Benzaldehyde,2-hydroxy-3-methoxy-, oxime

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Names

[ CAS No. ]:
2169-99-5

[ Name ]:
Benzaldehyde,2-hydroxy-3-methoxy-, oxime

[Synonym ]:
m-Anisaldehyde,2-hydroxy-,oxime
2-Hydroxy-3-methoxybenzaldehyde oxime
2-hydroxy-3-methoxy benzaldoxime
3-methoxy-2-hydroxybenzaldoxime
o-vanilin oxime
o-Vanillin oxime
3-methoxysalicylaldoxime
2-Hydroxy-m-anisaldehyde oxime

Chemical & Physical Properties

[ Density]:
1.27g/cm3

[ Boiling Point ]:
345.3ºC at 760mmHg

[ Melting Point ]:
124 °C

[ Molecular Formula ]:
C8H9NO3

[ Molecular Weight ]:
167.16200

[ Flash Point ]:
162.6ºC

[ Exact Mass ]:
167.05800

[ PSA ]:
62.05000

[ LogP ]:
1.20890

[ Vapour Pressure ]:
3.93E-06mmHg at 25°C

[ Index of Refraction ]:
1.577

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
BZ2930000
CHEMICAL NAME :
m-Anisaldehyde, 2-hydroxy-, oxime
CAS REGISTRY NUMBER :
2169-99-5
BEILSTEIN REFERENCE NO. :
2413960
LAST UPDATED :
199612
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C8-H9-N-O3
MOLECULAR WEIGHT :
167.18

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
>2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
MEXPAG Medicina Experimentalis. (Basel, Switzerland) V.1-11, 1959-64; V.18-19, 1968-69. For publisher information, see JNMDBO. Volume(issue)/page/year: 11,137,1964

Safety Information

[ Hazard Codes ]:
T+

[ HS Code ]:
2928000090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 3-Methoxysalicylaldehyde

DownStream

  • 2H-1-Benzopyran-3-carboxylicacid, 8-methoxy-2-oxo-
  • 2-Hydroxy-3-methoxybenzonitrile
  • 3-Methoxysalicylaldehyde
  • 1-(2-hydroxy-3-methoxyphenyl)propan-1-one
  • 2-HYDROXY-3-METHOXYBENZYLAMINE
  • O-(2-cyano-6-methoxyphenyl) N,N-dimethylcarbamothioate
  • S-(2-cyano-6-methoxyphenyl) N,N-dimethylcarbamothioate
  • 3-methoxy-2-sulfanylbenzonitrile
  • 1-(3-amino-7-methoxy-1-benzothiophen-2-yl)ethanone
  • N-hydroxy-8-methoxy-2-oxochromene-3-carboxamide

Customs

[ HS Code ]: 2928000090

[ Summary ]:
2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

Related Compounds

  • 2-HYDROXY-3-METHOXYBENZALDEHYDE OXIME
  • Benzaldehyde, 2-hydroxy-3-methoxy-6-nitro-
  • Benzaldehyde,2-hydroxy-3-methoxy-, 2-(5-nitro-2-pyridinyl)hydrazone
  • 2-hydroxy-3-methoxy-6-methylbenzaldehyde
  • 2-HYDROXY-3-METHOXY-4,5-DIMETHYL-BENZALDEHYDE
  • 2-hydroxy-3-methoxy-5-morpholin-4-ylmethyl-benzaldehyde
  • methyl 4-amino-1-(3-methylbutan-2-yl)-1H-pyrrole-2-carboxylate
  • (9H-fluoren-9-yl)methyl N-[(4-hydroxyphenyl)methyl]-N-methylcarbamate
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 2-[3-(Methoxymethyl)phenyl]-1-methylpiperazine
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 3-Methyl-1-[2-(pyridin-4-yl)ethyl]-1,2,3,4-tetrahydropyrimidine-2,4-dione
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • rac-(1R,2R)-2-(3-bromopyridin-2-yl)cyclopropan-1-amine
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol