Trimethylsulfonium iodide

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Names

[ CAS No. ]:
2181-42-2

[ Name ]:
Trimethylsulfonium iodide

[Synonym ]:
trimethylsulfanium iodide
trimethylsulphonium iodide
Sulfonium,trimethyl-,iodide
trimethylsulfonium iodode
Corey-Chaykovsky reagent
Trimethyl sulfonium iodide
Sulfonium, trimethyl-, iodide (1:1)
EINECS 218-555-4
Trimethylsulfonium iodide
MFCD00011632

Chemical & Physical Properties

[ Melting Point ]:
215-220 °C(lit.)

[ Molecular Formula ]:
C3H9IS

[ Molecular Weight ]:
204.073

[ Exact Mass ]:
203.946960

[ PSA ]:
25.30000

[ Water Solubility ]:
soluble

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
WR8750000
CHEMICAL NAME :
Sulfonium, trimethyl-, iodide
CAS REGISTRY NUMBER :
2181-42-2
LAST UPDATED :
199701
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C3-H9-S.I
MOLECULAR WEIGHT :
204.08
WISWESSER LINE NOTATION :
1S1&1 &I

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
88 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 20,135,1971
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
300 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 25,315,1925
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
18 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#02185

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
WR8750000

[ HS Code ]:
29309070

Synthetic Route

Precursor & DownStream

Precursor

  • dms
  • methyl iodide
  • Diiodomethane
  • Methyl mercaptan
  • Allyl Sulfide
  • METHALLYLSULPHIDE
  • 1,3,5-trithiane
  • (fluoren-2-yl-phenyl-methyl)-methyl sulfide
  • Dimethyl disulfide
  • Dimethyl trisulfide

DownStream

  • 4-(2-Methyloxiran-2-yl)benzonitrile
  • 2-[4-(trifluoromethoxy)phenyl]oxirane
  • Trimethylsulfonium-d9 iodide
  • 4-Vinyl-1,3-dioxolan-2-one
  • 2-(4-bromophenyl)oxirane
  • 1,2-epoxyheptane
  • 3-Phenylpropene-3-ol
  • β-methylenephenethyl alcohol
  • 1-hepten-3-ol
  • Ethyl 1-oxaspiro[2.5]octane-6-carboxylate

Customs

[ HS Code ]: 2930909090

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Interferences in the direct quantification of bisphenol S in paper by means of thermochemolysis.

J. Chromatogr. A. 1275 , 70-7, (2013)

This article analyses the interferences in the quantification of traces of bisphenol S in paper by applying the direct analytical method "analytical pyrolysis gas chromatography mass spectrometry" (Py...

A high-throughput fatty acid profiling screen reveals novel variations in fatty acid biosynthesis in Chlamydomonas reinhardtii and related algae.

Eukaryotic Cell 13(11) , 1431-8, (2014)

Analysis of fatty acid methyl esters (FAMEs) by gas chromatography (GC) is a common technique for the quantitative and qualitative analysis of acyl lipids. Methods for FAME preparation are typically t...

S-methyl derivatives from thiol compounds by the pyrolytic reaction with trimethylsulfonium hydroxide.

Lipids 33(10) , 1037-41, (1998)

Base-catalyzed transesterification of acyl lipids with methanol in the presence of trimethylsulfonium hydroxide (TMSH) is an easy and convenient method for the preparation of fatty acid methyl esters ...


More Articles


Related Compounds

  • trimethylsulfonium iodide-d9
  • trimethylsulfonium iodide-d3
  • trimethylsulfonium iodide-d3
  • trimethylsulfonium methyl sulfate
  • Trimethylsulfonium Fluoride
  • trimethylsulfonium triflate
  • 5-Methylamino-2,4,6-triiodoisophthalic acid dichloride
  • 3-(4-chlorobutyl)-1H-indole-5-carboxamide
  • O-(4-fluorobenzoyl)hydroxylamine
  • 2-But-3-ynyl-quinoline
  • 2-(6,6-Dimethylbicyclo[3.1.1]hept-2-yl)propanal
  • Methyl 2-hydroxy-4-(1-tert-butyloxycarbonyl-3-pyrrolidinyloxy)benzoate
  • 3-Benzyloxy-4-methyl-benzoyl chloride
  • [(1R,2R,5S,7S,8S,9S)-2,6,6,8-tetramethyl-9-tricyclo[5.3.1.01,5]undecanyl] acetate
  • 1-(2,3-Difluoro-4-hydroxyphenyl)propan-1-one
  • Triisopropylsilyltrifluoromethane
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