Diallyl disulfide

Suppliers

Names

[ Name ]:
Diallyl disulfide

[Synonym ]:
2-Propenyl disulfide
3-(prop-2-en-1-yldisulfanyl)prop-1-ene
Diallyl disulfide
EINECS 218-548-6
disulfide, diallyl
Diallyldisulfide
diallyic disulfide
3-(Allyldisulfanyl)prop-1-ene
Allyl disulfide
Disulfide,di-2-propenyl
3-(prop-2-enyldisulfanyl)prop-1-ene
Diallyldisulfide,remainder mainly diallyl sulfide
Allyl disulphide
diallyl disulphide
Disulfide, di-2-propen-1-yl
MFCD00008656
3-(Allyldisulfanyl)-1-propene
4,5-Dithia-1,7-octadiene
diprop-2-en-1-yl disulfide
2-propenyl disulphide

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
185.0±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C₆H₁₀S₂

[ Molecular Weight ]:
146.274

[ Flash Point ]:
42.4±25.8 °C

[ Exact Mass ]:
146.022385

[ PSA ]:
50.60000

[ LogP ]:
3.26

[ Vapour density ]:
>5 (vs air)

[ Vapour Pressure ]:
1.0±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.534

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: BB1000000

CHEMICAL NAME :: Allyl disulfide

CAS REGISTRY NUMBER :: 2179-57-9

BEILSTEIN REFERENCE NO. :: 1699241

LAST UPDATED :: 199801

DATA ITEMS CITED :: 6

MOLECULAR FORMULA :: C6-H10-S2

MOLECULAR WEIGHT :: 146.28

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 260 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 3600 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 878 mg/kg/6D-I

TOXIC EFFECTS :: Endocrine - other changes Endocrine - changes in spleen weight Blood - pigmented or nucleated red blood cells

MUTATION DATA

TYPE OF TEST :: Sister chromatid exchange

TEST SYSTEM :: Rodent - hamster Ovary

DOSE/DURATION :: 10 mg/L

REFERENCE :: FCTOD7 Food and Chemical Toxicology. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.20- 1982- Volume(issue)/page/year: 35,379,1997

Safety Information

[ Symbol ]:

GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H315-H319-H335

[ Precautionary Statements ]:
Missing Phrase - N15.00950417-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R10;R22;R36/37/38

[ Safety Phrases ]:
S26-S36/37/39-S37/39-S16

[ RIDADR ]:
UN 2810 6.1/PG 3

[ WGK Germany ]:
3

[ RTECS ]:
BB1000000

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1

[ HS Code ]:
3911900004

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Allyl mercaptan
allyl bromide
ALLYL CHLORIDE
allyl thiocyanate
allyl toluene-4-sulfonate
diallylselenide
Allicin
Allyl Sulfide
allyl iodide
S-Allyl-L-cysteine

DownStream

1-ethenylsulfanylprop-1-ene
1,2-bis(1-propylenylthio)ethene
Allyl Sulfide
(E)-allyl 1-propenyl sulfide
di-(1-propanyl) sulfide
1-vinylthio-3-allylthio-1-propene
3-vinyl-4H-1,2-dithiin
Diallyl trisulfide
Diallyl Tetrasulfide

Customs

[ HS Code ]: 2930909090

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Optimizations of packed sorbent and inlet temperature for large volume-direct aqueous injection-gas chromatography to determine high boiling volatile organic compounds in water.

J. Chromatogr. A. 1356 , 221-9, (2014)

For the expanded application area, fast trace analysis of certain high boiling point (i.e., 150-250 °C) volatile organic compounds (HVOCs) in water, a large volume-direct aqueous injection-gas chromat...

Effect of processing conditions on the organosulfides of shallot (Allium cepa L. Aggregatum group).

J. Agric. Food Chem. 62(23) , 5296-304, (2014)

There is a growing account of the health benefits of H2S as an endogenous cell-signaling molecule. H2S from organic polysulfides, in particular, is increasingly gaining attention for their beneficial ...

The defense substance allicin from garlic permeabilizes membranes of Beta vulgaris, Rhoeo discolor, Chara corallina and artificial lipid bilayers.

Biochim. Biophys. Acta 1850(4) , 602-11, (2015)

Allicin (diallylthiosulfinate) is the major volatile- and antimicrobial substance produced by garlic cells upon wounding. We tested the hypothesis that allicin affects membrane function and investigat...