(1S,2S)-(+)-1,2-Diaminocyclohexane

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Names

[ CAS No. ]:
21436-03-3

[ Name ]:
(1S,2S)-(+)-1,2-Diaminocyclohexane

[Synonym ]:
(1S,2S)-(+)-1,2-Diaminocyclohexane
(+)-S,S-1,2-Diaminocyclohexane
1,2-Cyclohexanediamine, (1S,2S)-
(1S,2S)-1,2-Cyclohexanediamine
(1S,2S)-Cyclohexan-1,2-diamin
trans-1,2-Diaminocyclohexane
(1S,2S)-(+)-Cyclohexane-1,2-diamine
ss-diaminocyclohexane
(1S)-(+)-trans-1,2-Diaminocyclohexane
s-dach
(1S,2S)-Cyclohexane-1,2-diamine
trans-1,2-Cyclohexanediamine
(1S,2S)-(+)-1,2-Cyclohexanediamine
MFCD00062986

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
193.6±0.0 °C at 760 mmHg

[ Melting Point ]:
40-43 °C(lit.)

[ Molecular Formula ]:
C6H14N2

[ Molecular Weight ]:
114.19

[ Flash Point ]:
75.0±0.0 °C

[ Exact Mass ]:
114.115700

[ PSA ]:
52.04000

[ LogP ]:
-0.12

[ Vapour Pressure ]:
0.5±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.484

[ Water Solubility ]:
soluble

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 3259 8/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
2942000000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • (1S,2S)-2-azido-N-((R)-1-phenylethyl)cyclohexanamine
  • (R,R)-(-)-1,2-Diaminocyclohexane
  • Tartaric acid
  • Cyclohexene oxide
  • 7-((R)-1-phenylethyl)-7-azabicyclo[4.1.0]heptane
  • 2-(((R)-1-phenylethyl)amino)cyclohexanol
  • Dimethyl malonate
  • 1,2-Diaminocyclohexane
  • Cyclohexene
  • Nioxime

DownStream

  • tert-Butyl-[(1R,2R)-2-aminocyclohexyl]carbamat
  • tert-Butyl (2-aminocyclohexyl)carbamate
  • (1S,2S)-1,2-N,N'-bis[(methane-sulfonyl)amino]-cyclohexane
  • N,N'-Dimethyl-1,2-cyclohexanediamine
  • 1-(3-triethoxysilylpropyl)-3-[(1S,2S)-2-(3-triethoxysilylpropylcarbamoylamino)cyclohexyl]urea
  • (R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine
  • (S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine
  • (1S,2S)-(-)-N-(4-TOLUENESULPHONYL)-1,2-DIAMINOCYCLOHEXANE
  • 1-(4-methylphenyl)indole
  • (1s,2s)-(-)-n,n-di-p-tosyl-1,2-cyclohexanediamine

Customs

[ HS Code ]: 2921300090

[ Summary ]:
2921300090 other cyclanic, cyclenic or cyclotherpenic mono- or polyamines, and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

Steric modifications tune the regioselectivity of the alkane oxidation catalyzed by non-heme iron complexes.

Inorg. Chem. 50(24) , 12651-60, (2011)

Iron complexes with the tetradentate N-donor ligand N,N'-di(phenylmethyl)-N,N'-bis(2-pyridinylmethyl)-1,2-cyclohexanediamine (bbpc) are reported. Despite the benzyl groups present on the amines, the i...

Antitumor platinum(II) complexes of N-monoalkyl-1R, 2R-diaminocyclohexane derivatives with alkyl groups as hindrance.

J. Inorg. Biochem. 112 , 68-76, (2012)

A number of platinum (II) complexes, characteristic of (1R,2R)-N(1)-alkyl-1,2-diaminocyclohexane derivatives as carrier ligands, were designed, synthesized and characterized, where the alkyl group ser...

Synthesis, in vitro cytotoxicity, and interaction with DNA of platinum(II) complexes with N-monocycloalkyl derivatives of 1R,2R-diaminocyclohexane as carrier ligands.

ChemMedChem 7(4) , 642-9, (2012)

A series of platinum(II) complexes with N-monocyclopentyl/cyclohexyl derivatives of 1R,2R-diaminocyclohexane as carrier ligands and dicarboxylate anions as leaving groups were synthesized and characte...


More Articles

Related Compounds

  • (1S,2S)-(+)-1,2-Diaminocyclohexane
  • N-Toluenesulfonyl-(1S,2S)-(+)-1,2-diaminocyclohexane
  • (1S,2S)-(+)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)cobalt(III) p-toluenesulfonate monohydrate
  • (1s,2s)-(+)-[1,2-cyclohexanediamino-n n'-bis(3,5-di-t-butylsalicylidene)]aluminum (iii) chloride
  • (1S,2S)-(+)-1,2-BIS[(N-DIPHENYLPHOSPHINO)AMINO]CYCLOHEXANE
  • (1S,2S)-(+)-1,2-bis(phenylmethoxy)cyclopentane
  • 3-(4-methoxyphenyl)-9-(3-methoxypropyl)-4-methyl-9,10-dihydrochromeno[8,7-e][1,3]oxazin-2(8H)-one
  • 3-(3,4-dimethoxyphenyl)-9-(3-methoxypropyl)-9,10-dihydrochromeno[8,7-e][1,3]oxazin-2(8H)-one
  • 3-(3,4-dimethoxyphenyl)-9-(3-methoxypropyl)-4-methyl-9,10-dihydrochromeno[8,7-e][1,3]oxazin-2(8H)-one
  • 3-(2,5-dimethoxyphenyl)-9-(3-methoxypropyl)-9,10-dihydrochromeno[8,7-e][1,3]oxazin-2(8H)-one
  • (Z)-ethyl 1-((6-hydroxy-7-methyl-3-oxobenzofuran-2(3H)-ylidene)methyl)piperidine-4-carboxylate
  • (2Z)-2-(1,4-dioxa-8-azaspiro[4.5]dec-8-ylmethylidene)-6-hydroxy-7-methyl-1-benzofuran-3(2H)-one
  • (Z)-ethyl 4-((6-hydroxy-7-methyl-3-oxobenzofuran-2(3H)-ylidene)methyl)piperazine-1-carboxylate
  • 1-Ethyl-6-fluoro-7-[4-[(2-methylpropan-2-yl)oxycarbonyl]piperazin-1-yl]-4-oxo-1,8-naphthyridine-3-carboxylic acid
  • 4-[(7-methoxy-4-oxo-4H-chromen-3-yl)oxy]-N-(2-methoxyphenyl)benzamide
  • 9-(furan-2-ylmethyl)-3-phenyl-9,10-dihydro-2H,8H-chromeno[8,7-e][1,3]oxazin-2-one
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