Bromoacetyl chloride

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Names

[ Name ]:
Bromoacetyl chloride

[Synonym ]:
Acetyl chloride, 2-bromo-
bromoethanoyl chloride
monobromoacetic acid chloride
MFCD00000724
Acetyl chloride,bromo
Bromoacetyl chloride
EINECS 244-790-7
bromo-acetyl chloride
bromoacethyl chloride

Chemical & Physical Properties

[ Density]:
1.9±0.1 g/cm3

[ Boiling Point ]:
127.0±0.0 °C at 760 mmHg

[ Melting Point ]:
127 - 128 °C

[ Molecular Formula ]:
C₂H₂BrClO

[ Molecular Weight ]:
157.394

[ Flash Point ]:
26.1±19.8 °C

[ Exact Mass ]:
155.897751

[ PSA ]:
17.07000

[ LogP ]:
1.15

[ Vapour Pressure ]:
11.4±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.487

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314-H335

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R14;R34;R37

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 3265 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
2915900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Bromoacetic acid
BROMOACETIC ANHYDRIDE
phenyldichlorofluorosilane
Benzoyl chloride
1-Bromo-1-chloroethene

DownStream

Acetamide,2-bromo-N-(4-bromophenyl)-
2-Bromo-N-methyl-acetamide
2-Bromo-1-(4-morpholinyl)ethanone
2-Bromo-N,N-dimethylacetamide
2-bromo-N-[4-(trifluoromethyl)phenyl]acetamide
N1-(3,5-DICHLOROPHENYL)-2-BROMOACETAMIDE
2-Bromo-N-(2,6-dimethylphenyl)acetamide
2-bromo-n-(3-methylphenyl)acetamide
2-bromo-1-(2,3-dihydro-1-benzofuran-5-yl)ethanone
2-Bromo-N-(4-methoxybenzyl)acetamide

Customs

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

Articles

Evidence for histidine in the active site of papain.

Biochem. J. 108(5) , 855-9, (1968)

Papain was irreversibly inhibited by 1,3-dibromoacetone, a reagent designed to react first with the active-site cysteine residue and subsequently with a second nucleophile. The molecular weight of the...

Non-adiabatic effects in the photodissociation of bromoacetyl chloride. Bacchus-Montabonel M-C, et al.

Chem. Phys. Lett. 374(3) , 307-13, (2003)

Cycloaddition chemistry of anhydro-4-hydroxy-1, 3-thiazolium hydroxides (thioisomünchnones) for the synthesis of heterocycles. Padwa A, et al.

Synthesis 1994(9) , 993-1004, (1994)

bromoacetyl chloride, [1-14c]
4-[(2-bromoacetyl)amino]benzenesulfonyl chloride
4-(2-BROMOACETYL)BENZENESULFONYLCHLORIDE
3-(2-BROMOACETYL)BENZENESULFONYLCHLORIDE
Butanoyl chloride, 4-aMino-, hydrochloride
Cyclohexanecarbonyl chloride, 2-methyl- (6CI, 9CI)
{3-[(Cyclopropylcarbonyl)amino]phenoxy}acetic acid
2-(2,4-dichlorophenyl)-1-methyl-1H-indole
2-ethyl-5-{[(4-methylphenyl)sulfanyl]methyl}[1,2,4]triazolo[1,5-a]pyrimidin-7(4H)-one
N-(4-chlorophenyl)-2-[(4-fluorophenyl)amino]-6-oxo-3,4,5,6-tetrahydropyrimidine-4-carboxamide
5-[(3-nitrophenyl)methyl]-2H-tetrazole
2-(3,4-Dimethyl-phenylamino)-N-(4-methoxy-phenyl)-propionamide
2,3a(2)-Bipyrrolidine, 1,1a(2)-diphenyl-, (R*,R*)-
2-(naphthalen-1-yl)-N-(1-(propylsulfonyl)-1,2,3,4-tetrahydroquinolin-6-yl)acetamide
N-(4-(N-(1-(ethylsulfonyl)-1,2,3,4-tetrahydroquinolin-6-yl)sulfamoyl)-3-methylphenyl)acetamide
2-Amino-4-(4-chlorophenyl)-6-methyl-5,6,7,8-tetrahydro-1,6-naphthyridine-3-carbonitrile