Tetrachlorobis(tetrahydrofuran)zirconium

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Names

[ CAS No. ]:
21959-01-3

[ Name ]:
Tetrachlorobis(tetrahydrofuran)zirconium

[Synonym ]:
ZrCl4(tetrahydrofuran)2
[ZrCl4(thf)2]
Zirconium(IV) chloride tetrahydrofuran complex (1:2)
tetrachlorobis(tetrahydrofuran-O)zirconium(IV)
MFCD00145367
Tetrachlorobis(tetrahydrofuran)zirconium
Tetrachlorobis(tetrahydrofuran)zirconium(IV)
Zirconium tetrachloride tetrahydrofuran complex

Chemical & Physical Properties

[ Melting Point ]:
175-177 °C(lit.)

[ Molecular Formula ]:
C8H16Cl4O2Zr

[ Molecular Weight ]:
377.24700

[ Exact Mass ]:
373.89500

[ PSA ]:
18.46000

[ LogP ]:
4.35160

[ Appearance of Characters ]:
crystal，white

[ Vapour Pressure ]:
152mmHg at 25°C

[ Storage condition ]:
0-6°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H228-H302 + H312 + H332-H314

[ Precautionary Statements ]:
P210-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R20/21/22;R34

[ Safety Phrases ]:
S22-S26-S36/37/39-S45

[ RIDADR ]:
UN 2925 4.1/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
8

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • thf
  • Zirconium(2+) chloride (1:2)

DownStream

  • 2-pentylcyclopenta-1,3-diene,zirconium(4+),dichloride
  • Bis(methylcyclopentadienyl)zirconium dichloride
  • Bis(2-methylindenyl)zirconiumdichloride

Preparation


Related Compounds

  • tetrachlorobis(tetrahydrofuran)niobium(IV)
  • HAFNIUM CHLORIDE TETRAHYDROFURAN COMPLEX (1:2)
  • tetrachlorobis(trimethylphosphine)niobium(IV)
  • tetrachlorobis[4-(dimethylamino)pyridine]phosphorus(V) chloride
  • tetrachlorobis{1,1'-oxybis(ethane)}molybdenum(IV)
  • tetrachlorobis(ethyl cyanide)molybdenum(IV)