formetanate

Names

[ CAS No. ]:
22259-30-9

[ Name ]:
formetanate

[Synonym ]:
Caswell No. 465A
N,N-Dimethyl-N'-(3-methylcarbamoyloxy-phenyl)-formamidine
FORMETANATE
N,N-dimethyl-N’-[3-[[(methylamino)carbonyl]oxy]phenyl]methanimidamide
[3-(dimethylaminomethylideneamino)phenyl] N-methylcarbamate
Formetanate [ANSI:BSI:ISO]
Formetanat
EP 322
N,N-Dimethyl-N'-(3-{[(methylamino)carbonyl]oxy}phenyl)methanimidamide
3-[(EZ)-dimethylaminomethyleneamino]phenyl methylcarbamate
Dicarzol
3-{[(Ξ)-(dimethylamino)methylidene]amino}phenyl methylcarbamate
Carbamic acid,methyl-,ester with N'-(m-hydroxyphenyl)-N,N-dimethylformamidine
m-[N-(dimethylaminomethylene) amino] phenyl N-methyl carbamate
EINECS 244-879-0

Chemical & Physical Properties

[ Density]:
1.09g/cm3

[ Boiling Point ]:
362.32°C (rough estimate)

[ Melting Point ]:
102.5°C

[ Molecular Formula ]:
C11H15N3O2

[ Molecular Weight ]:
221.25600

[ Exact Mass ]:
221.11600

[ PSA ]:
57.42000

[ LogP ]:
1.83060

[ Index of Refraction ]:
1.529

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
FC2513000
CHEMICAL NAME :
Carbamic acid, methyl-, ester with N'-(m-hydroxyphenyl)-N,N-dimethylformamidine
CAS REGISTRY NUMBER :
22259-30-9
LAST UPDATED :
199612
DATA ITEMS CITED :
7
MOLECULAR FORMULA :
C11-H15-N3-O2
MOLECULAR WEIGHT :
221.29

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
20 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
WRPCA2 World Review of Pest Control. (London, UK) V.1-10, 1962-71. Discontinued. Volume(issue)/page/year: 9,119,1970
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
290 mg/m3/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A216,1983
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>5600 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France) V.1- 1947- Volume(issue)/page/year: 28,43,1974
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
18 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A216,1983
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
19 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A216,1983
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>10200 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France) V.1- 1947- Volume(issue)/page/year: 28,43,1974
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - chicken
DOSE/DURATION :
21500 ug/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France) V.1- 1947- Volume(issue)/page/year: 28,43,1974

Safety Information

[ Hazard Codes ]:
T+: Very toxic;N: Dangerous for the environment;

[ Risk Phrases ]:
26/28-43-50/53

[ Safety Phrases ]:
24-28-37/39-45-60-61

[ RIDADR ]:
UN 2757

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1(a)

[ HS Code ]:
2925290012

Synthetic Route

Precursor & DownStream

Precursor

  • N'-(3-hydroxyphenyl)-N,N-dimethylformamidine
  • Methylisocyanate 1 x 500mg neat

DownStream

  • N'-(3-hydroxyphenyl)-N,N-dimethylformamidine
  • N-(3-hydroxyphenyl)formamide
  • (3-formamidophenyl) N-methylcarbamate

Customs

[ HS Code ]: 2925290012

[ Summary ]:
2925290012 (e)-3-(((dimethylamino)methylene)amino)phenyl methylcarbamate。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:30.0%


Related Compounds

  • 9H-9-(2-Naphthyl)-benzo[4,5]thieno[3,2-b]thieno[3,4-d]pyrrole
  • tert-butyl 4-amino-1-cyclopropyl-3-(trifluoromethyl)-1H-pyrazole-5-carboxylate
  • 4-chloro-2-(cyclopropylmethyl)-7H-pyrrolo[2,3-d]pyrimidine
  • N-[(4,5-dibromo-1-ethyl-1H-imidazol-2-yl)methyl]cyclopropanamine
  • 1-(5-Aminoisoquinolin-1-yl)cyclopropane-1-carboxylic acid
  • Ethyl 2-amino-5-chloro-4-(trifluoromethyl)thiophene-3-carboxylate
  • 4-chloro-2-(cyclopropylmethyl)-5-iodo-7H-pyrrolo[2,3-d]pyrimidine
  • Methyl 2-[4-(6-aminopyridin-3-yl)-2-oxo-1,2-dihydropyridin-1-yl]acetate
  • 2-Benzyl-4,5,6,7-tetrahydro-2H-indazole-3-sulfonyl chloride
  • 4,4-dichloro-N,N-dimethylbutanamide
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