(|R|)-(+)-2,2',6,6'-Tetramethoxy-4,4'-bis(diphenylphosphino)-3,3'-bipyridine

Names

[ CAS No. ]:
221012-82-4

[ Name ]:
(|R|)-(+)-2,2',6,6'-Tetramethoxy-4,4'-bis(diphenylphosphino)-3,3'-bipyridine

[Synonym ]:
(R)-(+)-2,2',6,6'-Tetramethoxy-4,4'-bis(diphenylphosphino)-3,3'-bipyridine
MFCD04038734

Chemical & Physical Properties

[ Boiling Point ]:
686.1ºC at 760 mmHg

[ Melting Point ]:
261-265ºC

[ Molecular Formula ]:
C₃₈H₃₄N₂O₄P₂

[ Molecular Weight ]:
644.63500

[ Flash Point ]:
368.7ºC

[ Exact Mass ]:
644.19900

[ PSA ]:
89.88000

[ LogP ]:
5.69440

[ Vapour Pressure ]:
6.72E-18mmHg at 25°C

MSDS

Safety Information

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36/37/39

[ RIDADR ]:
NONH for all modes of transport

Articles

P-Phos: a family of versatile and effective atropisomeric dipyridylphosphine ligands in asymmetric catalysis.

Acc. Chem. Res. 39 , 711, (2006)

This Account outlines our efforts in the design and synthesis of a family of highly effective atropisomeric dipyridylphosphine ligands (P-Phos and its variants) and in the development of their widespr...