(+)-TETRAPHOS

Names

[ CAS No. ]:
21451-74-1

[ Name ]:
(+)-TETRAPHOS

[Synonym ]:
Troeger base
MFCD00151117

Chemical & Physical Properties

[ Density]:
1.21g/cm3

[ Boiling Point ]:
461ºC at 760mmHg

[ Melting Point ]:
127-131ºC(lit.)

[ Molecular Formula ]:
C₁₇H₁₈N₂

[ Molecular Weight ]:
250.33800

[ Flash Point ]:
213.5ºC

[ Exact Mass ]:
250.14700

[ PSA ]:
6.48000

[ LogP ]:
3.73110

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

6H,12H-5,11-Methanodibenzo[b,f][1,5]diazocine,2,8-dimethyl-
p-Toluidine

DownStream

Articles

The covalently bonded cellulose tris(3,5-dimethylphenylcarbamate) on a silica monolithic capillary column for enantioseparation in capillary electrochromatography.

J. Chromatogr. B. Analyt. Technol. Biomed. Life Sci. 875(1) , 317-22, (2008)

A chiral capillary monolithic column for capillary electrochromatography (CEC) was prepared by covalent bonding of cellulose tris(3,5-dimethylphenylcarbamate) (CDMPC) on the silica monolithic matrix w...

Resolution, asymmetric transformation, and configuration of Tröger's base. Application of Tröger's base as a chiral solvating agent. Wilen, Samuel H., Jian Zhong Qi, and Paul G. Williard

Organic Chemistry 56 , 485-487, (1991)

V. Prelog, P. Wieland

Helv. Chim. Acta 27 , 1127, (1944)

(+)-tetraphos
(+/-)-4-(2-furyl)-butan-2-ol acetate
(+)-5-methylcyclohex-2-en-1-one
(+)-(3R,4S)-4-hydroxy-3-methylnonan-2-one
(+/-)-2,5-hexanediol
(+)-alpha-terpineol
2-amino-3-chloro-N-(4-chlorophenyl)-5-(trifluoromethyl)pyridine-4-carboxamide
3-Chloro-4-(4-methylpiperazine-1-carbonyl)-5-(trifluoromethyl)pyridin-2-amine
3-{2-[3-Chloro-5-(trifluoromethyl)pyridin-2-yl]ethyl}-1-(4-chlorophenyl)urea
N-{2-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]ethyl}-3-methoxybenzamide
N-{2-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]ethyl}-1,1,1-trifluoromethanesulfonamide
methyl N-{2-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]ethyl}carbamate
1-{2-[3-Chloro-5-(trifluoromethyl)pyridin-2-yl]ethyl}-3,3-dimethylurea
1-{2-[3-Chloro-5-(trifluoromethyl)pyridin-2-yl]ethyl}-3-ethylurea
N-{2-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]ethyl}-2,2,2-trifluoroacetamide
1-methanesulfonyl-4-[5-(trifluoromethyl)-1H-pyrrolo[2,3-b]pyridine-2-carbonyl]piperazine