3-Bromo-4-methoxytoluene

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Names

[ CAS No. ]:
22002-45-5

[ Name ]:
3-Bromo-4-methoxytoluene

[Synonym ]:
MFCD00017783
2-Bromo-1-methoxy-4-methylbenzene
2-bromo-4-methylphenyl methyl ether
Benzene, 2-bromo-1-methoxy-4-methyl-
2-Bromo-4-methyl anisole
4-methyl-2-bromoanisole
EINECS 244-705-3
2-bromo-1-methoxy-4-methyl-benzene
Benzene,2-bromo-1-methoxy-4-methyl
anisole, 2-bromo-4-methyl-
Anisole,2-bromo-4-methyl
3-BroMo-4-Methoxytoluene
1-bromo-2-methoxy-5-methylbenzene

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
227.9±20.0 °C at 760 mmHg

[ Melting Point ]:
15.5 °C(lit.)

[ Molecular Formula ]:
C8H9BrO

[ Molecular Weight ]:
201.061

[ Flash Point ]:
102.9±7.8 °C

[ Exact Mass ]:
199.983673

[ PSA ]:
9.23000

[ LogP ]:
3.16

[ Vapour Pressure ]:
0.1±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.535

[ Storage condition ]:
Room temperature.

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2909309090

Precursor & DownStream

Precursor

  • 2-Bromo-4-methylphenol
  • Dimethyl sulfate
  • 4-Methylanisole
  • methyl iodide
  • 3-Bromo-4,4-dimethoxy-1-methyl-2,5-cyclohexadien-1-ol
  • p-Cresol
  • 2-Bromo-p-toluidine
  • Para-Cresidine
  • acetic acid
  • Chloroform

DownStream

  • 1,2-Dimethoxy-4-methylbenzene
  • 2-amino-4-methoxytoluene
  • 6-methoxy-3-methyl-2-(thiophen-2-ylmethyl)benzonitrile
  • Benzyl 2-bromo-4-methylphenyl ether
  • 3-Bromo-4-methoxybenzoic acid
  • 2-METHOXY-5-METHYLBENZOIC ACID
  • 2-Methoxy-5-methylbenzaldehyde
  • 2-Methoxy-5-methylbenzonitrile
  • Ormetoprim
  • 2-Bromo-4-methylphenol

Preparation


Customs

[ HS Code ]: 2909309090

[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Poly (4-vinylpyridinium bromochromate): an efficient reagent for bromination of aromatic compounds. Albadi J, et al.

Monatsh. Chem 144(2) , 179-181, (2013)

Highly efficient white organic electroluminescence from a double-layer device based on a boron hydroxyphenylpyridine complex. Liu Y, et al.

Angew. Chem. Int. Ed. Engl. 41(1) , 182-184, (2002)

Unambiguous synthesis and spectral characterization of 1,8-dihydroxy-4-methylanthraquinone. Wang A, et al.

ARKIVOC 1 , 80-84, (2002)


More Articles

Related Compounds

  • 3-bromo-4-hydroxy-3,4-dimethylpentan-2-one
  • 3-Bromo-4-chloro-cinnoline
  • 3-bromo-4-hydroxy-quinoline-2-carboxylic acid methyl ester
  • 3-bromo-4,5,6,7-tetrahydrobenzo[c]thiophene-1-carboxylic acid
  • 3-bromo-4,5-di-n-propyl-1,2,3-dithiaborole
  • 3-Bromo-4-phenylfuroxan
  • Na-Boc-Ne-isopropyl-L-lysine
  • (2S)-7-methoxy-2-phenyl-5-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-2,3-dihydrochromen-4-one
  • Methyl 3-amino-2-hydroxy-3-phenylpropanoate
  • (2S,4S)-1-tert-butyl 2-ethyl 4-bromopyrrolidine-1,2-dicarboxylate
  • N-Boc-trans-4-azido-L-proline
  • (4S)-1-Boc-4-cyano-L-proline
  • 7-Ethenyl-4-oxo-1,4-dihydroquinoline-2-carboxylic acid
  • 3,4,5-Trifluoro-1H-pyrazole
  • 1-(1,2,3,4-Tetrahydronaphth-1-yl)cyclopropanecarbonitrile
  • 2-(2-oxo-2,3-dihydro-1H-imidazol-4-yl)acetic acid
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