3-Bromo-4-methoxytoluene

Suppliers

Names

[ CAS No. ]:
22002-45-5

[ Name ]:
3-Bromo-4-methoxytoluene

[Synonym ]:
MFCD00017783
2-Bromo-1-methoxy-4-methylbenzene
2-bromo-4-methylphenyl methyl ether
Benzene, 2-bromo-1-methoxy-4-methyl-
2-Bromo-4-methyl anisole
4-methyl-2-bromoanisole
EINECS 244-705-3
2-bromo-1-methoxy-4-methyl-benzene
Benzene,2-bromo-1-methoxy-4-methyl
anisole, 2-bromo-4-methyl-
Anisole,2-bromo-4-methyl
3-BroMo-4-Methoxytoluene
1-bromo-2-methoxy-5-methylbenzene

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
227.9±20.0 °C at 760 mmHg

[ Melting Point ]:
15.5 °C(lit.)

[ Molecular Formula ]:
C₈H₉BrO

[ Molecular Weight ]:
201.061

[ Flash Point ]:
102.9±7.8 °C

[ Exact Mass ]:
199.983673

[ PSA ]:
9.23000

[ LogP ]:
3.16

[ Vapour Pressure ]:
0.1±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.535

[ Storage condition ]:
Room temperature.

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2909309090

Precursor & DownStream

Precursor

2-Bromo-4-methylphenol
Dimethyl sulfate
4-Methylanisole
methyl iodide
3-Bromo-4,4-dimethoxy-1-methyl-2,5-cyclohexadien-1-ol
p-Cresol
2-Bromo-p-toluidine
Para-Cresidine
acetic acid
Chloroform

DownStream

1,2-Dimethoxy-4-methylbenzene
2-amino-4-methoxytoluene
6-methoxy-3-methyl-2-(thiophen-2-ylmethyl)benzonitrile
Benzyl 2-bromo-4-methylphenyl ether
3-Bromo-4-methoxybenzoic acid
2-METHOXY-5-METHYLBENZOIC ACID
2-Methoxy-5-methylbenzaldehyde
2-Methoxy-5-methylbenzonitrile
Ormetoprim
2-Bromo-4-methylphenol

Preparation

Customs

[ HS Code ]: 2909309090

[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Poly (4-vinylpyridinium bromochromate): an efficient reagent for bromination of aromatic compounds. Albadi J, et al.

Monatsh. Chem 144(2) , 179-181, (2013)

Highly efficient white organic electroluminescence from a double-layer device based on a boron hydroxyphenylpyridine complex. Liu Y, et al.

Angew. Chem. Int. Ed. Engl. 41(1) , 182-184, (2002)

Unambiguous synthesis and spectral characterization of 1,8-dihydroxy-4-methylanthraquinone. Wang A, et al.

ARKIVOC 1 , 80-84, (2002)

3-bromo-4-hydroxy-3,4-dimethylpentan-2-one
3-Bromo-4-chloro-cinnoline
3-bromo-4-hydroxy-quinoline-2-carboxylic acid methyl ester
3-bromo-4,5,6,7-tetrahydrobenzo[c]thiophene-1-carboxylic acid
3-bromo-4,5-di-n-propyl-1,2,3-dithiaborole
3-Bromo-4-phenylfuroxan
N-(2-((3-phenyl-[1,2,4]triazolo[4,3-b]pyridazin-6-yl)oxy)ethyl)-6-(1H-pyrazol-1-yl)pyridazine-3-carboxamide
N-(4-(6-hydroxypyridazin-3-yl)phenyl)-6-(1H-pyrazol-1-yl)pyridazine-3-carboxamide
N-(2-(2-phenylthiazol-4-yl)ethyl)-6-(1H-pyrazol-1-yl)pyridazine-3-carboxamide
N-(2-(cyclohex-1-en-1-yl)ethyl)-6-(1H-pyrazol-1-yl)pyridazine-3-carboxamide
N-(2-phenoxyethyl)-6-(1H-pyrazol-1-yl)pyridazine-3-carboxamide
4-benzyl-5-oxo-N-(4-(pyridin-3-yl)thiazol-2-yl)morpholine-3-carboxamide
4-benzyl-N-(4-(furan-2-yl)thiazol-2-yl)-5-oxomorpholine-3-carboxamide
N-[(1H-1,3-benzodiazol-2-yl)methyl]-4-benzyl-5-oxomorpholine-3-carboxamide
N-(benzo[c][1,2,5]thiadiazol-4-yl)-4-benzyl-5-oxomorpholine-3-carboxamide
4-benzyl-5-(2,3-dihydro-1H-benzo[d]imidazo[1,2-a]imidazole-1-carbonyl)morpholin-3-one

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