3-Bromofuran

Suppliers

Names

[ CAS No. ]:
22037-28-1

[ Name ]:
3-Bromofuran

[Synonym ]:
EINECS 244-744-6
3-bromofurane
Furan,3-bromo
3-bromo-furan
3-furan bromide
Furan, 3-bromo-
3-Furyl bromide
MFCD00005347
3-Brom-furan
3-Bromofuran
4-bromofuran

Chemical & Physical Properties

[ Density]:
1.7±0.1 g/cm3

[ Boiling Point ]:
103.0±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C4H3BrO

[ Molecular Weight ]:
146.970

[ Flash Point ]:
3.3±0.0 °C

[ Exact Mass ]:
145.936722

[ PSA ]:
13.14000

[ LogP ]:
2.18

[ Vapour Pressure ]:
38.0±0.1 mmHg at 25°C

[ Index of Refraction ]:
1.505

[ Storage condition ]:
−20°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225

[ Precautionary Statements ]:
P210

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F:Flammable;Xi:Irritant;

[ Risk Phrases ]:
R11;R36/37/38

[ Safety Phrases ]:
S16-S23-S24/25-S37/39-S26

[ RIDADR ]:
UN 1993 3/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
3

[ HS Code ]:
2932190090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 3,4-dibromofuran
  • trans-5,6-dibromo-7-oxabicyclo{2.2.1}heptane-2-exo,3-cis-dicarboxylic acid anhydride

DownStream

  • Bromobenzene
  • 1,3-Hexadien-5-yne.
  • carbon monoxide
  • benzene
  • 3-Furylboronic acid
  • Furan-3-carboxylic acid
  • Methyl furan-3-carboxylate
  • tert-Butyl furan-3-ylcarbamate
  • 3-furansulfonyl chloride
  • 5-Furan-3-yl-1H-indole

Customs

[ HS Code ]: 2932190090

[ Summary ]:
2932190090 other compounds containing an unfused furan ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

Articles

Cantharidin analogues: synthesis and evaluation of growth inhibition in a panel of selected tumour cell lines.

Bioorg. Chem. 31(1) , 68-79, (2003)

Diels-Alder addition of furans (furan, furfuryl alcohol, and 3-bromofuran) to maelic anhydride yields three distinct 5,6-dehydronorcantharidins. Hydrogenation of (4,10-dioxatricyclo[5.2.1.0]decane-3,5...

Addition/oxidative rearrangement of 3-furfurals and 3-furyl imines: new approaches to substituted furans and pyrroles.

J. Am. Chem. Soc. 130(12) , 4097-104, (2008)

Furans and pyrroles are important synthons in chemical synthesis and are commonly found in natural products, pharmaceutical agents, and materials. Introduced herein are three methods to prepare 2-subs...


More Articles

Related Compounds

  • 2-methyl-3-bromofuran
  • 2-Acetyl-3-bromofuran
  • 3-bromofuran-2,5-dione
  • 3-Bromofuran-2(5H)-one
  • 3-bromofuran-2-methanol
  • 3-bromofuran-2-carbaldehyde
  • 2-[3-(4-chlorophenyl)-6-oxopyridazin-1(6H)-yl]-N-[1-(2-methoxyethyl)-1H-indol-4-yl]acetamide
  • N-[2-(5-chloro-1H-indol-3-yl)ethyl]-4-(5-methyl-1H-tetrazol-1-yl)benzamide
  • 4-(4-fluorophenyl)-N-{2-oxo-2-[(2-phenylethyl)amino]ethyl}piperazine-1-carboxamide
  • C19H27Cl2NO3
  • 2-[3-(4-chlorophenyl)-6-oxopyridazin-1(6H)-yl]-N-(1-methyl-1H-indol-4-yl)acetamide
  • N-(4-acetamidophenyl)-4-(6-methoxy-[1,2,4]triazolo[4,3-b]pyridazin-3-yl)butanamide
  • 4-phenyl-N-(4,5,6,7-tetrahydrobenzo[d]thiazol-2-yl)tetrahydro-2H-pyran-4-carboxamide
  • 2'-(butan-2-yl)-1'-oxo-N-(pyridin-3-ylmethyl)-1',4'-dihydro-2'H-spiro[cyclohexane-1,3'-isoquinoline]-4'-carboxamide
  • 4-(4-chlorophenyl)-N-{2-[(3,5-dimethoxyphenyl)amino]-2-oxoethyl}piperazine-1-carboxamide
  • 3-(3-acetyl-1H-indol-1-yl)-N-(6-methoxypyridin-3-yl)propanamide
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