(+)-TETRAPHOS

Names

[ CAS No. ]:
21451-74-1

[ Name ]:
(+)-TETRAPHOS

[Synonym ]:
Troeger base
MFCD00151117

Chemical & Physical Properties

[ Density]:
1.21g/cm3

[ Boiling Point ]:
461ºC at 760mmHg

[ Melting Point ]:
127-131ºC(lit.)

[ Molecular Formula ]:
C₁₇H₁₈N₂

[ Molecular Weight ]:
250.33800

[ Flash Point ]:
213.5ºC

[ Exact Mass ]:
250.14700

[ PSA ]:
6.48000

[ LogP ]:
3.73110

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

6H,12H-5,11-Methanodibenzo[b,f][1,5]diazocine,2,8-dimethyl-
p-Toluidine

DownStream

Articles

The covalently bonded cellulose tris(3,5-dimethylphenylcarbamate) on a silica monolithic capillary column for enantioseparation in capillary electrochromatography.

J. Chromatogr. B. Analyt. Technol. Biomed. Life Sci. 875(1) , 317-22, (2008)

A chiral capillary monolithic column for capillary electrochromatography (CEC) was prepared by covalent bonding of cellulose tris(3,5-dimethylphenylcarbamate) (CDMPC) on the silica monolithic matrix w...

Resolution, asymmetric transformation, and configuration of Tröger's base. Application of Tröger's base as a chiral solvating agent. Wilen, Samuel H., Jian Zhong Qi, and Paul G. Williard

Organic Chemistry 56 , 485-487, (1991)

V. Prelog, P. Wieland

Helv. Chim. Acta 27 , 1127, (1944)

(+)-tetraphos
(+/-)-4-(2-furyl)-butan-2-ol acetate
(+)-5-methylcyclohex-2-en-1-one
(+)-(3R,4S)-4-hydroxy-3-methylnonan-2-one
(+/-)-2,5-hexanediol
(+)-alpha-terpineol
N-[(1r,4r)-4-(pyrazin-2-yloxy)cyclohexyl]-1H-indole-3-carboxamide
N-((1r,4r)-4-(pyrazin-2-yloxy)cyclohexyl)-2,3-dihydrobenzo[b][1,4]dioxine-2-carboxamide
6-Fluoropyrazolo[1,5-a]pyrimidin-5-amine
2-(2-chlorophenyl)-N-((1r,4r)-4-(pyrazin-2-yloxy)cyclohexyl)acetamide
4-methyl-N-((1r,4r)-4-(pyrazin-2-yloxy)cyclohexyl)-1,2,3-thiadiazole-5-carboxamide
1-methanesulfonyl-N-[(1r,4r)-4-(pyrazin-2-yloxy)cyclohexyl]piperidine-4-carboxamide
2-(2-oxobenzo[d]oxazol-3(2H)-yl)-N-((1r,4r)-4-(pyrazin-2-yloxy)cyclohexyl)acetamide
N-[4-(pyrazin-2-yloxy)cyclohexyl]pyridine-4-carboxamide
5-methyl-N-((1r,4r)-4-(pyrazin-2-yloxy)cyclohexyl)isoxazole-3-carboxamide
4-cyano-N-((1r,4r)-4-(pyrazin-2-yloxy)cyclohexyl)benzamide

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