3-Bromo-4-picoline

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Names

[ CAS No. ]:
22282-99-1

[ Name ]:
3-Bromo-4-picoline

[Synonym ]:
4-Brom-2-methyl-pyridin
3-Bromo-4-methylpyridine
Pyridine,4-bromo-2-methyl
4-bromo-2-methyl pyridine
4-BROMO-2-PICOLINE HCL
Pyridine, 3-bromo-4-methyl-
4-BROMO-METHYL-PYRIDINE
MFCD03788196
4-BroMo-2-Methylpyridine
4-Bromo-2-methylpyridie
3-Bromo-4-picoline
4-Bromo-2-picoline
2-Methyl-4-bromopyridine
4-bromopicoline
4-bormo-2-methylpyridine

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
198.8±20.0 °C at 760 mmHg

[ Molecular Formula ]:
C6H6BrN

[ Molecular Weight ]:
172.02

[ Flash Point ]:
74.1±21.8 °C

[ Exact Mass ]:
170.968353

[ PSA ]:
12.89000

[ LogP ]:
2.21

[ Vapour Pressure ]:
0.5±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.553

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302-H315-H318-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn:Harmful

[ Risk Phrases ]:
R22;R37/38;R41

[ Safety Phrases ]:
S26-S36/39

[ RIDADR ]:
NA 1993 / PGIII

[ WGK Germany ]:
3

[ HS Code ]:
2942000000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 4-Amino-2-picoline
  • Methylmagnesium chloride
  • 4-Bromo-pyridine HCl
  • METHYLMAGNESIUM BROMIDE
  • 4-Bromopicolinaldehyde
  • 4-Nitro-2-picoline
  • Acetyl bromide
  • 4-Nitro-2-picoline-N-oxide
  • 2-Picoline 1-oxide

DownStream

  • ethyl 2-(4-bromopyridin-2-yl)acetate
  • 4-Bromo-pyridinecarboxylic acid
  • (4-bromopyridin-2-yl)methyl acetate
  • 4-Ethynyl-2-methylpyridine
  • (4-Bromopyridin-2-yl)methanamine
  • (2-Methyl-4-pyridinyl)boronic acid
  • 2-Methylpyridine-4-boronic acid pinacol ester
  • 4-Bromo-2-(bromomethyl)pyridine
  • 4-bromo-2-dibromomethylpyridine
  • 2-METHYL-4-HYDROXYMETHYLPYRIDINE

Preparation


Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Synthesis , 907, (2005)


More Articles

Related Compounds

  • 3-Bromo-4-picoline
  • 2-Amino-3-bromo-4-picoline
  • 2-CHLORO-3-BROMO-4-PICOLINE
  • 2,5-DIAMINO-3-BROMO-4-PICOLINE
  • 2,5-Diamino-3-bromo-4-picoline
  • 2,5-DIAMINO-3-BROMO-4-PICOLINE
  • 4-(4-methyl-4H-1,2,4-triazol-3-yl)benzene-1-sulfonamide
  • 2-((3-butyl-4-oxo-7-phenyl-4,5-dihydro-3H-pyrrolo[3,2-d]pyrimidin-2-yl)thio)-N-(3-chloro-2-methylphenyl)acetamide
  • 2-((3-butyl-4-oxo-7-phenyl-4,5-dihydro-3H-pyrrolo[3,2-d]pyrimidin-2-yl)thio)-N-(3-chloro-4-methylphenyl)acetamide
  • 2-[(3-butyl-4-oxo-7-phenyl-4,5-dihydro-3H-pyrrolo[3,2-d]pyrimidin-2-yl)sulfanyl]-N-(2,6-dimethylphenyl)acetamide
  • 2-[(3-butyl-4-oxo-7-phenyl-4,5-dihydro-3H-pyrrolo[3,2-d]pyrimidin-2-yl)sulfanyl]-N-(2,5-dimethylphenyl)acetamide
  • 2-((3-butyl-4-oxo-7-phenyl-4,5-dihydro-3H-pyrrolo[3,2-d]pyrimidin-2-yl)thio)-N-(5-chloro-2-methoxyphenyl)acetamide
  • 2-[(3-butyl-4-oxo-7-phenyl-4,5-dihydro-3H-pyrrolo[3,2-d]pyrimidin-2-yl)sulfanyl]-N-(3-chloro-4-methoxyphenyl)acetamide
  • 2-((3-butyl-4-oxo-7-phenyl-4,5-dihydro-3H-pyrrolo[3,2-d]pyrimidin-2-yl)thio)-N-(2,5-dimethoxyphenyl)acetamide
  • 3-(4-methyl-4H-1,2,4-triazol-3-yl)benzene-1-sulfonamide
  • N-(4-acetylphenyl)-2-((3-butyl-4-oxo-7-phenyl-4,5-dihydro-3H-pyrrolo[3,2-d]pyrimidin-2-yl)thio)acetamide