DICHORO(3-METHYL-2-BUTENYLIDENE)BIS

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Names

[ CAS No. ]:
220883-08-9

[ Name ]:
DICHORO(3-METHYL-2-BUTENYLIDENE)BIS

[Synonym ]:
Phosphine, tricyclopentyl-, compd. with dichloro(3-methyl-2-buten-1-ylidene)ruthenium (2:1)
dichloro(3-methylbut-2-enylidene)ruthenium
MFCD04039971
RuCl2(=CH-CH=CMe2)(P(Cyp)3)2
DICHORO(3-METHYL-2-BUTENYLIDENE)BIS
Dichloro(3-methyl-2-buten-1-ylidene)ruthenium - tricyclopentylphosphine (1:2)

Chemical & Physical Properties

[ Melting Point ]:
94-96ºC(lit.)

[ Molecular Formula ]:
C₃₅H₆₂Cl₂P₂Ru

[ Molecular Weight ]:
716.790

[ Exact Mass ]:
716.274780

[ PSA ]:
27.18000

[ LogP ]:
13.48730

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H228

[ Precautionary Statements ]:
P210

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ RIDADR ]:
UN1325 - class 4.1 - PG 2 - Flammable solids, organic, n.o.s., HI: all

[ WGK Germany ]:
3

Articles

Schrodi, Y.; Pederson, R. L.

Aldrichimica Acta 40th ed.,, 45, (2007)

Vougioukalakis, G. C.; Grubbs, R. H.

Chem. Rev. 110th ed.,, 1746, (2010)

Grubbs, R. H.

Tetrahedron 60th ed.,, 7117, (2004)

Dichloro(3-methyl-2-butenylidene)bis(tricyclohexylphosphine)ruthenium(II)
[1-[chloro-(2-chlorophenyl)-diphenyl-λ5-phosphanyl]-3-methylbut-2-enyl]-triphenylphosphanium,ruthenium
(1-cyclopropyl-3-methyl-2-propan-2-ylbut-1-enyl)cyclopropane
Grubbs Catalyst M207
trimethyl-[3-methyl-2,5-bis(trimethylsilyl)phenoxy]silane
(E)-3-methyl-2,5-bis(triisopropylsiloxy)-1,3-pentadiene
1-(2,4,6-Trimethylphenyl)cyclopentan-1-amine
3,4,4-Trifluoropentan-1-amine
7-Methoxy-4-methylene-1-(methylsulfonyl)-1,2,3,4-tetrahydroquinoline
3-Ethyl-5-iodobenzenesulfonyl chloride
2,2-Difluoro-2-[2-(trifluoromethyl)phenyl]ethan-1-amine
2-(2-Ethoxyphenyl)-2,2-difluoroethan-1-amine
3-(2-Amino-1,1-difluoroethyl)benzonitrile
1H-Pyrazole-1-ethanol, 4-chloro-5-[(methylamino)methyl]-
5-Bromo-4-methyl-4H-1,2,4-triazole-3-carbaldehyde
[(4-Bromofuran-2-yl)methyl](methyl)amine

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