(+)-TETRAPHOS

Suppliers

Names

[ CAS No. ]:
21451-74-1

[ Name ]:
(+)-TETRAPHOS

[Synonym ]:
Troeger base
MFCD00151117

Chemical & Physical Properties

[ Density]:
1.21g/cm3

[ Boiling Point ]:
461ºC at 760mmHg

[ Melting Point ]:
127-131ºC(lit.)

[ Molecular Formula ]:
C17H18N2

[ Molecular Weight ]:
250.33800

[ Flash Point ]:
213.5ºC

[ Exact Mass ]:
250.14700

[ PSA ]:
6.48000

[ LogP ]:
3.73110

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Synthetic Route

Precursor & DownStream

Precursor

  • 6H,12H-5,11-Methanodibenzo[b,f][1,5]diazocine,2,8-dimethyl-
  • p-Toluidine

DownStream

Articles

The covalently bonded cellulose tris(3,5-dimethylphenylcarbamate) on a silica monolithic capillary column for enantioseparation in capillary electrochromatography.

J. Chromatogr. B. Analyt. Technol. Biomed. Life Sci. 875(1) , 317-22, (2008)

A chiral capillary monolithic column for capillary electrochromatography (CEC) was prepared by covalent bonding of cellulose tris(3,5-dimethylphenylcarbamate) (CDMPC) on the silica monolithic matrix w...

Resolution, asymmetric transformation, and configuration of Tröger's base. Application of Tröger's base as a chiral solvating agent. Wilen, Samuel H., Jian Zhong Qi, and Paul G. Williard

Organic Chemistry 56 , 485-487, (1991)

V. Prelog, P. Wieland

Helv. Chim. Acta 27 , 1127, (1944)


More Articles


Related Compounds

  • (+)-tetraphos
  • (+/-)-4-(2-furyl)-butan-2-ol acetate
  • (+)-5-methylcyclohex-2-en-1-one
  • (+)-(3R,4S)-4-hydroxy-3-methylnonan-2-one
  • (+/-)-2,5-hexanediol
  • (+)-alpha-terpineol
  • 3-(1H-1,2,3,4-tetrazol-5-yl)morpholine
  • Paraminabeolide C
  • Paraminabeolide E
  • 4-(2-Chloroacetyl)-5-methylfuran-2-carboxamide
  • 1-[(Cyclopentylcarbamoyl)methyl]pyrrolidine-3-carboxylic acid
  • Paraminabeolide F
  • Methyl (3-methyl-5-t-butyl-4-hydroxyphenyl)acetate
  • 2-Amino-N-methoxy-N-methyl-4-(methylsulfanyl)butanamide
  • 2-Bromo-5-(bromomethyl)-3-methylpyridine
  • 6-((benzyloxy)methyl)-2-thioxo-2,3-dihydropyrimidin-4(1H)-one
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