Copper(1+) sulfidocopper

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Names

[ CAS No. ]:
22205-45-4

[ Name ]:
Copper(1+) sulfidocopper

[Synonym ]:
Copper(1+) sulfidocopper
MFCD00016062
COPPER(I) SULFIDE
copper stearate
copper selenide
Cu-stearate
copper sulphide
EINECS 244-842-9
cuprous sulphide
cuprous sulfide

Chemical & Physical Properties

[ Density]:
5.6 g/mL at 25ºC(lit.)

[ Melting Point ]:
1100ºC

[ Molecular Formula ]:
Cu2S

[ Molecular Weight ]:
159.157

[ Exact Mass ]:
157.831268

[ PSA ]:
25.30000

[ LogP ]:
0.64320

[ Appearance of Characters ]:
powder

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
GL8910000
CHEMICAL NAME :
Copper(I) sulfide
CAS REGISTRY NUMBER :
22205-45-4
LAST UPDATED :
199707
DATA ITEMS CITED :
32
MOLECULAR FORMULA :
Cu2-S
MOLECULAR WEIGHT :
159.14
WISWESSER LINE NOTATION :
.CU..S

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :
Morphological transformation
TEST SYSTEM :
Rodent - hamster Embryo
DOSE/DURATION :
380 umol/L
REFERENCE :
CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut Sts., Philadelphia, PA 19106) V.1- 1941- Volume(issue)/page/year: 39,193,1979 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 0.1 mg(Cu)/m3 (fume) JAN 1993 OEL-AUSTRALIA:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-AUSTRALIA:TWA 1 mg(Cu)/m3 (dust) JAN 1993 OEL-BELGIUM:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-BELGIUM:TWA 1 mg(Cu)/m3 (dust) JAN 1993 OEL-DENMARK:TWA 0.1 mg(Cu)/m3 (fume) JAN 1993 OEL-DENMARK:TWA 1 mg(Cu)/m3 (dust) JAN 1993 OEL-FINLAND:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-FINLAND:TWA 1 mg(Cu)/m3 (dust) JAN 1993 OEL-FRANCE:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-FRANCE:TWA 1 mg(Cu)/m3;STEL 2 mg(Cu)/m3 (dust) JAN 1993 OEL-GERMANY:TWA 0.1 mg(Cu)/m3 (fume) JAN 1993 OEL-GERMANY:TWA 1 mg(Cu)/m3 (dust) JAN 1993 OEL-HUNGARY:TWA 0.2 mg(Cu)/m3;STEL 0.4 mg(Cu)/m3 (dust) JAN 1993 OEL-INDIA:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-THE NETHERLANDS:TWA 02 mg(Cu)/m3 (fume) JAN 1993 OEL-THE NETHERLANDS:TWA 1 mg(Cu)/m3 (dust) JAN 1993 OEL-THE PHILIPPINES:TWA 1.0 mg(Cu)/m3 (fume) JAN 1993 OEL-POLAND:TWA 0.1 mg(Cu)/m3 (fume) JAN 1993 OEL-RUSSIA:STEL 0.5 ppm (1 mg(Cu)/m3) (dust) JAN 1993 OEL-SWEDEN:TWA 0.2 mg(Cu)/m3 (resp. dust) JAN 1993 OEL-SWEDEN:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-SWEDEN:TWA 1 mg(Cu)/m3 (total dust) JAN 1993 OEL-SWITZERLAND:TWA 0.1 mg(Cu)/m3;STEL 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-SWITZERLAND:TWA 1 mg(Cu)/m3;STEL 1 mg(Cu)/m3 JAN 1993 OEL-THAILAND:TWA 0.1 mg(Cu)/m3 (fume) JAN 1993 OEL-THAILAND:TWA 1 mg(Cu)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-UNITED KINGDOM:TWA 1 mg(Cu)/m3 JAN 1993

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R20/21/22

[ Safety Phrases ]:
7-22-36/37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
GL8910000

Synthetic Route

Precursor & DownStream

Precursor

  • Carbon disulphide
  • Sulfur
  • hydrogen sulfide
  • Copper sulfate pentahydrate
  • SULFUR DIOXIDE
  • Copper(II) acetate
  • cyclooctasulfur
  • Sulfuric acid

DownStream

  • Cupric hydroxide
  • Copper sulfate pentahydrate
  • Carbon
  • Sulfur trioxide
  • sulfate
  • Sulfur
  • SULFUR DIOXIDE
  • Nickel
  • hydrogen sulfide

Articles

Preparation and properties of a new solid state borate ion selective electrode and its application.

Talanta 85(3) , 1461-5, (2011)

A new borate ion selective electrode using solid salts of Ag(3)BO(3), Ag(2)S and Cu(2)S has been developed. Detailed information is provided concerning the composition, working pH and conditioning of ...

Nanoscale copper sulfide hollow spheres with phase-engineered composition: covellite (CuS), digenite (Cu1.8S), chalcocite (Cu2S).

Nanoscale 3(6) , 2544-51, (2011)

Covellite (CuS), digenite (Cu(1.8)S) and chalcocite (Cu(2)S) are prepared as nanoscaled hollow spheres by reaction at the liquid-to-liquid phase boundary of a w/o-microemulsion. According to electron ...

Nanocrystalline Janus films of inorganic materials prepared at the liquid–liquid interface

J. Colloid. Interface Sci. 333(1) , 404-10, (2009)

The interface between toluene and water has been employed to prepare ultrathin Janus nanocrystalline films of metal oxides, metal chalcogenides and gold, wherein the surface on the organic-side is hyd...


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