5-Bromoindoline

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Names

[ CAS No. ]:
22190-33-6

[ Name ]:
5-Bromoindoline

[Synonym ]:
5-Brom-2,3-dihydro-1H-indol
5-bromo-1H-indoline
6-bromo-dihydroindole
5-bromodihydroindole
MFCD00027410
5-Bromoindoline
1H-Indole, 5-bromo-2,3-dihydro-

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
282.5±29.0 °C at 760 mmHg

[ Melting Point ]:
36-40 °C(lit.)

[ Molecular Formula ]:
C8H8BrN

[ Molecular Weight ]:
198.060

[ Flash Point ]:
124.7±24.3 °C

[ Exact Mass ]:
196.984009

[ PSA ]:
12.03000

[ LogP ]:
2.79

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.602

[ Storage condition ]:
?20°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ HS Code ]:
2933990090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 5-Bromoindole
  • 1-acetyl-5-bromoindoline
  • 1H-Indole-1-carboxylic acid, 5-bromo-2,3-dihydro-, methyl ester
  • Indoline
  • 1-Acetylindoline

DownStream

  • 5-Phenylindoline
  • tert-butyl 5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)indoline-1-carboxylate
  • 5-Bromo-1H-indol-6-amine
  • 5-Bromoindole
  • 5-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)indoline
  • GSK2606414
  • 1-acetyl-5-bromoindoline
  • tert-Butyl 5-bromoindoline-1-carboxylate
  • 5-bromo-N-methyl-2,3-dihydroindole-1-carboxamide
  • tert-butyl 4-(5-bromo-2,3-dihydroindol-1-yl)piperidine-1-carboxylate

Preparation


Customs

[ HS Code ]: 2933990090

[ Summary ]:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Related Compounds

  • N-Boc-5-bromoindoline
  • 5-bromoindoline-2-thione
  • N-methyl-5-bromoindoline
  • 1-acetyl-5-bromoindoline
  • 5-Bromoindoline-2,3-dione
  • 1-BENZOYL-5-BROMOINDOLINE
  • N,2,2-trimethylcyclopropan-1-amine
  • 5-Bromo-1-(4-iodophenyl)-1H-indazole
  • 2-(5-Amino-2,4-dioxo-3,4-dihydropyrimidin-1(2h)-yl)-N-ethylacetamide
  • 1-(4-Iodo-1H-pyrazol-1-yl)-3-morpholinopropan-2-ol
  • 2-Methoxy-1-(oxan-4-yl)ethan-1-one
  • Pyridine, 3,5-dichloro-2-(1-hydrazinyl-2-methylbutyl)-
  • [1-(Oxan-4-yl)pyrrolidin-3-yl]methanol
  • 1-(Benzyloxy)-3-(2-methoxyphenoxy)propan-2-ol
  • 1-(Oxan-2-ylmethyl)-2-oxopyridine-3-carboxylic acid
  • 5-(Allyloxy)-4-chloro-1-methyl-1H-pyrazole-3-carboxylic acid
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