocyclopropane
5-fluoro-4-nitro-1-(propan-2-yl)-1H-pyrazole

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