(+)-TETRAPHOS

Names

[ CAS No. ]:
21451-74-1

[ Name ]:
(+)-TETRAPHOS

[Synonym ]:
Troeger base
MFCD00151117

Chemical & Physical Properties

[ Density]:
1.21g/cm3

[ Boiling Point ]:
461ºC at 760mmHg

[ Melting Point ]:
127-131ºC(lit.)

[ Molecular Formula ]:
C₁₇H₁₈N₂

[ Molecular Weight ]:
250.33800

[ Flash Point ]:
213.5ºC

[ Exact Mass ]:
250.14700

[ PSA ]:
6.48000

[ LogP ]:
3.73110

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

6H,12H-5,11-Methanodibenzo[b,f][1,5]diazocine,2,8-dimethyl-
p-Toluidine

DownStream

Articles

The covalently bonded cellulose tris(3,5-dimethylphenylcarbamate) on a silica monolithic capillary column for enantioseparation in capillary electrochromatography.

J. Chromatogr. B. Analyt. Technol. Biomed. Life Sci. 875(1) , 317-22, (2008)

A chiral capillary monolithic column for capillary electrochromatography (CEC) was prepared by covalent bonding of cellulose tris(3,5-dimethylphenylcarbamate) (CDMPC) on the silica monolithic matrix w...

Resolution, asymmetric transformation, and configuration of Tröger's base. Application of Tröger's base as a chiral solvating agent. Wilen, Samuel H., Jian Zhong Qi, and Paul G. Williard

Organic Chemistry 56 , 485-487, (1991)

V. Prelog, P. Wieland

Helv. Chim. Acta 27 , 1127, (1944)

(+)-tetraphos
(+/-)-4-(2-furyl)-butan-2-ol acetate
(+)-5-methylcyclohex-2-en-1-one
(+)-(3R,4S)-4-hydroxy-3-methylnonan-2-one
(+/-)-2,5-hexanediol
(+)-alpha-terpineol
2-[3-(Hydroxymethyl)-4-oxo-2-phenyl-4H,5H-pyrazolo[1,5-A]pyrazin-5-YL]-N-[4-(trifluoromethyl)phenyl]acetamide
N-(3,4-Dimethylphenyl)-2-[3-(hydroxymethyl)-4-oxo-2-phenyl-4H,5H-pyrazolo[1,5-A]pyrazin-5-YL]acetamide
Tert-butyl 4-((3-(2-methoxyphenyl)ureido)methyl)piperidine-1-carboxylate
2-(4-fluorophenyl)-7-[(2-thienylmethyl)amino]-6,7-dihydropyrazolo[1,5-a]pyrazin-4(5H)-one
N-(4-Bromo-3-methylphenyl)-2-[3-(hydroxymethyl)-4-oxo-2-phenyl-4H,5H-pyrazolo[1,5-A]pyrazin-5-YL]acetamide
N-(4-Chloro-2-methoxy-5-methylphenyl)-2-[3-(hydroxymethyl)-4-oxo-2-phenyl-4H,5H-pyrazolo[1,5-A]pyrazin-5-YL]acetamide
N-(2,3-Dihydro-1H-inden-5-YL)-2-[3-(hydroxymethyl)-4-oxo-2-phenyl-4H,5H-pyrazolo[1,5-A]pyrazin-5-YL]acetamide
N-[(2,4-Difluorophenyl)methyl]-2-[3-(hydroxymethyl)-4-oxo-2-phenyl-4H,5H-pyrazolo[1,5-A]pyrazin-5-YL]acetamide
N-[4-(Dimethylamino)phenyl]-2-[2-(4-fluorophenyl)-4-methyl-6-oxo-1,6-dihydropyrimidin-1-YL]acetamide
N-(3-Chloro-4-methoxyphenyl)-2-[2-(4-fluorophenyl)-4-methyl-6-oxo-1,6-dihydropyrimidin-1-YL]acetamide

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